scholarly journals Deep resistivity “turnover” effect at oil generation “peak” in the Woodford Shale, Anadarko Basin, USA

2019 ◽  
Vol 16 (5) ◽  
pp. 972-980
Author(s):  
Ting Wang ◽  
Jacobi David

Abstract The Devonian Woodford Shale in the Anadarko Basin is a highly organic, hydrocarbon source rock. Accurate values of vitrinite reflectance (Ro) present in the Woodford Shale penetrated by 52 control wells were measured directly. These vitrinite reflectance values, when plotted against borehole resistivity for the middle member of the Woodford Shale in the wells, display a rarely reported finding that deep resistivity readings decrease as Ro increases when Ro is greater than 0.90%. This phenomenon may be attributed to that aromatic and resin compounds containing conjugated pi bonds generated within source rocks are more electrically conductive than aliphatic compounds. And aromatic and resin fractions were generated more than aliphatic fraction when source rock maturity further increases beyond oil peak. The finding of the relationship between deep resistivity and Ro may re-investigate the previously found linear relationship between source rock formation and aid to unconventional play exploration.

2020 ◽  
Vol 10 (8) ◽  
pp. 3191-3206
Author(s):  
Olusola J. Ojo ◽  
Ayoola Y. Jimoh ◽  
Juliet C. Umelo ◽  
Samuel O. Akande

Abstract The Patti Formation which consists of sandstone and shale offers the best potential source beds in the Bida Basin. This inland basin is one of the basins currently being tested for hydrocarbon prospectivity in Nigeria. Fresh samples of shale from Agbaja borehole, Ahoko quarry and Geheku road cut were analysed using organic geochemical and palynological techniques to unravel their age, paleoecology, palynofacies and source bed hydrocarbon potential. Palynological data suggest Maastrichtian age for the sediments based on the abundance of microfloral assemblage; Retidiporites magdalenensis, Echitriporites trianguliformis and Buttinia andreevi. Dinocysts belonging to the Spiniferites, Deflandrea and Dinogymnium genera from some of the analysed intervals are indicative of freshwater swamp and normal sea conditions. Palynological evidence further suggests mangrove paleovegetation and humid climate. Relatively high total organic carbon TOC (0.77–8.95 wt%) was obtained for the shales which implies substantial concentration of organic matter in the source beds. Hydrocarbon source rock potential ranges from 0.19 to 0.70 mgHC/g.rock except for a certain source rock interval in the Agbaja borehole with high yield of 25.18 mgHC/g.rock. This interval also presents exceptionally high HI of 274 mgHC/g.TOC and moderate amount of amorphous organic matter. The data suggests that in spite of the favourable organic matter quantity, the thermal maturity is low as indicated by vitrinite reflectance and Tmax (0.46 to 0.48 Ro% and 413 to 475 °C, respectively). The hydrocarbon extracts show abundance of odd number alkanes C27–C33, low sterane/hopane ratio and Pr/Ph > 2. We conclude that the source rocks were terrestrially derived under oxic condition and dominated by type III kerogen. Type II organic matter with oil and gas potential is a possibility in Agbaja area of Bida Basin. Thermal maturity is low and little, or no hydrocarbon has been generated from the source rocks.


2016 ◽  
Author(s):  
Samuel Salufu ◽  
Rita Onolemhemhen ◽  
Sunday Isehunwa

ABSTRACT This paper sought to use information from outcrop sections to characterize the source and reservoir rocks in a basin in order to give indication(s) for hydrocarbon generation potential in a basin in minimizing uncertainty and risk that are allied with exploration and field development of oil and gas, using subsurface data from well logs, well sections, seismic and core. The methods of study includes detailed geological, stratigraphical, geochemical, structural,, petro-graphical, and sedimentological studies of rock units from outcrop sections within two basins; Anambra Basin and Abakaliki Basin were used as case studies. Thirty eight samples of shale were collected from these Basins; geochemical analysis (rockeval) was performed on the samples to determine the total organic content (TOC) and to assess the oil generating window. The results were analyzed using Rock wares, Origin, and Surfer software in order to properly characterize the potential source rock(s) and reservoir rock(s) in the basins, and factor(s) that can favour hydrocarbon traps. The results of the geological, stratigraphical, sedimentological, geochemical, and structural, were used to developed a new model for hydrocarbon generation in the Basins. The result of the geochemical analysis of shale samples from the Anambra Basin shows that the TOC values are ≥ 1wt%, Tmax ≥ 431°C, Vitrinite reflectance values are ≥ 0.6%, and S1+S2 values are > 2.5mg/g for Mamu Formation while shale samples from other formations within Anambra Basin fall out of these ranges. The shale unit in the Mamu Formation is the major source rock for oil generation in the Anambra Basin while others have potential for gas generation with very little oil generation. The shale samples from Abakaliki Basin shows that S1+S2 values range from< 1 – 20mg/g, TOC values range from 0.31-4.55wt%, vitrinite reflectance ranges from 0.41-1.24% and Tmax ranges from423°C – 466°C. This result also shows that there is no source rock for oil generation in Abakaliki Basin; it is either gas or graphite. This observation indicates that all the source rocks within Abakaliki Basin have exceeded petroleum generating stage due to high geothermal heat resulting from deep depth or the shale units have not attained catagenesis stage as a result of S1+S2 values lesser than 2.5mg/g despite TOC values of ≥ 0.5wt% and vitrinite reflectance values of ≥ 0.6%. The novelty of this study is that the study has been able to show that here there is much more oil than the previous authors claimed, and the distribution of this oil and gas in the basins is controlled by two major factors; the pattern of distribution of the materials of the source rock prior to subsidence and during the subsidence period in the basin, and the pattern and the rate of tectonic activities, and heat flow in the basin. If these factors are known, it would help to reduce the uncertainties associated with exploration for oil and gas in the two basins.


