scholarly journals Occurrence and removal characteristics of phthalate esters from bottled drinking water using silver modified roasted date pits

2021 ◽  
Author(s):  
Fedae A. Alhaddad ◽  
Mohammed Abu-Dieyeh ◽  
Dana Da’ana ◽  
Murad Helaleh ◽  
Mohammad A. Al-Ghouti
Keyword(s):  
Drinking Water ◽  
Water Samples ◽  
Storage Temperature ◽  
Phthalate Esters ◽  
Mass Spectrometry Analysis ◽  
Bet Surface Area ◽  
Gas Chromatography Mass Spectrometry ◽  
Batch Adsorption ◽  
Bottled Drinking Water ◽  
Date Pits

Abstract Background This paper aims to investigate the occurrence and removal characteristics of phthalate esters from bottled drinking water using silver modified roasted date pits. Three adsorbents, namely roasted date pits (RODP), silver-modified roasted date pits (S-RODP), and activated carbon (AC) were used to investigate their adsorption characterizations in removing dimethyl phthalate (DMP), diethyl phthalate (DEP), dibutyl phthalate (DBP), butyl benzyl phthalate (BBP), di-2-ethylhexyl phthalate (DEHP), and di-n-octyl phthalate (DNOP) from the collected bottle water samples. Methods The occurrences of the phthalate esters in the collected bottled water samples were carried out at different temperatures (30, 50, and 60 °C), and analyzed using gas chromatography-mass spectrometry analysis - selected ion monitoring. Batch adsorption isotherms were used to study and establish the efficiency of such adsorbents in removing phthalate esters, in which they describe the adsorbent-adsorbate interaction systems. Adsorption efficiency of the various adsorbents was investigated by using different adsorbent masses (0.05 g, 0.10 g, and 0.15 g) and temperature (30 °C, 50 °C, and 60 °C). Different physical and chemical characterizations were studied using scanning electron microscopy (SEM), Fourier transform infrared (FTIR), Brunauer-Emmett-Teller (BET) surface area, pore radius, and pore volume. Results The results indicated that the most abundant phthalate esters were DMP followed by DEP under 30 °C; however, DNOP was not detected in any of the tested water samples, except for one sample under 30 °C with a concentration of 0.031 μg/mL. The obtained results showed that phthalate esters leaching to the bottled drinking water were affected by storage temperature. The phthalate esters levels were increased with increasing the temperature to 60 °C. It was concluded that the ability of S-RODP for the adsorption of phthalate esters was better than the removal percentage obtained by AC and RODP. The removal percentage was increased from 90 to 99% by increasing the temperature from 30 to 50 °C and then decreased to 92.3% at 60 °C. Conclusion RODP was successfully used as an effective adsorbent for phthalate esters removal from drinking water. However, S-RODP has the highest removal abilities than other adsorbents due to the newly formed functional groups on its surface.

scholarly journals The Assessment of the Sewage and Sludge Contamination by Phthalate Acid Esters (PAEs) in Eastern Europe Countries

2021 ◽  
Vol 13 (2) ◽  
pp. 529
Author(s):  
Olga Anne ◽  
Tatjana Paulauskiene
Keyword(s):  
Water Samples ◽  
Raw Materials ◽  
Phthalate Esters ◽  
Gas Chromatography Mass Spectrometry ◽  
Sediment Samples ◽  
Toxicological Effects ◽  
Sources Of Pollution ◽  
Eastern European Countries ◽  
Acid Esters ◽  
Phthalate Acid Esters

Phthalate acid esters (PAEs) are widely used as raw materials for industries that are well known for their environmental contamination and toxicological effects as “endocrine disruptors”. The determining of PAE contamination was based on analysis of dimethyl phthalate (DMP), diethyl phthalate (DEP), dipropyl phthalate (DPP), dibutyl phthalate (DBP), diisobutyl phthalate (DiBP), dicyclohexyl phthalate (DCHP) and di(2-ethylhexyl) phthalate (DEHP) in wastewater and sediment samples collected from city sewer systems of Lithuania and Poland, and Denmark for comparison. The potential PAE sources as well as their concentrations in the wastewater were analyzed and discussed. The intention of the study was to determine the level and key sources of pollution by phthalates in some Eastern European countries and to reveal the successful managerial actions to minimize PAEs taken by Denmark. Water and sludge samples were collected in 2019–2020 and analyzed by gas chromatography-mass spectrometry. The highest contamination with phthalates in Lithuania can be attributed to DEHP: up to 63% of total PAEs in water samples and up to 94% of total PAEs in sludge samples, which are primarily used as additive compounds to plastics but do not react with them and are gradually released into the environment. However, in water samples in Poland, the highest concentration belonged to DMP—up to 210 μg/L, while the share of DEHP reached 15 μg/L. The concentrations of priority phthalate esters in the water samples reached up to 159 μg/L (DEHP) in Lithuania and up to 1.2 μg/L (DEHP) in Denmark. The biggest DEHP concentrations obtained in the sediment samples were 95 mg/kg in Lithuania and up to 6.6 mg/kg in Denmark. The dominant compounds of PAEs in water samples of Lithuania were DEHP > DEP > DiBP > DBP > DMP. DPP and DCHP concentrations were less than 0.05 μg/L. However, the distribution of PAEs in the water samples from Poland was as follows: DMP > DEHP > DEP > DBP, and DiBP, as well as DPP and DCHP, concentrations were less than 0.05 μg/L. Further studies are recommended for adequate monitoring of phthalates in wastewater and sludge in order to reduce or/and predict phthalates’ potential risk to hydrobiots and human health.

