Excellent photocatalytic performances of Co3O4–AC nanocomposites for H2 production via wastewater splitting

Chemosphere ◽  
2021 ◽  
pp. 131823
Author(s):  
Sankar Sekar ◽  
V. Preethi ◽  
S. Saravanan ◽  
Deuk Young Kim ◽  
Sejoon Lee
2018 ◽  
Vol 5 (1) ◽  
Author(s):  
Mahyudin Abdul Rachman

Enterobacter aerogenes AY-2 mutant is known for hydrogen gas producer which ws obtained from the sludge of methane fermentation and the yield is 1.5 fold higher than wildtype. Hydrogen gas production can be gain via NADH oxidation in anaerobic metabolic pathway by blocking organic acid production. Metabolic pathway can be changed by mutagenesis. Enterobacter aerogenes AY-2 mutated with ethyl methane sulfonate in logarithmic phase with consentration 10, 11, 12, 13, 14 and 15 μl/ml cell suspention during 120 minute. Mutation that result lowest survival ratio (0,01%) was 14 μl EMS/ml cell suspention is repeated with variation incubation time, 30, 60, 90 and 120 minute. 166 double mutant colony has been collected and choosen randomly. The choosen 43 colony was fermented in glycerol complex medium for determining ten double mutant with the highest H2 production. Double mutant AD-H43 is a highest H2 producer that increase 20% H2 production from AY-2 and has a decrease lactid acid production, 31% less from AY-2. Increasing H2 production in double mutant AD-H43 is caused by lactate dehydrogenase deffi cient.Keywords: Enterobacter aerogenes AY-2, ethyl methane sulfonate (EMS), H2 and methane sludge


Fuel ◽  
2021 ◽  
Vol 302 ◽  
pp. 121108
Author(s):  
Jun Hu ◽  
Wenwen Wei ◽  
Qing Li ◽  
Wen Cao ◽  
Anlong Zhang ◽  
...  

2021 ◽  
Vol 115 ◽  
pp. 111035
Author(s):  
Y. Benrighi ◽  
N. Nasrallah ◽  
T. Chaabane ◽  
V. Sivasankar ◽  
A. Darchen ◽  
...  

Author(s):  
Ahmed Hassan ◽  
Rabia Liaquat ◽  
Naseem Iqbal ◽  
Ghulam Ali ◽  
Xue Fan ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1301
Author(s):  
Oscar E. Medina ◽  
Jaime Gallego ◽  
Sócrates Acevedo ◽  
Masoud Riazi ◽  
Raúl Ocampo-Pérez ◽  
...  

This study focuses on evaluating the volumetric hydrogen content in the gaseous mixture released from the steam catalytic gasification of n-C7 asphaltenes and resins II at low temperatures (<230 °C). For this purpose, four nanocatalysts were selected: CeO2, CeO2 functionalized with Ni-Pd, Fe-Pd, and Co-Pd. The catalytic capacity was measured by non-isothermal (from 100 to 600 °C) and isothermal (220 °C) thermogravimetric analyses. The samples show the main decomposition peak between 200 and 230 °C for bi-elemental nanocatalysts and 300 °C for the CeO2 support, leading to reductions up to 50% in comparison with the samples in the absence of nanoparticles. At 220 °C, the conversion of both fractions increases in the order CeO2 < Fe-Pd < Co-Pd < Ni-Pd. Hydrogen release was quantified for the isothermal tests. The hydrogen production agrees with each material’s catalytic activity for decomposing both fractions at the evaluated conditions. CeNi1Pd1 showed the highest performance among the other three samples and led to the highest hydrogen production in the effluent gas with values of ~44 vol%. When the samples were heated at higher temperatures (i.e., 230 °C), H2 production increased up to 55 vol% during catalyzed n-C7 asphaltene and resin conversion, indicating an increase of up to 70% in comparison with the non-catalyzed systems at the same temperature conditions.


Nanoscale ◽  
2021 ◽  
Author(s):  
Xianyun Peng ◽  
Junrong Hou ◽  
Yuying Mi ◽  
Jiaqiang Sun ◽  
Gaocan Qi ◽  
...  

Electrocatalytic hydrogen evolution reaction (HER) for H2 production is essential for future renewable and clean energy technology. Screening energy-saving, low-cost, and highly active catalysts efficiently, however, is still a grand...


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