Author(s):  
S., R. Muthasyabiha

Geochemical analysis is necessary to enable the optimization of hydrocarbon exploration. In this research, it is used to determine the oil characteristics and the type of source rock candidates that produces hydrocarbon in the “KITKAT” Field and also to understand the quality, quantity and maturity of proven source rocks. The evaluation of source rock was obtained from Rock-Eval Pyrolysis (REP) to determine the hydrocarbon type and analysis of the value of Total Organic Carbon (TOC) was performed to know the quantity of its organic content. Analysis of Tmax value and Vitrinite Reflectance (Ro) was also performed to know the maturity level of the source rock samples. Then the oil characteristics such as the depositional environment of source rock candidate and where the oil sample develops were obtained from pattern matching and fingerprinting analysis of Biomarker data GC/GCMS. Moreover, these data are used to know the correlation of oil to source rock. The result of source rock evaluation shows that the Talangakar Formation (TAF) has all these parameters as a source rock. Organic material from Upper Talangakar Formation (UTAF) comes from kerogen type II/III that is capable of producing oil and gas (Espitalie, 1985) and Lower Talangakar Formation (LTAF) comes from kerogen type III that is capable of producing gas. All intervals of TAF have a quantity value from very good–excellent considerable from the amount of TOC > 1% (Peters and Cassa, 1994). Source rock maturity level (Ro > 0.6) in UTAF is mature–late mature and LTAF is late mature–over mature (Peters and Cassa, 1994). Source rock from UTAF has deposited in the transition environment, and source rock from LTAF has deposited in the terrestrial environment. The correlation of oil to source rock shows that oil sample is positively correlated with the UTAF.


1987 ◽  
Vol 133 ◽  
pp. 141-157
Author(s):  
F.G Christiansen ◽  
H Nøhr-Hansen ◽  
O Nykjær

During the 1985 field season the Cambrian Henson Gletscher Formation in central North Greenland was studied in detail with the aim of evaluating its potential as a hydrocarbon source rock. The formation contains organic rich shale and carbonate mudstone which are considered to be potential source rocks. These are sedimentologically coupled with a sequence of sandstones and coarse carbonates which might be potential reservoir rocks or migration conduits. Most of the rocks exposed on the surface are, however, thermally mature to postrnature with respect to hydrocarbon generation, leaving only few chances of finding trapped oil in the subsurface of the area studied in detail.


2020 ◽  
Vol 17 (3) ◽  
pp. 582-597 ◽  
Author(s):  
Ting Wang ◽  
Dong-Lin Zhang ◽  
Xiao-Yong Yang ◽  
Jing-Qian Xu ◽  
Coffey Matthew ◽  
...  

AbstractThe Woodford–Mississippian “Commingled Production” is a prolific unconventional hydrocarbon play in Oklahoma, USA. The tight reservoirs feature variations in produced fluid chemistry usually explained by different possible source rocks. Such chemical variations are regularly obtained from bulk, molecular, and isotopic characteristics. In this study, we present a new geochemical investigation of gasoline range hydrocarbons, biomarkers, and diamondoids in oils from Mississippian carbonate and Woodford Shale. A set of oil/condensate samples were examined using high-performance gas chromatography and mass spectrometry. The result of the condensates from the Anadarko Basin shows a distinct geochemical fingerprint reflected in light hydrocarbon characterized by heptane star diagrams, convinced by biomarker characteristics and diamantane isomeric distributions. Two possible source rocks were identified, the Woodford Shale and Mississippian mudrocks, with a variable degree of mixing. Thermal maturity based on light hydrocarbon parameters indicates that condensates from the Anadarko Basin are of the highest maturity, followed by “Old” Woodford-sourced oils and central Oklahoma tight oils. These geochemical parameters shed light on petroleum migration within Devonian–Mississippian petroleum systems and mitigate geological risk in exploring and developing petroleum reservoirs.


