Electrochemical enhancement of high-efficiency wet removal of mercury from flue gas

Author(s):  
Nai-jiao Xu ◽  
Sen Li ◽  
Yu-hong Fu ◽  
Zhao-yang Wang ◽  
Li-juan Feng ◽  
...  
Keyword(s):  
Flue Gas ◽  
2014 ◽  
Vol 675-677 ◽  
pp. 422-425
Author(s):  
Jun Xia Liu

This Paper introduced the research background and technical features of the simulative experiments in the laboratory with the sorbent of lime solution without lime particles. By means of the effects of various influencing factors on SO2 removal efficiency were studied carefully. These parameters include gas flow rate (G), inlet SO2 concentration, liquid-to-gas ratios, the height of the packing and the additive, at the same time menstruating the pH value of the liquid flowing from the tower. To improve desulfurization efficiency of limestone in the wet flue gas desulfurization (WFGD), effect of the hexanedioic acid additive on limestone desulfurization agent were studied. The result shows that this system has advantages of high efficiency, stable, low investment and low circulating cost. The result could give a reference to optimization and will be helpful in selecting desulfurization techniques.


2002 ◽  
Vol 125 (1) ◽  
pp. 216-227 ◽  
Author(s):  
N. D. A˚gren ◽  
M. O. J. Westermark

This is Part II of a two-part paper and presents calculation results of a part-flow EvGT cycle based on gas turbine data for the ABB GTX100 (modified for intercooling). The evaporative gas turbine cycle is a new high-efficiency cycle that has reached the pilot testing stage. This paper presents calculation results of a new humidification strategy based on part-flow humidification. This strategy involves using only a fraction of the compressed air for humidification. Thermodynamically, it can be shown that not all the air needs to be passed through the humidification system to attain the intrinsic good flue gas heat recovery of an EvGT cycle. The presented system also includes live steam production and superheating, by heat from the hottest flue gas region, for injection. The humidifier then only uses the lower temperature levels, where it is best suited. The analyzed system is based on data for the ABB GTX100.gas turbine in intercooled mode. Part I of this two-part paper presents the results based on data for the aeroderovative Rolls Royce Trent. Simulation results include electric efficiency and other process data as function of degree of part flow. A detailed model of the humidifier is used, which produces sizing results both for column height and diameter. Paper I includes detailed description of the modeling. For the GTX100 system, full-flow humidification generates an electric efficiency of 52.6% (simple cycle 36.2%). The efficiency is virtually unaffected if the air portion to humidification is cut to 60% of accessible compressor air (represents 48% of compressor intake). If 30% of air from the compressor after cooling bleed (24% of intake) is led to the humidifier, the efficiency is reduced to 52.2%. On the other hand is the total heat exchanger area reduced by 20% and column volume by 50%. This calls for a recommendation not to use all the compressed air for humidification. It is recommended to use 15–30% of compressor intake air. The exact economic optimum depends on local fuel prices, CO2 taxes, interest rates, etc.


1997 ◽  
Vol 11 (2) ◽  
pp. 277-283 ◽  
Author(s):  
Radu V. Vladea ◽  
Natalia Hinrichs ◽  
Robert R. Hudgins ◽  
Sam Suppiah ◽  
Peter L. Silveston

2010 ◽  
Vol 24 (9) ◽  
pp. 4931-4936 ◽  
Author(s):  
Yangxian Liu ◽  
Jun Zhang ◽  
Changdong Sheng ◽  
Yongchun Zhang ◽  
Liang Zhao

Author(s):  
Niklas D. Ågren ◽  
Mats O. Westermark ◽  
Michael A. Bartlett ◽  
Torbjörn Lindquist

The evaporative gas turbine (EvGT), also known as the humid air turbine (HAT) cycle, is a novel advanced gas turbine cycle that has attracted considerable interest for the last decade. This high efficiency cycle shows the potential to be competitive with Diesel engines or combined cycles in small and intermediate scale plants for power production — and/or cogeneration. A 0.6 MW natural gas fired EvGT pilot plant has been constructed by a Swedish national research group in cooperation between universities and industry. The plant is located at the Lund Institute of Technology, Lund, Sweden. The pilot plant uses a humidification tower with metallic packing in which heated water from the flue gas economizer is brought into direct counter current contact with the pressurized air from the compressor. This gives an efficient heat recovery and thereby a thermodynamically sound cycle. As the hot sections in high temperature gas turbines are sensitive to particles and alkali compounds, water quality issues need to be carefully considered. As such, apart from evaluating the thermodynamic and part load performance characteristics of the plant, and verifying the operation of the high pressure humidifier, much attention is focused on the water chemistry issues associated with the recovery and reuse of condensate water from the flue gas. A water treatment system has been designed and integrated into the pilot plant. This paper presents the first water quality results from the plant. The experimental results show that the condensate contains low levels of alkali and calcium, around 2 mg/l Σ(K,Na,Ca), probably originating from the unfiltered compressor intake. About 14 mg/l NO2− + NO3− comes from condensate absorption of flue gas NOx. Some Cu is noted, 16 mg/l, which originates from copper corrosion of the condenser tubes. After CO2-stripping, condensate filtration and a mixed bed ion exchanger, the condensate is of suitable quality for reuse as humidification water. The need for large quantities of demineralized water has by many authors been identified as a drawback for the evaporative cycle. However, by cooling the humid flue gas, the recovery of condensed water cuts the need of water feed. A self supporting water circuit can be achieved, with no need for any net addition of water to the system. In the pilot plant, this was achieved by cooling the flue gas to around 35°C.


