scholarly journals Scanning different Ni-noble metal (Pt, Pd, Ru) bimetallic nanoparticles supported on carbon nanofibers for one-pot cellobiose conversion

2019 ◽  
Vol 585 ◽  
pp. 117182 ◽  
Author(s):  
E. Frecha ◽  
D. Torres ◽  
A. Pueyo ◽  
I. Suelves ◽  
J.L. Pinilla
Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2206
Author(s):  
Gaoqian Yuan ◽  
Gen Zhang ◽  
Kezhuo Li ◽  
Faliang Li ◽  
Yunbo Cao ◽  
...  

Loading a noble metal on Bi4Ti3O12 could enable the formation of the Schottky barrier at the interface between the former and the latter, which causes electrons to be trapped and inhibits the recombination of photoelectrons and photoholes. In this paper, AgPt/Bi4Ti3O12 composite photocatalysts were prepared using the photoreduction method, and the effects of the type and content of noble metal on the photocatalytic performance of the catalysts were investigated. The photocatalytic degradation of rhodamine B (RhB) showed that the loading of AgPt bimetallic nanoparticles significantly improved the catalytic performance of Bi4Ti3O12. When 0.10 wt% noble metal was loaded, the degradation rate for RhB of Ag0.7Pt0.3/Bi4Ti3O12 was 0.027 min−1, which was respectively about 2, 1.7 and 3.7 times as that of Ag/Bi4Ti3O12, Pt/Bi3Ti4O12 and Bi4Ti3O12. The reasons may be attributed as follows: (i) the utilization of visible light was enhanced due to the surface plasmon resonance effect of Ag and Pt in the visible region; (ii) Ag nanoparticles mainly acted as electron acceptors to restrain the recombination of photogenerated electron-hole pairs under visible light irradiation; and (iii) Pt nanoparticles acted as electron cocatalysts to further suppress the recombination of photogenerated electron-hole pairs. The photocatalytic performance of Ag0.7Pt0.3/Bi4Ti3O12 was superior to that of Ag/Bi4Ti3O12 and Pt/Bi3Ti4O12 owing to the synergistic effect between Ag and Pt nanoparticles.


2022 ◽  
Vol 573 ◽  
pp. 151528
Author(s):  
Ke Huan ◽  
Yuanyuan Li ◽  
Dongmei Deng ◽  
Huan Wang ◽  
Dejia Wang ◽  
...  

2018 ◽  
Vol 6 (7) ◽  
pp. 2895-2899 ◽  
Author(s):  
Shuangshuang Kai ◽  
Baojuan Xi ◽  
Xiaolei Liu ◽  
Lin Ju ◽  
Peng Wang ◽  
...  

An innovative CdS/ZnS-RGO hybrid is synthesizedviaan one-pot hydrothermal method. The further introduction of Au nanoparticles enables the composite with the merits of heterostructured semiconductor/semiconductor junction benefiting the hole transfer, as well as graphene and noble metal favorable for electron transportation.


Molecules ◽  
2019 ◽  
Vol 24 (7) ◽  
pp. 1241 ◽  
Author(s):  
Jikuan Qiu ◽  
Yue Zhao ◽  
Yuling Zhao ◽  
Huiyong Wang ◽  
Zhiyong Li ◽  
...  

Recently, the efficient chemical fixation of carbon dioxide (CO2) into high value chemicals without using noble metal catalysts has become extremely appealing from the viewpoint of sustainable chemistry. In this work, a one-pot three component reaction of propargylic alcohols, anines and CO2 that can proceed in an atom economy and environmentally benign manner by combination of CuI and tetrabutylphosphonium imidazol ([P4444][Im]) as a catalyst was described. Catalysis studies indicate that this catalytic system is an effective catalyst for the conversion of CO2 into oxazolidinones at room temperature and ambient pressure without any solvent. The results provide a useful way to design novel noble metal-free catalyst systems for the transformation of CO2 into other valuable compounds.


2015 ◽  
Vol 51 (33) ◽  
pp. 7164-7167 ◽  
Author(s):  
Qiujun Lu ◽  
Jianhui Deng ◽  
Yuxin Hou ◽  
Haiyan Wang ◽  
Haitao Li ◽  
...  

Hydro-rich C-dots were used as both the reducing and stabilizing agent in the preparation of noble metal nanoparticles (AuNPs, AgNPs and Au@AgNPs) for the detection of glucose.


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