Geofluids ◽  
2017 ◽  
Vol 2017 ◽  
pp. 1-14 ◽  
Author(s):  
Chunfang Cai ◽  
Chenlu Xu ◽  
Wenxiang He ◽  
Chunming Zhang ◽  
Hongxia Li

The potential parent source rocks except from Upper Permian Dalong Formation (P3d) for Upper Permian and Lower Triassic solid bitumen show high maturity to overmaturity with equivalent vitrinite reflectance (ERo) from 1.7% to 3.1% but have extractable organic matter likely not contaminated by younger source rocks. P3d source rocks were deposited under euxinic environments as indicated by the pyrite δ34S values as light as -34.5‰ and distribution of aryl isoprenoids, which were also detected from the Lower Silurian (S1l) source rock and the solid bitumen in the gas fields in the west not in the east. All the solid bitumen not altered by thermochemical sulfate reduction (TSR) has δ13C and δ34S values similar to part of the P3l kerogens and within the S1l kerogens. Thus, the eastern solid bitumen may have been derived from the P3l kerogens, and the western solid bitumen was likely to have precracking oils from P3l kerogens mixed with the S1l or P3d kerogens. This case-study tentatively shows that δ13C and δ34S values along with biomarkers have the potential to be used for the purpose of solid bitumen and source rock correlation in a rapidly buried basin, although further work should be done to confirm it.


1985 ◽  
Vol 126 ◽  
pp. 117-128
Author(s):  
F.G Christiansen ◽  
H Nøhr-Hansen ◽  
F Rolle ◽  
P Wrang

During the 1984 field season potential hydrocarbon source rocks were studied in central and western North Greenland. Samples from most lithostratigraphic units were collected from Freuchen Land in the north-east to Washington Land in the south-west. Preliminary results from LECO, Rock-Eval and palynofacies analyses suggest that some intervals in the Cambrian shelf sequence and in the Ordovician and Silurian trough sequence have enough organic matter to qualify as source rocks. Most of the trough sequence is, however, thermally postrnature with respect to oil generation and only the Cambrian Brønlund Fjord Group is expected to have been the source of the oil accumulations in the subsurface.


2021 ◽  
Author(s):  
Chong Jiang ◽  
Haiping Huang ◽  
Zheng Li ◽  
Hong Zhang ◽  
Zheng Zhai

Abstract A suite of oils and bitumens from the Eocene Shahejie Formation (Es) in the Dongying Depression, East China was geochemically characterized to illustrate the impact of source input and redox conditions on the distributions of pentacyclic terpanes. The fourth member (Es4) developed under highly reducing, sulfidic hypersaline conditions, while the third member (Es3) formed under dysoxic, brackish to freshwater conditions. Oils derived from Es4 are enriched in C32 homohopanes (C32H), while those from Es3 are prominently enriched in C31 homohopanes (C31H). The C32H/C31H ratio shows positive correlation with homohopane index (HHI), gammacerane index (G/C30H), and negative correlation with pristane/phytane (Pr/Ph) ratio, and can be used to evaluate oxic/anoxic conditions during deposition and diagenesis. High C32H/C31H ratio (> 0.8) is an important characteristic of oils derived from sulfidic, hypersaline anoxic environments, while low values (< 0.8) indicate non-sulfidic, dysoxic conditions. Extremely low C32H/C31H ratios (< 0.4) indicate strong oxic conditions of coal depsoition. Advantages to use C32H/C31H ratio as redox condition proxy compared to the HHI and gammacerane indexes are wider valid maturity range, less sensitive to biodegradation influence and better differentiation of reducing from oxic environments. Preferential cracking of C35-homohopanes leads HHI to be valid in a narrow maturity range before peak oil generation. No C35 homohopane can be reliably detected in the Es4 bitumens when vitrinite reflectance is > 0.75%, which explains the rare occurrence of high HHI values in Es4 source rocks. Gammacerane is thermally more stable and biologically more refractory than C30 hopane, leading G/C30H ratio more sensitive to maturation and biodegradation than C32H/C31H ratio. Meanwhile, both HHI and gammacerane index cannot differentiate level of oxidation. The C32H/C31H ratio can be applied globally as a novel redox proxy in addition to the Dongying Depression.


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