Heterogeneous catalysis of calcium oxide used for transesterification of soybean oil with refluxing methanol

2009 ◽  
Vol 355 (1-2) ◽  
pp. 94-99 ◽  
Author(s):  
Masato Kouzu ◽  
Shin-ya Yamanaka ◽  
Jyu-suke Hidaka ◽  
Michito Tsunomori
Energies ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3950
Author(s):  
Hoora Mazaheri ◽  
Hwai Chyuan Ong ◽  
Zeynab Amini ◽  
Haji Hassan Masjuki ◽  
M. Mofijur ◽  
...  

Biodiesel is a clean, renewable, liquid fuel that can be used in existing diesel engines without modification as pure or blend. Transesterification (the primary process for biodiesel generation) via heterogeneous catalysis using low-cost waste feedstocks for catalyst synthesis improves the economics of biodiesel production. Heterogeneous catalysts are preferred for the industrial generation of biodiesel due to their robustness and low costs due to the easy separation and relatively higher reusability. Calcium oxides found in abundance in nature, e.g., in seashells and eggshells, are promising candidates for the synthesis of heterogeneous catalysts. However, process improvements are required to design productive calcium oxide-based catalysts at an industrial scale. The current work presents an overview of the biodiesel production advancements using calcium oxide-based catalysts (e.g., pure, supported, and mixed with metal oxides). The review discusses different factors involved in the synthesis of calcium oxide-based catalysts, and the effect of reaction parameters on the biodiesel yield of calcium oxide-based catalysis are studied. Further, the common reactor designs used for the heterogeneous catalysis using calcium oxide-based catalysts are explained. Moreover, the catalytic activity mechanism, challenges and prospects of the application of calcium oxide-based catalysts in biodiesel generation are discussed. The study of calcium oxide-based catalyst should continue to be evaluated for the potential of their application in the commercial sector as they remain the pivotal goal of these studies.


Author(s):  
Istadi Istadi ◽  
Udin Mabruro ◽  
Bintang Ayu Kalimantini ◽  
Luqman Buchori ◽  
Didi Dwi Anggoro

<p>This paper was purposed for testing reusability and stability of calcium oxide-based catalyst (K<sub>2</sub>O/CaO-ZnO) over transesterification reaction of soybean oil with methanol to produce biodiesel. The K<sub>2</sub>O/CaO-ZnO catalyst was synthesized by co-precipitation method of calcium and zinc nitrates followed by impregnation of potassium nitrate. The fresh and used catalysts were tested after regeneration. The catalysts were characterized by Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), and BET Surface Area in order to compare the catalyst structure between the fresh and used catalysts. The catalyst testing in transesterification proses was carried out at following operating conditions, i.e. catalyst weight of 6 wt.%, oil to methanol mole ratio of 1:15, and temperature of 60 oC. In addition, metal oxide leaching of K<sub>2</sub>O/CaO-ZnO catalyst during reaction was also tested. From the results, the catalysts exhibited high catalytic activity (80% fatty acid methyl ester (FAME) yield after three-cycles of usage) and acceptable reusability after regeneration. The catalyst also showed acceptable stability of catalytic activity, even after three-cycles of usage. Copyright © 2016 BCREC GROUP. All rights reserved</p><p><em>Received: 10<sup>th</sup> November 2015; Revised: 16<sup>th</sup> January 2016; Accepted: 16<sup>th</sup> January 2016</em></p><p><strong>How to Cite</strong>: Istadi, I., Mabruro, U., Kalimantini, B.A.,  Buchori, L., Anggoro, D.D. (2016). Reusability and Stability Tests of Calcium Oxide Based Catalyst (K<sub>2</sub>O/CaO-ZnO) for Transesterification of Soybean Oil to Biodiesel. <em>Bulletin of Chemical Reaction Engineering &amp; Catalysis</em>, 11 (1): 34-39. (doi:10.9767/bcrec.11.1.413.34-39)</p><p><strong>Permalink/DOI</strong>: <a href="http://dx.doi.org/10.9767/bcrec.11.1.413.34-39">http://dx.doi.org/10.9767/bcrec.11.1.413.34-39</a></p><p> </p>


2009 ◽  
Vol 90 (7-8) ◽  
pp. 922-925 ◽  
Author(s):  
C. Samart ◽  
P. Sreetongkittikul ◽  
C. Sookman

1949 ◽  
Vol 26 (9) ◽  
pp. 488-492 ◽  
Author(s):  
A. J. Lewis ◽  
J. C. Cowan ◽  
N. C. Schieltz
Keyword(s):  

2018 ◽  
Vol 7 (4) ◽  
pp. 542-548
Author(s):  
Ayoola A. Ayodeji ◽  
Igho E. Blessing ◽  
Babalola Rasheed ◽  
Ojewumi E. Modupe ◽  
Ogunbiyi Ajibola ◽  
...  
Keyword(s):  

2008 ◽  
Vol 334 (1-2) ◽  
pp. 357-365 ◽  
Author(s):  
Masato Kouzu ◽  
Takekazu Kasuno ◽  
Masahiko Tajika ◽  
Shinya Yamanaka ◽  
Jusuke Hidaka

Author(s):  
Siti Norhafiza Mohd Khazaai ◽  
Nurul Aina Nasriqah Ma’arof ◽  
Nurul Hajar Embong ◽  
Mohd Hasbi Ab. Rahim ◽  
Gaanty Pragas Maniam

Nowadays due to the depletion of non-renewable energy resources, production of green material from domestic wastes has played an important role. The waste of banana peel impregnated with calcium oxide (CaO) from eggshell had successfully been used as a low-cost catalyst to transesterify soybean oil to produce methyl ester. The catalytic actions from potassium and calcium oxide content in calcined banana peel (700°C) and eggshell (900°C) discover through FT-IR, XRD, and SEM. Methyl ester conversion can be obtained at 76.87 wt.% with the optimal condition of 7 wt.% of catalyst amount, methanol/oil mass ratio, 9:1; and the reaction temperature, 65 °C within 2 h reaction time.


Energies ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4670 ◽  
Author(s):  
Samuel Santos ◽  
Luís Nobre ◽  
João Gomes ◽  
Jaime Puna ◽  
Rosa Quinta-Ferreira ◽  
...  

In this study, micro-structured calcium oxide obtained from the calcination (850 °C for 3 h) of Gallus gallus domesticus (chicken) eggshells was used as a catalyst in the transesterification of soybean oil. This catalyst was characterized by Scanning Electron Spectroscopy (SEM) methods. The structure of the obtained CaO showed several agglomerates of white granular solids with a non-regular and unsymmetrical shape. In terms of calcium oxide catalytic activity, three different catalyst loadings (1%wt, 3%wt, and 5%wt) were tested for the same reaction conditions, resulting in transesterification yields of 77.27%wt, 84.53%wt, and 85.83%wt respectively. The results were compared to the current literature, and whilst they were lower, they were promising, allowing us to conclude that the tendency of yield improvement for this reaction, when the size range of catalyst particles is to be reduced to a nano scale, can be verified.


Fuel ◽  
2011 ◽  
Vol 90 (5) ◽  
pp. 1963-1967 ◽  
Author(s):  
Ming-Chien Hsiao ◽  
Chin-Chiuan Lin ◽  
Yung-Hung Chang

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