Activated carbons from waste biomass: An alternative use for biodiesel production solid residues

2009 ◽  
Vol 100 (5) ◽  
pp. 1786-1792 ◽  
Author(s):  
Anne A. Nunes ◽  
Adriana S. Franca ◽  
Leandro S. Oliveira
2013 ◽  
Vol 47 (4) ◽  
pp. 347-364 ◽  
Author(s):  
MS Islam ◽  
MA Rouf

A review of the production of activated carbons from waste biomass has been presented. The effects of various process parameters on the pyrolysis stage have been reviewed. Influences of activating conditions, physical and chemical, on the active carbon properties have been discussed. Under certain process conditions several active carbons with BET surface areas, ranging between 250 and 2410 m2/g and pore volumes of 0.022 and 91.4 cm3/g, have been produced. A comparison in characteristics and uses of activated carbons from waste biomass with those of commercial carbons has been made. Waste biomass being highly efficient, low cost and renewable sources of activated carbon production. Bangladesh J. Sci. Ind. Res. 47(4), 347-364, 2012 DOI: http://dx.doi.org/10.3329/bjsir.v47i4.14064


Author(s):  
Muhammad Hamza ◽  
Muhammad Ayoub ◽  
Rashid Bin Shamsuddin ◽  
Ahmad Mukhtar ◽  
Sidra Saqib ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (51) ◽  
pp. 45419-45427 ◽  
Author(s):  
Mary K. S. Batista ◽  
Ana S. Mestre ◽  
Inês Matos ◽  
Isabel M. Fonseca ◽  
Ana P. Carvalho

Turning waste into valuable products: K2CO3 activation of rapeseed residues from biodiesel industry for the production of new and reusable activated carbons for caffeine removal from water.


2021 ◽  
Vol 287 ◽  
pp. 04004
Author(s):  
Zhi Min Ng ◽  
Uganeeswary Suparmaniam ◽  
Man Kee Lam ◽  
Jun Wei Lim ◽  
Siew Hoong Shuit ◽  
...  

Harvesting of microalgae is one of the main challenges in the production of biodiesel due to the small cell size of microalgae cells. Chemical flocculants have been generally used in the harvesting of microalgae, but they are harmful to the environment and relatively costly. Therefore, the utilization of waste biomass in producing bioflocculants is the current research niche to introduce environmental-friendly harvesting method and to minimize the cost of biodiesel production. Thus, in the current work, flocculation Chlorella vulgaris using mild acid-extracted bioflocculants from miscellaneous waste biomass (cockle shell, peanut shell and banana peel) were conducted by varying the pH values, the dosage of bioflocculants and temperatures. Cockle shell bioflocculant demonstrated the best flocculation performance, with highest flocculation efficiency of 85.2% compared to the peanut shell bioflocculant with flocculation efficiency of 37% and banana peel bioflocculant with flocculation efficiency of 16.3%. The optimum flocculation conditions for cockle shell bioflocculant were determined as follow: pH 9, bioflocculant dosage of 140mg/L and temperature of 30oC. The findings herein presented practical applicability of bioflocculants extracted from cockle shell for safe, rapid and inexpensive microalgae harvesting.


2008 ◽  
Vol 136 ◽  
pp. S654-S655 ◽  
Author(s):  
Adriana S. Franca ◽  
Anne A. Nunes ◽  
Leandro S. Oliveira

2018 ◽  
Vol 36 (8) ◽  
pp. 719-728 ◽  
Author(s):  
Indika Thushari ◽  
Sandhya Babel

Waste utilization is essential and challenging. Utilization of wastes gives environmental, economic, and social benefits. In this study, inexpensive, sulfonated solid acid catalysts were successfully prepared from palm empty fruit bunch (PEFB), coconut meal residue (CMR), and coconut coir husk (CH) waste by a simple protocol. It was found that prepared PEFB–BCS–SO3H, CMR–BCS–SO3H, and CH–BCS–SO3H catalysts have 4.79, 3.75, and 2.80 mmol g-1 acid density and 739.0, 89.77, and 61.49 m2 g-1 surface areas, respectively. Further, the presence of active functional groups on the surface of the catalysts was confirmed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Thermal stability of the catalysts was found below 150°C. Results show that biodiesel yield increases with increasing reaction time and methanol loading, when using microwave heating for biodiesel production from waste palm oil (WPO) and prepared catalysts. A maximum biodiesel yield of 95.5% was obtained by PEFB–BCS–SO3H in 60 minutes using 20:1 methanol:oil (molar ratio) at 70°C. CMR–BCS–SO3H and CH–BCS–SO3H obtained 88.7 and 88.5% biodiesel yields in 60 minutes, using 20:1 and 16:1 methanol:oil (molar ratio), at 70 and 110°C, respectively. Even though, the activity of the catalysts decreased during reuse, these are still of interest as the waste biomass of PEFB, CMR, and CH can be used for catalyst preparation and microwave-assisted biodiesel production from WPO.


2021 ◽  
Vol 100 (10) ◽  
pp. 219-224
Author(s):  
Warangkana KHANGWICHIAN ◽  
Sudarat PATTAMASEWE ◽  
Atip LAUNGPHAIROJANA ◽  
Rattanaporn LEESING ◽  
Andrew J. HUNT ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7448
Author(s):  
Adrianna Kamińska ◽  
Piotr Miądlicki ◽  
Karolina Kiełbasa ◽  
Marcin Kujbida ◽  
Joanna Sreńscek-Nazzal ◽  
...  

This work presents studies on the preparation of porous carbon materials from waste biomass in the form of orange peels, coffee grounds, and sunflower seed husks. The preparation of activated carbons from these three waste materials involved activation with KOH followed by carbonization at 800 °C in an N2 atmosphere. This way of obtaining the activated carbons is very simple and requires the application of only two reactants. Thus, this method is cheap, and it does not generate much chemical waste. The obtained activated carbons were characterized by XRD, SEM, XPS, and XRF methods. Moreover, the textural properties, acidity, and catalytic activity of these materials were descried. During catalytic tests carried out in the alpha-pinene isomerization process (the use of the activated carbons thus obtained in the process of alpha-pinene isomerization has not been described so far), the most active were activated carbons obtained from coffee grounds and orange peels. Generally, the catalytic activity of the obtained materials depended on the pore size, and the most active activated carbons had more pores with sizes of 0.7–1.0 and 1.1–1.4 nm. Moreover, the presence of potassium and chlorine ions in the pores may also be of key importance for the alpha-pinene isomerization process. On the other hand, the acidity of the surface of the tested active carbons did not affect their catalytic activity. The most favorable conditions for carrying out the alpha-pinene isomerization process were the same for the three tested activated carbons: temperature 160 °C, amount of the catalyst 5 wt.%, and reaction time 3 h. Kinetic studies were also carried out for the three tested catalysts. These studies showed that the isomerization over activated carbons from orange peels, coffee grounds, and sunflower seed husks is a first-order reaction.


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