scholarly journals Graphene quantum dots based on maltose as a high yield photocatalyst for efficient photodegradation of imipramine in wastewater samples

2020 ◽  
Vol 18 (2) ◽  
pp. 1531-1540
Author(s):  
Raheleh Hatefi ◽  
Ali Mashinchian-Moradi ◽  
Habibollah Younesi ◽  
Saeed Nojavan
Nanomaterials ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 844 ◽  
Author(s):  
Quanrun Liu ◽  
Jingjie Zhang ◽  
He He ◽  
Guangxu Huang ◽  
Baolin Xing ◽  
...  

Coal tar pitch (CTP), a by-product of coking industry, has a unique molecule structure comprising an aromatic nucleus and several side chains bonding on this graphene-like nucleus, which is very similar to the structure of graphene quantum dots (GQDs). Based on this perception, we develop a facile approach to convert CTP to GQDs only by oxidation with hydrogen peroxide under mild conditions. One to three graphene layers, monodisperse GQDs with a narrow size distribution of 1.7 ± 0.4 nm, are obtained at high yield (more than 80 wt. %) from CTP. The as-produced GQDs are highly soluble and strongly fluorescent in aqueous solution. This simple strategy provides a feasible route towards the commercial synthesis of GQDs for its cheap material source, green reagent, mild condition, and high yield.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Aumber Abbas ◽  
Tanveer A. Tabish ◽  
Steve J. Bull ◽  
Tuti Mariana Lim ◽  
Anh N. Phan

AbstractGraphene quantum dots (GQDs), a novel type of zero-dimensional fluorescent materials, have gained considerable attention owing to their unique optical properties, size and quantum confinement. However, their high cost and low yield remain open challenges for practical applications. In this work, a low cost, green and renewable biomass resource is utilised for the high yield synthesis of GQDs via microwave treatment. The synthesis approach involves oxidative cutting of short range ordered carbon derived from pyrolysis of biomass waste. The GQDs are successfully synthesised with a high yield of over 84%, the highest value reported to date for biomass derived GQDs. As prepared GQDs are highly hydrophilic and exhibit unique excitation independent photoluminescence emission, attributed to their single-emission fluorescence centre. As prepared GQDs are further modified by simple hydrothermal treatment and exhibit pronounced optical properties with a high quantum yield of 0.23. These modified GQDs are used for the highly selective and sensitive sensing of ferric ions (Fe3+). A sensitive sensor is prepared for the selective detection of Fe3+ ions with a detection limit of as low as 2.5 × 10–6 M. The utilisation of renewable resource along with facile microwave treatment paves the way to sustainable, high yield and cost-effective synthesis of GQDs for practical applications.


RSC Advances ◽  
2014 ◽  
Vol 4 (91) ◽  
pp. 50141-50144 ◽  
Author(s):  
J. Gu ◽  
M. J. Hu ◽  
Q. Q. Guo ◽  
Z. F. Ding ◽  
X. L. Sun ◽  
...  

The obtained GQDs have high fluorescent quantum yield (FL QY = 44.3%) and excitation-independent photoluminescence emission performance.


2012 ◽  
Vol 22 (18) ◽  
pp. 8764 ◽  
Author(s):  
Yongqiang Dong ◽  
Congqiang Chen ◽  
Xinting Zheng ◽  
Lili Gao ◽  
Zhiming Cui ◽  
...  

2020 ◽  
Vol 44 (26) ◽  
pp. 11085-11091 ◽  
Author(s):  
Arvind Singh ◽  
Sumeet Kumar ◽  
Animesh K. Ojha

In this article, charcoal is used as a new raw material for the synthesis of high yield graphene quantum dots (GQDs) for supercapacitor application.


Small ◽  
2013 ◽  
Vol 10 (5) ◽  
pp. 866-870 ◽  
Author(s):  
Yonghun Shin ◽  
Junghyun Lee ◽  
Junghee Yang ◽  
Jintaek Park ◽  
Keunsik Lee ◽  
...  

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
M. Sajjad ◽  
V. Makarov ◽  
M. S. Sultan ◽  
W. M. Jadwisienczak ◽  
B. R. Weiner ◽  
...  

The combination of nanomaterial graphene quantum dots (GQDs) with magnetic nanoparticles offers a unique set of optical and magnetic properties for future energy and medical applications. We report on the synthesis and engineering of GQDs and iron oxide (Fe3O4) nanocomposites (NCs) by using a pulsed laser discharge technique. High-resolution transmission electron microscopy (HRTEM) images showed a high yield of pure GQDs with 2–10 nm diameter. The hexagonal structures and lattice fringes associated with the C–C bond in GQDs were clearly identifiable. The structural and optical changes in GQDs and GQDs-Fe3O4 NC samples induced by UV light were investigated by the absorption and emission spectroscopy over the deep UV–visible spectral range. The photoluminescence spectra have shown subband π→π∗ transitions in GQDs-Fe3O4 NC. Magnetic properties of the GQDs-Fe3O4 NC samples have shown room temperature ferromagnetism induced by pure Fe3O4 nanoparticles and from the substantial spin polarized edges of GQD nanoparticles. It is concluded that the observed optical and magnetic properties could be further tailored in the studied nanocomposites for prospective medical applications.


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