PROBLEMS OF QUALITY AND SAFETY OF BOTTLED DRINKING WATER

2018 ◽  
Author(s):  
Л.И. АМБАРЦУМЯН ◽  
Е.Н. ГУБА ◽  
М.В. ГУСЕВА ◽  
С.Н. ДИЯНОВА ◽  
В.В. ИЛЛАРИОНОВА
Keyword(s):  
Drinking Water ◽  
Chemical Composition ◽  
Water Samples ◽  
Quality And Safety ◽  
Testing Laboratory ◽  
Bottled Drinking Water ◽  
Microelement Composition ◽  
Microbiological Indicators

Проведены исследования качества 12 образцов питьевой бутилированной воды в условиях аккредитованной испытательной лаборатории. Исследование информативности маркировки образцов воды выявило, что не все производители выполняют требования ТР ТС 022/2011. Дана оценка органолептических, физико-химических и микробиологических показателей питьевой воды. Определены критерии безвредности химического состава образцов. Исследован макро- и микроэлементный состав. Выявлена необходимость повышения степени ответственности производителей при формировании качества. The quality of 12 samples of bottled drinking water was studied in an accredited testing laboratory. The study of informative labeling of water samples revealed that not all manufacturers fulfill the requirements of TR TS 022/2011. The evaluation of organoleptic, physicochemical and microbiological indicators of drinking water is given. Criteria of harmlessness of the chemical composition of samples are defined. It is investigated macro- and microelement composition of drinking water. The necessity to increase the degree of responsibility of producers in the formation of quality is revealed.

scholarly journals Study on Speciation of As, Cr, and Sb in Bottled Flavored Drinking Water Samples Using Advanced Analytical Techniques IEC/SEC-HPLC/ICP-DRC-MS and ESI-MS/MS

Molecules ◽  
2019 ◽  
Vol 24 (4) ◽  
pp. 668 ◽  
Author(s):  
Wiktor Lorenc ◽  
Barbara Markiewicz ◽  
Dariusz Kruszka ◽  
Piotr Kachlicki ◽  
Danuta Barałkiewicz
Keyword(s):  
Drinking Water ◽  
Water Samples ◽  
Arsenic Speciation ◽  
Analytical Techniques ◽  
Speciation Analysis ◽  
Size Exclusion ◽  
Sample Type ◽  
Esi Ms ◽  
Bottled Drinking Water ◽  
Drinking Water Samples

The main aim of the research was to develop a complementary analytical approach consisting of bespoke speciation analysis and non-targeted speciation analysis of As, Sb, and Cr in flavored bottled drinking water samples using HPLC/ICP-DRC-MS and ESI-MS/MS. The scope of two previously developed analytical procedures, (1) multielemental speciation procedure for AsIII, AsV, CrVI, SbIII, and SbV analysis and (2) arsenic speciation procedure for AsB, AsIII, DMA, MMA, and AsV quantification, was extended to the analysis of a new sample type in terms of bespoke speciation analysis. As for the non-targeted speciation, analysis size exclusion chromatography was used with ICP-MS and a complementary technique, ESI-MS/MS, was used for the organic species of As, Sb, and Cr screening. Full validation of procedures 1 and 2 was conducted. Procedure 1 and 2 were characterized with precision values in the range from 2.5% to 5.5% and from 3.6% to 7.2%, respectively. Obtained recoveries ranged from 97% to 106% and from 99% to 106% for procedures 1 and 2, respectively. Expanded uncertainties calculated for procedures 1 and 2 ranged from 6.1% to 9.4% and from 7.4% to 9.9%, respectively. The applicability of the proposed procedures was tested on bottled drinking water samples. Results for the real samples in procedure 1 were in the range from 0.286 ± 0.027 [μg L−1] to 0.414 ± 0.039 [μg L−1] for AsIII, from 0.900 ± 0.083 [μg L−1] to 3.26 ± 0.30 [μg L−1] for AsV, and from 0.201 ± 0.012 [μg L−1] to 0.524 ± 0.032 [μg L−1] for SbV. CrVI and SbIII were not detected in any sample. As for procedure 2, results were in the range from 0.0541 ± 0.0053 [μg L−1] to 0.554 ± 0.054 [μg L−1] for AsB. Results for AsIII and AsV obtained with procedure 2 were in good accordance with results obtained with procedure 1. DMA and MMA were not detected in any sample.

