Surface activation of polyethylene with an argon atmospheric pressure plasma jet: Influence of applied power and flow rate

2015 ◽  
Vol 328 ◽  
pp. 269-278 ◽  
Author(s):  
A. Van Deynse ◽  
P. Cools ◽  
C. Leys ◽  
N. De Geyter ◽  
R. Morent
Plasma ◽  
2019 ◽  
Vol 2 (3) ◽  
pp. 283-293 ◽  
Author(s):  
Bolouki ◽  
Hsieh ◽  
Li ◽  
Yang

A helium-based atmospheric pressure plasma jet (APPJ) with various flow rates of argon gas as a variable working gas was characterized by utilizing optical emission spectroscopy (OES) alongside the plasma jet. The spectroscopic characterization was performed through plasma exposure in direct and indirect interaction with and without de-ionized (DI) water. The electron density and electron temperature, which were estimated by Stark broadening of atomic hydrogen (486.1 nm) and the Boltzmann plot, were investigated as a function of the flow rate of argon gas. The spectra obtained by OES indicate that the hydroxyl concentrations reached a maximum value in the case of direct interaction with DI water as well as upstream of the plasma jet for all cases. The relative intensities of hydroxyl were optimized by changing the flow rate of argon gas.


Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 87 ◽  
Author(s):  
Alenka Vesel ◽  
Rok Zaplotnik ◽  
Gregor Primc ◽  
Miran Mozetič

A useful technique for pre-treatment of polymers for improved biocompatibility is surface activation. A method for achieving optimal wettability at a minimal thermal load and unwanted modifications of the polymer properties is elaborated in this paper. Samples of polyethylene terephthalate polymer were exposed to an atmospheric-pressure plasma jet created by a high-impedance low-frequency discharge in wet argon. Different treatment times and distances from the end of the glowing discharge enabled detailed investigation of the evolution of surface activation. A rather fast saturation of the surface wettability over the area of the order of cm2 was observed upon direct treatment with the glowing discharge. At a distance of few mm from the glowing discharge, the activation was already two orders of magnitude lower. Further increase of the distance resulted in negligible surface effects. In the cases of a rapid activation, very sharp interphase between the activated and unaffected surface was observed and explained by peculiarities of high-impedance discharges sustained in argon with the presence of impurities of water vapor. Results obtained by X-ray photoelectron spectroscopy confirmed that the activation was a consequence of functionalization with oxygen functional groups.


2017 ◽  
Vol 53 (50) ◽  
pp. 6704-6707 ◽  
Author(s):  
Farkfun Duriyasart ◽  
Masataka Ohtani ◽  
Jun-Seok Oh ◽  
Akimitsu Hatta ◽  
Kazuya Kobiro

Facile treatment of mesoporous nanomaterials by a helium APPJ under optimum conditions activates the surface of the materials by removing contaminants without damaging their morphologies and surface properties.


Plasma ◽  
2022 ◽  
Vol 5 (1) ◽  
pp. 44-59
Author(s):  
Gerrit Wulf ◽  
Bernd Mayer ◽  
Uwe Lommatzsch

Plasma co-polymers (co-p) were deposited with an atmospheric pressure plasma jet (APPJ) using a precursor mixture containing hexamethyldisiloxane (HMDSO) and limonene. A coating with fragments from both precursors and with siloxane, carbonyl and nitrogen functional groups was deposited. The flow rate of limonene was found to be an important parameter for plasma co-polymerization to tune the formation and structure of the functional groups. The FTIR and XPS analysis indicates that with increasing flow rate of limonene a higher proportion of carbon is bound to silicon. This is related to a stronger incorporation of fragments from limonene into the siloxane network and a weaker fragmentation of HMDSO. The formation mechanism of the nitroxide and carboxyl groups can be mainly differentiated into in-plasma and post-plasma reactions, respectively.


Micromachines ◽  
2021 ◽  
Vol 12 (6) ◽  
pp. 683
Author(s):  
Huiliang Jin ◽  
Caixue Tang ◽  
Haibo Li ◽  
Yuanhang Zhang ◽  
Yaguo Li

The continuous phase plate (CPP) is the vital diffractive optical element involved in laser beam shaping and smoothing in high-power laser systems. The high gradients, small spatial periods, and complex features make it difficult to achieve high accuracy when manufacturing such systems. A high-accuracy and high-efficiency surface topography manufacturing method for CPP is presented in this paper. The atmospheric pressure plasma jet (APPJ) system is presented and the removal characteristics are studied to obtain the optimal processing parameters. An optimized iterative algorithm based on the dwell point matrix and a fast Fourier transform (FFT) is proposed to improve the accuracy and efficiency in the dwell time calculation process. A 120 mm × 120 mm CPP surface topography with a 1326.2 nm peak-to-valley (PV) value is fabricated with four iteration steps after approximately 1.6 h of plasma processing. The residual figure error between the prescribed surface topography and plasma-processed surface topography is 28.08 nm root mean square (RMS). The far-field distribution characteristic of the plasma-fabricated surface is analyzed, for which the energy radius deviation is 11 μm at 90% encircled energy. The experimental results demonstrates the potential of the APPJ approach for the manufacturing of complex surface topographies.


2019 ◽  
Vol 675 ◽  
pp. 34-42 ◽  
Author(s):  
Md. Mokter Hossain ◽  
Quang Hung Trinh ◽  
Duc Ba Nguyen ◽  
M.S.P. Sudhakaran ◽  
Young Sun Mok

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