Preparation of oriented SiO32− doped TiO2 film and degradation of methylene blue under visible light irradiation

2010 ◽  
Vol 36 (2) ◽  
pp. 443-450 ◽  
Author(s):  
Xiangying Xu ◽  
Dehong Yin ◽  
Shufeng Wu ◽  
Jinqu Wang ◽  
Jinming Lu
2007 ◽  
Vol 336-338 ◽  
pp. 1972-1975 ◽  
Author(s):  
Yan Hong Li ◽  
Wen Bin Cao ◽  
Fan Yong Ran ◽  
Xiao Ning Zhang

N-doped TiO2 powders with high photocatalytic activity under visible-light irradiation have been prepared by calcining anatase nanocrystalline TiO2 powders and guanidine hydrochloride at 350 °C, 450 °C, 550 °C and 650 °C with the holding time ranged from 1.5 h to 3 h, respectively. The guanidine hydrochloride content was varied from 1 to 6 M for the experiments. XRD patterns indicate that all the powders are anatase crystalline phase. The specific surface area is 25~45 m2/g measured by BET method. XPS results show that N atoms were incorporated into the lattice of TiO2 and the amount of N doped in TiO2 is reached up to 8.26 at%. UV-Vis absorption spectra show that the absorption edge of the synthesized N-doped TiO2 powders, calcined at 350 °C for 2.5 h, has red-shifted well into visible region up to 700 nm. Degradation of methylene blue (MB) aqueous solution has been investigated by UV-Vis light spectrophotometer. The 400-mL 10 mg/L aqueous solution of methylene blue could be degraded completely with 4 g N-doped TiO2 within 4.5 h of visible light irradiation.


Catalysts ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1454
Author(s):  
Sarunas Varnagiris ◽  
Marius Urbonavičius ◽  
Sandra Sakalauskaitė ◽  
Emilija Demikyte ◽  
Simona Tuckute

In the current study, we analysed the influence of metallic underlayers on carbon-doped TiO2 films for RhB decomposition and Salmonella typhimurium inactivation under visible-light irradiation. All the experiments were divided into two parts. First, layered M/C-doped-TiO2 film structures (M = Ni, Nb, Cu) were prepared by magnetron sputtering technique on borosilicate glass substrates in the two-step deposition process. The influence of metal underlayer on the formation of the carbon-doped TiO2 films was characterised by X-ray diffractometer, scanning electron microscope, and atomic force microscope. The comparison between the visible-light assisted photocatalytic activity of M/C-doped TiO2 structures was performed by the photocatalytic bleaching tests of Rhodamine B dye aqueous solution. The best photocatalytic performance was observed for Ni/C-doped-TiO2 film combination. During the second part of the study, the Ni/C-doped-TiO2 film combination was deposited on high-density polyethylene beads which were selected as a floating substrate. The morphology and surface chemical analyses of the floating photocatalyst were performed. The viability and membrane permeability of Salmonella typhimurium were tested in cycling experiments under UV-B and visible-light irradiation. Three consecutive photocatalytic treatments of fresh bacteria suspensions with the same set of floating photocatalyst showed promising results, as after the third 1 h-long treatment bacteria viability was still reduced by 90% and 50% for UV-B and visible-light irradiation, respectively. The membrane permeability and ethidium fluorescence results suggest that Ni underlayer might have direct and indirect effect on the bacteria inactivation process. Additionally, relatively low loss of the photocatalyst efficiency suggests that floating C-doped TiO2 photocatalyst with the Ni underlayer might be seen as the possible solution for the used photocatalyst recovery issue.


2021 ◽  
Vol 9 (4) ◽  
pp. 105254
Author(s):  
Periyakaruppan Karuppasamy ◽  
Nagoorkani Ramzan Nilofar Nisha ◽  
Arivalagan Pugazhendhi ◽  
Sabariswaran Kandasamy ◽  
Sakthivel Pitchaimuthu

Catalysts ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 352 ◽  
Author(s):  
Benjawan Moongraksathum ◽  
Jun-Ya Shang ◽  
Yu-Wen Chen

Cu-doped titanium dioxide thin films (Cu/TiO2) were prepared on glass substrate via peroxo sol-gel method and dip-coating process with no subsequent calcination process for the degradation of organic dye and use as an antibacterial agent. The as-prepared materials were characterised using transmission electron microscopy (TEM), X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). For photocatalytic degradation of methylene blue in water, the samples were subjected to Ultraviolet C (UVC) and visible light irradiation. Degraded methylene blue concentration was measured using UV-Vis spectrophotometer. The antibacterial activities of the samples were tested against the gram-negative bacteria Escherichia coli (ATCC25922). Copper species were present in the form of CuO on the surface of modified TiO2 particles, which was confirmed using TEM and XPS. The optimal observed Cu/TiO2 weight ratio of 0.5 represents the highest photocatalytic activities under both UVC and visible light irradiation. Moreover, the same composition remarkably exhibited high antibacterial effectiveness against E. coli after illumination with ultraviolet A. The presence of CuO on TiO2 significantly enhanced photocatalytic activities. Therefore, active Cu-doped TiO2 can be used as a multipurpose coating material.


RSC Advances ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 6383-6394 ◽  
Author(s):  
Haishuai Li ◽  
Linlin Cai ◽  
Xin Wang ◽  
Huixian Shi

A noval ternary nanocomposite AgCl/Ag3PO4/g-C3N4 was successfully synthesized for photocatalytic degradation of methylene blue, methylparaben and inactivation of E. coli under visible light irradiation, showing excellent photocatalytic degradation performance and stability.


Sign in / Sign up

Export Citation Format

Share Document