scholarly journals Occurrence and distribution of pharmaceuticals in raw, finished, and drinking water from seven large river basins in China

2019 ◽  
Vol 17 (3) ◽  
pp. 477-489 ◽  
Author(s):  
Jia Lv ◽  
Lan Zhang ◽  
Yongyan Chen ◽  
Bixiong Ye ◽  
Jiayi Han ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Water Samples ◽  
Solid Phase ◽  
Tap Water ◽  
River Basins ◽  
Large River ◽  
Mass Spectrometry Analysis ◽  
Detection Rates ◽  
Large River Basins

Abstract The occurrence of pharmaceuticals in the drinking water is a growing concern in China. In this study, we determined the concentration and distribution of 59 selected pharmaceuticals in raw, finished, and tap water samples from 79 drinking water treatment plants (DWTPs) in 15 cities, encompassing seven large river basins in China, using solid-phase extraction pretreatment and ultra-high-performance liquid chromatography–tandem mass spectrometry analysis. Forty-seven pharmaceuticals were detected in raw water samples, with detection rates of 1.27–96.20% and average concentrations of 0.09–128.87 ng/L. Forty-three pharmaceuticals were detected in finished water samples, with detection rates of 1.27–96.20% and average concentrations of 0.07–59.17 ng/L. Forty-two pharmaceuticals were detected in tap water samples, with detection rates of 1.27–94.94% and average concentrations of 0.07–58.43 ng/L. Purification methods implemented by DWTPs are capable of removing some pharmaceuticals from water treatment systems; however, low concentrations of pharmaceuticals were detected in drinking water, raising concerns about the possible human health implications of long-term exposure to low-dose pharmaceuticals. The detection and quantification of pharmaceuticals in municipal water samples presented in this study represent the most extensive analysis of commonly used pharmaceuticals and personal care products located in Chinese river basins.

scholarly journals Analysis of phthalate esters contamination in drinking water samples

2012 ◽  
Vol 11 (96) ◽  
pp. 16263-16269 ◽  
Author(s):  
Kanchanamayoon W ◽  
Prapatpong P ◽  
Chumwangwapee S ◽  
Chaithongrat S
Keyword(s):  
Drinking Water ◽  
Water Samples ◽  
Phthalate Esters ◽  
Drinking Water Samples

Comparison of two selective methods for determination of geosmin (1,2,7,7-tetramethyl-2-norborneol) and 2-MIB (2-methylisoborneol) in drinking and raw water samples by capillary gas chromatography - mass spectrometry

2010 ◽  
Vol 45 (4) ◽  
pp. 491-497 ◽  
Author(s):  
Linda Lunga Sibali ◽  
Carl Schoeman ◽  
Jabulile Selina Morobi ◽  
Barnard Saenet Molalatladi
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Drinking Water ◽  
Water Samples ◽  
Solid Phase ◽  
Gas Chromatography Mass Spectrometry ◽  
Raw Water ◽  
Preparation Methods ◽  
Chromatography Mass Spectrometry ◽  
Concentration Levels

Abstract Two sample preparation methods were introduced and compared in this study to establish a simple, rapid, sensitive and selective method of analysis for geosmin and 2-MIB in raw and drinking water samples. Geosmin and 2-MIB are major organic pollutants responsible for undesirable taste and odour in aqueous matrices. Thus, there is a need to continue monitoring these compounds since they occur at very low levels (ng/L) in our water systems. Purge and trap (P/T) and solid phase extraction(SPE) methods were evaluated and optimised for separation of these compounds. Mean percentage recoveries obtained in spiked distilled Milli-Q water (18.2 Ω) for 2-MIB and geosmin ranged from 90.1 ± 2.32 (geosmin) to 97.3 ± 3.34 (2-MIB) and from 78.5 ± 4.82 (geosmin) to 87.1 ± 1.02 (2-MIB) for SPE and P/T respectively. Concentration levels obtained in drinking water were between not detected (ND)-6.05 ng/L whereas in raw water samples concentration levels ranged from less than 1 to 371 ng/L. Gas chromatography-mass spectrometry (GC-MS) was used for identification and quantification of target compounds in this study.

