scholarly journals Sorption and coprecipitation of copper to ferrihydrite and humic acid organomineral complexes and controls on copper availability

Chemosphere ◽  
2016 ◽  
Vol 147 ◽  
pp. 272-278 ◽  
Author(s):  
Neila N. Seda ◽  
Faye Koenigsmark ◽  
Timothy M. Vadas
RSC Advances ◽  
2015 ◽  
Vol 5 (122) ◽  
pp. 100464-100471 ◽  
Author(s):  
Xuetao Guo ◽  
Jing Zhang ◽  
Jianhua Ge ◽  
Chen Yang ◽  
Zhi Dang ◽  
...  

Humic acid and mineral oxides are simultaneously present in soils and can form organomineral complexes.


2013 ◽  
Vol 864-867 ◽  
pp. 1793-1797 ◽  
Author(s):  
Ni Liang ◽  
Di Zhang ◽  
Min Wu

Organo-mineral complexes are important in regulating the transport and retention of hydrophobic organic contaminants in soils/sediments. Humic acid will be fractionated during adsorption on mineral. This study examined the sorption of model compounds with different properties (tannin acid, gallic acid, fumaric acid sodium and sodium oleate) on nanoiron oxide minerals and determined the sorption of phenanthrene and Bisphenol A on these organooxide complexes. The results showed that the sorption of model compounds on nanoFe2O3 followed the order of O > T > G> F. The higher adsorption of O and T was likely attributed to their higher molecule weight. The sorption of PHE and BPA on organomineral complexes was controlled by hydrophobic interactions. HOCs will adsorb preferentially on hydrophobic aliphatic compositions of organic matter.


2010 ◽  
Vol 59 (1) ◽  
pp. 99-108 ◽  
Author(s):  
M. Takács ◽  
Gy. Füleky

The Hot Water Percolation (HWP) technique for preparing soil extracts has several advantages: it is easily carried out, fast, and several parameters can be measured from the same solution. The object of this study was to examine the possible use of HWP extracts for the characterization of soil organic matter. The HPLC-SEC chromatograms, UV-VIS and fluorescence properties of the HWP extracts were studied and the results were compared with those of the International Humic Substances Society (IHSS) Soil Humic Acid (HA), IHSS Soil Fulvic Acid (FA) and IHSS Suwannee Natural Organic Matter (NOM) standards as well as their HA counterparts isolated by traditional extraction methods from the original soil samples. The DOM of the HWP solution is probably a mixture of organic materials, which have some characteristics similar to the Soil FA fractions and NOM. The HWP extracted organic material can be studied and characterized using simple techniques, like UV-VIS and fluorescence spectroscopy.


2012 ◽  
Vol 51 (3) ◽  
pp. 228-237
Author(s):  
D. Dudare ◽  
M. Klavins

The aim of this study is to determine the Cu(II) complexing capacity and stability constants of Cu(II) complexes of humic acids isolated from two well-characterized raised bog peat profiles in respect to the basic properties and humification characteristics of the studied peats and their humic acids. The complex stability constants significantly change within the studied bog profiles and are well correlated with the age and decomposition degree of the peat layer from which the humic acids have been isolated. Among factors that influence this complexation process, molecular mass and ability to form micellar structures (supramolecules) of humic substances are of key importance.


2018 ◽  
Author(s):  
Zoltán Kis ◽  
Katalin Gméling ◽  
Tímea Kocsis ◽  
János Osán ◽  
Mihály András Pocsai ◽  
...  

We present precise analysis of major and trace elements of the humic acid. We used three different element analytical techniques in our investigations as prompt-gamma activation analysis (PGAA), neutron activation analysis (NAA) and X-ray fluorescence (XRF) analysis was carried out. We identified 42 elements in our sample.


2019 ◽  
Vol 1 (1) ◽  
pp. 29-32
Author(s):  
Ruzimurod B. Boimurodov ◽  
Zebinisso Q. Bobokhonova

In this article is showing, that the irrigation mountain brown carbonate soils prone methods of irrigation and grassing comes the rapid growth and development of natural vegetation, which leads to intensive humus accumulation. Humus content in the upper layer is increased by 0.98% and a significantly smaller severely eroded. Increasing the amount of humus promotes accumulation mainly humic acids, that conducts to expansion of relations the content of humic acid: The content of folic acid. When grassing of soil traced sharp increase in the number associated with the related and R2 O3 humic acid.


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