Rheology, crystal structure, and nanomechanical properties in large-scale additive manufacturing of polyphenylene sulfide/carbon fiber composites

2018 ◽  
Vol 168 ◽  
pp. 263-271 ◽  
Author(s):  
Peng Liu ◽  
Ralph B. Dinwiddie ◽  
Jong K. Keum ◽  
Rama K. Vasudevan ◽  
Stephen Jesse ◽  
...  

Author(s):  
Р. Ш. Іскандаров ◽  
Н. В. Сова ◽  
Б. М. Савченко ◽  
І. І. П'ятничук ◽  
В. А. Татаренко

Study of the FFF additive manufacturing process of composite material based on L – polylactide (PLLA) with ultra-short carbon fibers. Tensile strength and elongation at break for all test specimens were determined according to ISO 527. Tensile modulus - ASTM D638-10, specimen density - PN-EN ISO 1183, microscopic examination - according to ASTM E2015 - 04 (2014). Charpy Shock Tests ISO 179 and ASTM D256. Bending test method ISO 178 and ASTM D 790. The rational modes of FFF additive manufacturing (AM) of carbon fiber composite based on PLLA was established. Properties of carbon fiber PLLA and unfilled PLLA was determinated for AM formed samples and injection molded samples. Carbon fiber composites have significantly higher flexural and tensile module us values compared to the original L-polylactide, which is due to the effect of polymer matrix reinforcement by the fibrous component. However, finished products obtained by AM PLLA carbon composite have a lower impact strength and tensile strength, which is likely to be due to the fact that the carbon fibers are short (50-60 mkm) and have a cavitations effect during injection molding and AM. Density of carbon fiber filled PLLLA was lower the theoretically calculated value for filament material as well for injection molded and AM formed samples. Density reduction probably the main cause of impact properties deterioration due to cavity forming around carbon fibers. Density and tensile properties of AM formed samples can be changed by AM slicing parameter – extrusion multiplier. Cavitation effect for carbon fiber composites observed for PLLA composite in form AM filament, injection molded parts and AM formed samples. Cavity forming was confirmed by optical microscopy and density measurement. Possible reason for cavity forming is orientation deformation of the fiber in polymer matrix during the formation of the filament. The effect of cavitation also persists in the AM of products from carbon composites due to the passage of the orientation at the exit of the printer nozzle.  The possibility of regulating the density and physical and mechanical properties of carbon composite products obtained by the additive manufacturing method has been established. Selection of rational values of the extrusion multiplier and the direction of the layers in the additive molding allows you to create products with the desired complex of properties.





Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 684 ◽  
Author(s):  
Chukov ◽  
Nematulloev ◽  
Zadorozhnyy ◽  
Tcherdyntsev ◽  
Stepashkin ◽  
...  

The paper studies new high-temperature thermoplastic impregnated unidirectional carbon fiber composites. The research focuses on the effect of thermal and chemical oxidation of the carbon fibers surface on the interfacial interaction between fibers and polysulfone and polyphenylene sulfide as well as thermal and mechanical properties of the composites. The research reveals the interaction between carbon fibers and the polymer matrix depend both on the type of surface treatment and nature of the polymer. The chemical oxidation of carbon fibers results in good interfacial interaction, and the best mechanical properties were observed for tows impregnated with polyphenylene sulfide.



2013 ◽  
Vol 28 (3) ◽  
pp. 340-356 ◽  
Author(s):  
Natassia Lona Batista ◽  
Maria Cândida Magalhães de Faria ◽  
Koshun Iha ◽  
Pedro Carlos de Oliveira ◽  
Edson Cocchieri Botelho


2021 ◽  
Author(s):  
Arit Das ◽  
Martin Etemadi ◽  
Bradley A. Davis ◽  
Steven H. McKnight ◽  
Christopher B. Williams ◽  
...  


2017 ◽  
Vol 146 ◽  
pp. 65-72 ◽  
Author(s):  
Hao-hao Ren ◽  
Dong-xia Xu ◽  
Guang-ming Yan ◽  
Gang Zhang ◽  
Xiao-jun Wang ◽  
...  


2015 ◽  
Vol 815 ◽  
pp. 523-528 ◽  
Author(s):  
Rui Hong ◽  
Kun Zhang ◽  
Bao Ying Liu ◽  
Gang Zhang ◽  
Xiao Jun Wang ◽  
...  

The carbon fiber (CF) reinforced polyphenylene sulfide (PPS) composite was modified by aminated polyphenylene sulfide (PPS-NH2) with different mass fractions. The quantified influence of aminated PPS on PPS/CF composites was investigated. The PPS/CF composite with 7wt% PPS-NH2 showed the best mechanical properties. The tensile strength, flexural strength, flexural modulus and impact strength of the composites increased by 12.5%, 13.0%, 38.5% and 31.5%, respectively. PPS-NH2 hardly influenced the melting process of PPS/CF composite. But the crystallization temperature (Tc) of PPS were obviously increased with the present of aminated PPS.



Materials ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 669 ◽  
Author(s):  
Yongfeng Li ◽  
Qingjun Ding ◽  
Hongyuan Zhao ◽  
Tingting Wu ◽  
Mingming Zhang ◽  
...  

Anisotropic materials are important functional materials in many fields. The use of these materials is currently being expanded through the rapid development of additive manufacturing. However, there is still no universal method for fabricating two-dimensional anisotropic polymer composites. Here, polylactic acid–carbon fiber composites were prepared using the droplet spray method, and their mechanical and friction properties were studied. The tensile strength in the X–Y plane perpendicular to the direction of the droplet spray was significantly higher than that in the direction of droplet ejection. Similar trends were observed for the elongation at breaking and the impact strength. The friction coefficient was smallest in the X–Y plane. Scanning electron microscopy showed that carbon fibers were oriented in the X–Y plane, which enhanced the mechanical and friction properties in this plane.



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