Phenol formaldehyde resin derived carbon-MCMB composite foams for electromagnetic interference shielding and thermal management applications

2020 ◽  
Vol 22 ◽  
pp. 100433 ◽  
Author(s):  
Anushi Sharma ◽  
Rajeev Kumar ◽  
Veerendra Kumar Patle ◽  
Ridham Dhawan ◽  
Amit Abhash ◽  
...  
2020 ◽  
pp. 34-43
Author(s):  
N. R. Memetov ◽  
◽  
A. V. Gerasimova ◽  
A. E. Kucherova ◽  
◽  
...  

The paper evaluates the effectiveness of the use of graphene nanostructures in the purification of lead (II) ions to improve the ecological situation of water bodies. The mechanisms and characteristic parameters of the adsorption process were analyzed using empirical models of isotherms at temperatures of 298, 303, 313 and 323 K, which correspond to the following order (based on the correlation coefficient): Langmuir (0.99) > Temkin (0.97) > Dubinin – Radushkevich (0.90). The maximum adsorption capacity of the material corresponds to the range from 230 to 260 mg/g. We research the equilibrium at the level of thermodynamic parameter estimates, which indicates the spontaneity of the process, the endothermic nature and structure change of graphene modified with phenol-formaldehyde resin during the adsorption of lead (II) ions, leading to an increase in the disorder of the system.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Guolong Sang ◽  
Pei Xu ◽  
Tong Yan ◽  
Vignesh Murugadoss ◽  
Nithesh Naik ◽  
...  

Abstract Lightweight microcellular polyurethane (TPU)/carbon nanotubes (CNTs)/ nickel-coated CNTs (Ni@CNTs)/polymerizable ionic liquid copolymer (PIL) composite foams are prepared by non-solvent induced phase separation (NIPS). CNTs and Ni@CNTs modified by PIL provide more heterogeneous nucleation sites and inhibit the aggregation and combination of microcellular structure. Compared with TPU/CNTs, the TPU/CNTs/PIL and TPU/CNTs/Ni@CNTs/PIL composite foams with smaller microcellular structures have a high electromagnetic interference shielding effectiveness (EMI SE). The evaporate time regulates the microcellular structure, improves the conductive network of composite foams and reduces the microcellular size, which strengthens the multiple reflections of electromagnetic wave. The TPU/10CNTs/10Ni@CNTs/PIL foam exhibits slightly higher SE values (69.9 dB) compared with TPU/20CNTs/PIL foam (53.3 dB). The highest specific EMI SE of TPU/20CNTs/PIL and TPU/10CNTs/10Ni@CNTs/PIL reaches up to 187.2 and 211.5 dB/(g cm−3), respectively. The polarization losses caused by interfacial polarization between TPU substrates and conductive fillers, conduction loss caused by conductive network of fillers and magnetic loss caused by Ni@CNT synergistically attenuate the microwave energy.


Nanoscale ◽  
2021 ◽  
Author(s):  
Bing Zhou ◽  
Qingtao Li ◽  
Penghui Xu ◽  
Yuezhan Feng ◽  
Jianmin Ma ◽  
...  

Flexible cellulose-based conductive films reveal the high potential in electromagnetic interference (EMI) shielding and thermal management applications. However, the high contact electrical/thermal resistance in these films is still one of...


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