Author(s):  
Niklas D. Ågren ◽  
Mats O. J. Westermark

The evaporative gas turbine cycle is a new high efficiency power cycle that has reached the pilot testing stage. This paper presents calculation results of a new humidification strategy based on part flow humidification. This strategy involves using only a fraction of the compressed air for humidification. Thermodynamically, it can be shown that not all the air needs to be passed through the humidification system to attain the intrinsic good flue gas heat recovery of an EvGT cycle. The system presented also includes live steam production and superheating by heat from the hottest flue gas region. The humidifier only uses the lower temperature levels flue gas heat, where it is best suited. The analyzed system is based on data for the aeroderivative Rolls Royce Trent as a gas turbine core. Part 2 of this 2-part paper presents the results based on data for the industrial gas turbine ABB GTX100. Simulation results include electric efficiency and other process datas as functions of degree of part flow. A detailed model of the humidifier is also used and described, which produces sizing results both for column height and diameter. Full flow humidification generates an electric efficiency of 51.5% (simple cycle 41%). The efficiency increases when the humidification air flow is reduced, to reach a maximum of 52.9% when air flow to the humidification amounts to around 12% of the intake air to the compressor. At the same time, total heat exchanger area is reduced by 50% and humidifier volume by 36% compared to full flow humidification. This calls for a recommendation not to use all the compressed air for humidification.


2013 ◽  
Vol 699 ◽  
pp. 72-76
Author(s):  
Yu Zheng ◽  
Xiang Chao Meng ◽  
Chun Hu Li ◽  
Liang Wang ◽  
Qun Wang ◽  
...  

The removal of SO2 and NO from flue gas could be achieved with high efficiency by using activated semi-coke through catalytic oxidation. In order to probe the interaction between SO2 and NO on the surface of activated semi-coke, the TPD study was carried out when NO and SO2 had adsorbed separately on the support surface or they were brought into the reaction of TPD simultaneously. The results showed that the activated semi-coke had two different alkaline adsorption sites and the surface of semi-coke was heterogeneous due to the appearance of overlap peak. What’s more, SCO process by using activated semi-coke should be placed after the process of desulfurization.


Nukleonika ◽  
2021 ◽  
Vol 66 (4) ◽  
pp. 227-231
Author(s):  
Andrzej Pawelec ◽  
Andrzej G. Chmielewski ◽  
Yongxia Sun ◽  
Sylwester Bułka ◽  
Toms Torims ◽  
...  

Abstract Operation of marine diesel engines causes significant emission of sulphur and nitrogen oxides. It was noticed worldwide and the regulations concerning harmful emissions were introduced. There were several solutions elaborated; however, emission control for both SOx and NOx requires two distinctive processes realized in separated devices, which is problematic due to limited space on ship board and high overall costs. Therefore, the electron beam flue gas treatment (EBFGT) process was adopted to ensure the abatement of the problem of marine diesel off-gases. This novel solution combines two main processes: first the flue gas is irradiated with electron beam where NO and SO2 are oxidized; the second stage is wet scrubbing to remove both pollutants with high efficiency. Laboratory tests showed that this process could be effectively applied to remove SO2 and NOx from diesel engine off-gases. Different compositions of absorbing solution with three different oxidants (NaClO, NaClO2 and NaClO3) were tested. The highest NOx removal efficiency (>96%) was obtained when seawater-NaClO2-NaOH was used as scrubber solution at 10.9 kGy dose. The process was further tested in real maritime conditions at Riga shipyard, Latvia. More than 45% NOx was removed at a 5.5 kGy dose, corresponding to 4800 Nm3/h off-gases arising from ship emission. The operation of the plant was the first case of examination of the hybrid electron beam technology in real conditions. Taking into account the experiment conditions, good agreement was obtained with laboratory tests. The results obtained in Riga shipyard provided valuable information for the application of this technology for control of large cargo ship emission.


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