scholarly journals Quality Assessment of Sachet and Bottled Water in Ogbomoso Metropolis, Nigeria

2019 ◽  
pp. 1-15
Author(s):  
Augustine I. Airaodion ◽  
Edith O. Airaodion ◽  
Etinosa U. Osemwowa ◽  
Emmanuel O. Ogbuagu ◽  
Uloaku Ogbuagu
Keyword(s):  
Drinking Water ◽  
Water Supply ◽  
Mineral Composition ◽  
Water Samples ◽  
Urban Areas ◽  
Bottled Water ◽  
Bottled Drinking Water ◽  
Physical Chemical ◽  
Quality Water ◽  
The Government

Background: Access to potable water has become a difficult task in many countries of the world including Nigeria. In Nigeria, the government is trying her best to make water supply available to the masses but till now this vision has never been accomplished. If those living in urban areas could not have access to portable water supply by the government, what is the fate of the people living in rural areas? This has led to increased usage of sachet and bottled water as portable drinking water. Aim: The aim of this study was to investigate the quality of sachet and bottled water produced and/or sold in Ogbomoso metropolis, Nigeria. Place and Duration of Study: This research was carried out in Ogbomoso and Ibadan both in Oyo State Nigeria between November 2018 and February, 2019. Methodology: Twenty sachet and five bottled drinking water brands; making a total of 25 brands from different manufacturers were used for this study. They were purchased randomly from local markets, shops and street vendors within Ogbomoso metropolis. They were clearly marked for easy identification, and transported to the Quality Assurance Laboratory of Water Corporation, Eleyele, Ibadan for immediate analysis. The samples were examined physically and information on the packages were recorded. Each product was carefully opened to avoid contamination. The physical, chemical and bacteriological qualities as well as the mineral composition of all samples were analyzed using standard methods and results were compared with the recommended WHO/NIS guidelines for quality water. Results: Physical examination indicated that all the sampled water were registered with NAFDAC but 50% of the sachet water had no manufacturing and expiry dates. The results of physical, chemical and bacteriological qualities as well as the mineral composition of sachet and bottled drinking water analyzed showed that 90% of the values were within the guideline of WHO/NIS for quality water. Conclusion: Though, the average temperature values of both the sachet and bottled drinking water samples were significantly above the WHO/NIS standard, it did not have any effect on their microbiological quality properties. Total coliforms, faecal coliforms and enterococci bacteria       that principally characterize drinking water quality were not present in any of the water       samples. Generally, the results obtained in this study indicated that sachet and bottled drinking water produced and/or sold in Ogbomoso metropolis were of good quality and hygienic for consumption.

scholarly journals Icp-Ms Determination of Trace Metals in Drinking Water Sources in Jazan Area, Saudi Arabia

2017 ◽  
Vol 12 (1) ◽  
pp. 06-17 ◽  
Author(s):  
Mohamed Albratty ◽  
Ismail Arbab ◽  
Hassan Alhazmi ◽  
Ibraheem Attafi ◽  
Abdul Al-Rajab
Keyword(s):  
Water Quality ◽  
Drinking Water ◽  
Saudi Arabia ◽  
Water Samples ◽  
Research Team ◽  
Tap Water ◽  
Drinking Water Quality ◽  
World Health ◽  
Bottled Drinking Water ◽  
Icp Ms

Requisite reference facts about essential elements in treated and plastic bottled drinking water is usually mentioned on the products. However, more information is sometime crucial regarding trace elements in treated, bottled and other sources of drinking water such as tap water to evaluate their quality. This study is aimed to evaluate drinking water quality in the main governorates (Jazan, Sabya and Abu Arish) of Jazan province located in the South-Western region of Kingdom of Saudi Arabia. This is the first such study carried out in Jazan city so that the research team can come out with valuable recommendations in the issue. The research team has collected a sum of 68 water samples from different sources comprising hospitals (treated tap water), stations for drinking water treatment (large blue bottles of drinking water) and bottled drinking water (purchased from local markets). Using inductively coupled plasma-mass spectrometry (ICP-MS), the concentrations of 20 elements were determined. The physiochemical parameters of water samples were measured. All parameters were within the recommended limits of the World Health Organization (WHO, 2011) and Gulf Cooperation Council Standardization Organization (GSO, 2008). Trace and major elements were found to be below the standard guideline values , except for uranium in some tap water samples. This preliminary study will significantly improve the awareness and knowledge among the society about the drinking water quality in Jazan area.

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