Mass transfer process intensification for SO2 absorption in a commercial-scale wet flue gas desulfurization scrubber

Author(s):  
Jiangyuan Qu ◽  
Nana Qi ◽  
Zhen Li ◽  
Kai Zhang ◽  
Pengcheng Wang ◽  
...  
2011 ◽  
Vol 356-360 ◽  
pp. 1461-1468
Author(s):  
Dong Ping Zhang ◽  
Qian Jun Li ◽  
Xian Feng Liu

In the limestone/gypsum wet flue gas desulfurization pilot-scale test rig, key parameters such as SO2 absorption rate, mass transfer were experimentally determined.The results show that desulphurizing capacity of gypsum and fly ash is relatively weaker, which is only equivalent to fresh limestone with a content of 0.27% and 1.5% respectively. pH-t curve of slurry with different levels of fly ash could be divided into a sharply increasing stage and a steadily increasing stage. The leaching content of Mn2+ is about 9 times of Fe3+ , Mn2+ can form intermediate complex with HSO3- in the solution, which can induce catalytic reaction and accelerate SO2 absorption. Fly ash in gypsum slurry can obviously promote desulfurization. The pH value of slurry is high at the initial reaction stage, and effect of fly ash on SO2 absorption rate is less than 1.5%. when the pH value is decreased to 5.0, The leaching content of Mn2+ will grow with the decrease of pH value, better catalytic efficiency can be gained, effect of fly ash on SO2 absorption rate can increase 6.0% at most. The reaction is controlled by liquid phase resistance; the ratio of gas phase resistance to overall resistance is less than 38%. Mn2+ concentration of slurry increases with pH value decreasing and fly ash concentration increasing, which has significant effect on catalyzed oxidation of SO32-.


2012 ◽  
Vol 9 (1) ◽  
pp. 91-93
Author(s):  
U.R. Ilyasov ◽  
A.V. Dolgushev

The problem of volumetric thermal action on a moist porous medium is considered. Numerical solution, the influence of fluid mobility on the dynamics of the heat and mass transfer process is analyzed. It is established that fluid mobility leads to a softer drying regime. It is shown that in low-permeability media, the fluid can be assumed to be stationary.


Author(s):  
Qing-Qing Duan ◽  
Zhi-Guo Yuan ◽  
You-Zhi Liu ◽  
Shan-Shan Duan ◽  
Xi-Fan Duan

2019 ◽  
Vol 36 (1) ◽  
pp. 187-214
Author(s):  
Chao Yang ◽  
Guangsheng Luo ◽  
Xigang Yuan ◽  
Jie Chen ◽  
Yangcheng Lu ◽  
...  

Abstract This paper presents a comprehensive review of the remarkable achievements by Chinese scientists and engineers who have contributed to the multiscale process design, with emphasis on the transport mechanisms in stirred reactors, extractors, and rectification columns. After a brief review of the classical theory of transport phenomena, this paper summarizes the domestic developments regarding the relevant experiments and numerical techniques for the interphase mass transfer on the drop/bubble scale and the micromixing in the single-phase or multiphase stirred tanks in China. To improve the design and scale-up of liquid-liquid extraction columns, new measurement techniques with the combination of both particle image velocimetry and computational fluid dynamics have been developed and advanced modeling methods have been used to determine the axial mixing and mass transfer performance in extraction columns. Detailed investigations on the mass transfer process in distillation columns are also summarized. The numerical and experimental approaches modeling transport phenomena at the vicinity of the vapor-liquid interface, the point efficiency for trays/packings regarding the mixing behavior of fluids, and the computational mass transfer approach for the simulation of distillation columns are thoroughly analyzed. Recent industrial applications of mathematical models, numerical simulation, and experimental methods for the design and analysis of multiphase stirred reactors/crystallizers, extractors, and distillation columns are seen to garnish economic benefits. The current problems and future prospects are pinpointed at last.


Processes ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 1269
Author(s):  
Yuzhen Jin ◽  
Weida Zhao ◽  
Zeqing Li

The deflector and the rod bank are commonly used to optimize flue gas distribution in the original spray tower (OST) of a wet flue gas desulfurization system (WFGD). In this paper, the internal optimization mechanism of the deflector desulfurization spray tower (DST) and the rod bank desulfurization spray tower (RBST) are studied. Based on the Euler–Lagrange method, the standard k-ε turbulence model, an SO2 absorption model and a porous media model, the numerical simulation of the desulfurization spray tower is carried out with the verification of the model rationality. The results show that there are gas-liquid contact intensification effects in DST and RBST. Compared with OST, gas-liquid contact intensification enhances the heat and mass transfer effects of DST and RBST. The temperature difference between inlet and outlet of flue gas increased by 3.3 K and the desulfurization efficiency of DST increased by 1.8%; the pressure drop decreased by 37 Pa. In RBST, the temperature difference between the flue gas inlet and outlet increased by 5.3 K and the desulfurization efficiency increased by 3.6%; the pressure drop increased by 33 Pa.


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