Self-preservation effect exceeding 273.2 K by introducing deuterium oxide to form methane hydrate

2022 ◽  
pp. 134591
Author(s):  
Jun Chen ◽  
Jianjian Wu ◽  
Yaosong Zeng ◽  
Zhikai Liang ◽  
Guangjin Chen ◽  
...  
2018 ◽  
Author(s):  
Saurav Parashar ◽  
Raghvendra Pratap Singh ◽  
Malay Kumar Das

2018 ◽  
Author(s):  
Mingjun Yang ◽  
Yi Gao ◽  
Hang Zhou ◽  
Bingbing Chen ◽  
Yongchen Song

2020 ◽  
Vol 13 (2) ◽  
pp. 185-203
Author(s):  
Dong Yan ◽  
Paolo Davide Farah ◽  
Tivadar Ötvös ◽  
Ivana Gaskova

Abstract Considering the fact that its existence is abundant while maintaining the ability to generate freshwater while burning, methane hydrates have been classified as sources of sustainable energy. China currently maintains an international role in developing technology meant to explore offshore methane hydrates buried under the mud of the seabed, their primary laboratory being the South China Sea. However, such a process does not come without its hazards and fatal consequences, ranging from the destruction of the flora and fauna, the general environment, and—the greatest hazard of all—the cost of human life. The United Nations Convention on the Law of the Sea (hereinafter ‘UNCLOS’), being an important international legal regime and instrument, has assigned damage control during the exploration of methane hydrates, as being the responsibilities and liability of individual sovereign states and corporations. China adopted the Deep Seabed Mining Law (hereinafter the DSM Law) on 26 February 2016, which came into force on the 1 of May 2016; a regulation providing the legal framework also for the Chinese government’s role in methane hydrate exploratory activities. This article examines the role of the DSM Law and its provisions, as well as several international documents intended to prevent transboundary environmental harm from arising, as a result of offshore methane hydrate extraction. Despite the obvious risk of harm to the environment, the DSM Law has made great strides in regulating exploratory activities so as to meet the criteria of the UNCLOS. However, this article argues that neither the UNCLOS nor the DSM Law are adequately prepared to address transboundary harm triggered by the exploitation of offshore methane hydrates. In particular, the technology of such extraction is still at an experimental stage, and potential risks remain uncertain—and even untraceable—for cross-jurisdictional claims. The article intends to seek available legal instruments or models, to overhaul the incapacity within the current governing framework, and offers suggestions supporting national and international legislative efforts towards protecting the environment during methane hydrate extraction.


2007 ◽  
Vol 130 (1) ◽  
pp. 111-116 ◽  
Author(s):  
Artem B. Mamonov ◽  
Rob D. Coalson ◽  
Mark L. Zeidel ◽  
John C. Mathai

Determining the mechanisms of flux through protein channels requires a combination of structural data, permeability measurement, and molecular dynamics (MD) simulations. To further clarify the mechanism of flux through aquaporin 1 (AQP1), osmotic pf (cm3/s/pore) and diffusion pd (cm3/s/pore) permeability coefficients per pore of H2O and D2O in AQP1 were calculated using MD simulations. We then compared the simulation results with experimental measurements of the osmotic AQP1 permeabilities of H2O and D2O. In this manner we evaluated the ability of MD simulations to predict actual flux results. For the MD simulations, the force field parameters of the D2O model were reparameterized from the TIP3P water model to reproduce the experimentally observed difference in the bulk self diffusion constants of H2O vs. D2O. Two MD systems (one for each solvent) were constructed, each containing explicit palmitoyl-oleoyl-phosphatidyl-ethanolamine (POPE) phospholipid molecules, solvent, and AQP1. It was found that the calculated value of pf for D2O is ∼15% smaller than for H2O. Bovine AQP1 was reconstituted into palmitoyl-oleoyl-phosphatidylcholine (POPC) liposomes, and it was found that the measured macroscopic osmotic permeability coefficient Pf (cm/s) of D2O is ∼21% lower than for H2O. The combined computational and experimental results suggest that deuterium oxide permeability through AQP1 is similar to that of water. The slightly lower observed osmotic permeability of D2O compared to H2O in AQP1 is most likely due to the lower self diffusion constant of D2O.


2021 ◽  
Vol 125 (33) ◽  
pp. 18483-18493
Author(s):  
Kehan Li ◽  
Bingbing Chen ◽  
Mingjun Yang ◽  
Yongchen Song ◽  
Lanlan Jiang

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 590
Author(s):  
Lihua Wan ◽  
Xiaoya Zang ◽  
Juan Fu ◽  
Xuebing Zhou ◽  
Jingsheng Lu ◽  
...  

The large amounts of natural gas in a dense solid phase stored in the confined environment of porous materials have become a new, potential method for storing and transporting natural gas. However, there is no experimental evidence to accurately determine the phase state of water during nanoscale gas hydrate dissociation. The results on the dissociation behavior of methane hydrates confined in a nanosilica gel and the contained water phase state during hydrate dissociation at temperatures below the ice point and under atmospheric pressure are presented. Fourier transform infrared spectroscopy (FTIR) and powder X-ray diffraction (PXRD) were used to trace the dissociation of confined methane hydrate synthesized from pore water confined inside the nanosilica gel. The characterization of the confined methane hydrate was also analyzed by PXRD. It was found that the confined methane hydrates dissociated into ultra viscous low-density liquid water (LDL) and methane gas. The results showed that the mechanism of confined methane hydrate dissociation at temperatures below the ice point depended on the phase state of water during hydrate dissociation.


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