Microstructural study of Portland cement partially replaced with fly ash, ground granulated blast furnace slag and silica fume as determined by pozzolanic activity

2020 ◽  
Vol 238 ◽  
pp. 117561 ◽  
Author(s):  
Sai Surya Sree Aparna Nedunuri ◽  
Seifemichael Getachew Sertse ◽  
Salman Muhammad
Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3448
Author(s):  
Chenhui Jiang ◽  
Aiying Wang ◽  
Xufan Bao ◽  
Zefeng Chen ◽  
Tongyuan Ni ◽  
...  

This paper presents an experimental investigation on geopolymer coatings (GPC) in terms of surface protection of civil structures. The GPC mixtures were prepared with a quadruple precursor simultaneously containing fly ash (FA), ground granulated blast-furnace slag (GBFS), metakaolin (MK), and Portland cement (OPC). Setting time, compressive along with adhesive strength and permeability, were tested and interpreted from a perspective of potential applications. The preferred GPC with favorable setting time (not shorter than 120 min) and desirable compressive strength (not lower than 35 MPa) was selected from 85 mixture formulations. The results indicate that balancing strength and setting behavior is viable with the aid of the multi-componential precursor and the mixture design based on total molar ratios of key oxides or chemical elements. Adhesive strength of the optimized GPC mixtures was ranged from 1.5 to 3.4 MPa. The induced charge passed based on a rapid test of coated concrete specimens with the preferred GPC was 30% lower than that of the uncoated ones. Setting time of GPC was positively correlated with η[Si/(Na+Al)]. An abrupt increase of setting time occurred when the molar ratio was greater than 1.1. Compressive strength of GPC was positively affected by mass contents of ground granulated blast furnace slag, metakaolin and ordinary Portland cement, and was negatively affected by mass content of fly ash, respectively. Sustained seawater immersion impaired the strength of GPC to a negligible extent. Overall, GPC potentially serves a double purpose of satisfying the usage requirements and achieving a cleaner future.


Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1593
Author(s):  
Monika Czop ◽  
Beata Łaźniewska-Piekarczyk

In Europe, the use of wastes in the cement and construction industry follows the assumptions of sustainability and the idea of circular economy. At present, it is observed that cement plants introduce wastes to the cement in the form of so-called mineral additives. The most often used mineral additives are: fly ash with silica fume, granulated blast furnace slag and silica fume. The use of mineral additives in the cement is related to the fact that the use of the most expensive component of cement—Portland cement clinker—is limited. The purpose of the article is a preliminary evaluation of the suitability of slag from the municipal solid waste incineration plant for its use as a replacement of cement. In this article, slag from the municipal solid waste incineration (MSWI) replaces cement in the quantity of 30%, and presents the content of oxides and elements of slag from the MSWI. The obtained results are compared to the requirements that the crushed and granulated blast furnace slag need to meet to be suitable for use as an additive of type II to the concrete. The conducted analyses confirmed that the tested slag meets the requirements for the granulated blast furnace slag as an additive to the concrete in the following parameters: CaO ≤ 18.0%, SO3 ≤ 2.5% and Cl ≤ 0.1%. At the same time, mechanical features were tested of the designed mortars which consisted of a mixture of Portland cement (CEM I) with 30% of slag admixture. The designed mortar after 28 days of maturing reached a compressive strength of 32.0 MPa, and bending strength of 4.0 MPa. When compared to the milled granulated blast furnace slag (GBFS), the obtained values are slightly lower. Furthermore, the hardened mortars were subject to a leachability test to check the impact on the environment. Test results showed that the aqueous extracts from mixtures with 30% of slag admixtures slightly exceed the limits and do not pose a sufficiant threat to the environment as to eliminate the MSWI slag from economical use.


2019 ◽  
Vol 25 (3) ◽  
pp. 340-347
Author(s):  
Ting WANG ◽  
Xiaojian GAO ◽  
Jian WANG

As a byproduct of phosphoric acid industry, phosphogypsum has many environmental problems. In order to recycle phosphogypsum to manufacture lightweight building materials, cementitious additives including fly ash, ground granulate blast-furnace slag and Portland cement were added to improve strength and water-resistance and different volume of foam was added to reduce the bulk density. The results show that hydrated lime can improve mechanical strength and water resistance of PG paste and the optimal dosage of hydrated lime is 6 %. Higher addition of fly ash or ground granulated blast-furnace slag improves the fluidity and delays the setting time of PG paste. The addition of 10 ~ 20 % fly ash results in a little reducing influence and 10 % ground granulated blast-furnace slag leads to an increase of 20.7 % for 28 days compressive strength of hardened PG specimen. The higher addition of Portland cement results in the better mechanical strength and water resistance of PG specimens. The 28day compressive and flexural strength reaches 25.9 MPa and 8.9 MPa respectively for the 25 % Portland cement mixture. PG based lightweight building materials can prepared by the addition of 60 % volume of air foam, with compressive strength of 1.7 MPa, bulk density of 521.7 kg/m3 and thermal conductivity of 0.0724 W/(m·K). DOI: http://dx.doi.org/10.5755/j01.ms.25.3.19910


2016 ◽  
Vol 711 ◽  
pp. 277-284 ◽  
Author(s):  
Walid A. Al-Kutti ◽  
Nabil M. Al-Akhras

This study investigates the durability of partially-damaged concrete with the addition of Silica Fume and Ground Granulated Blast Furnace Slag. Portland cement was replaced by 10% SF and 60% of GGBFS as a replacement of Portland cement. Thirty-six concrete cylinders (100 x 200 mm) were subjected to three compressive loading levels (50%, 75%, and 90% of its ultimate strength capacity). After 28 days of curing, the concrete specimens were experimentally tested for electrical resistivity, rapid chloride penetration (RCPT) and chloride migration coefficient (Dnssm) according to NT-BUILD 494. The experimental results showed that the GGBFS improves significantly the durability of concrete with the highest electrical resistivity and lowest chloride permeability compared to control and SF concrete and both SF and GGBFS had significant effect the concrete durability properties even when the concrete was subjected to compressive damage up to 90% of the compressive strength. A correlation between Dnssm and RCPT in partially damaged concrete was observed and an empirical linear relationship was developed to estimate Dnssm.


2020 ◽  
Vol 12 (14) ◽  
pp. 5783 ◽  
Author(s):  
Rosa Abnelia Rivera ◽  
Miguel Ángel Sanjuán ◽  
Domingo Alfonso Martín

Granulated blast-furnace slag (GBFS) and coal fly ash (CFA) are two well-known constituents in Portland cements. Ternary Portland cements (GBFS-CFA-K) provide environmental advantages by reducing Portland cement clinker (K) production and, therefore, promote lower CO2 emissions. Nevertheless, both of them cause a delay in the compressive strength gain. Given that, the early compressive strength for both constituents is low, but they improve the compressive strength at medium and later ages as consequence of the pozzolanic reaction. In this paper, a full factorial design with two levels was developed for the mortar compressive strength estimation at 2, 7 and 28 days. Mortar prisms made with 25% and 40% of granulated blast-furnace slag (GBFS) and/or coal fly ash (CFA) were tested. The effects of the interaction between GBFS and CFA on the compressive strength development of ternary Portland cement mortars were reported. Results show that the contribution of both cement constituents to the ternary mortar mix reduces the compressive strength for all the tested ages. Nevertheless, the finer the GBFS, the better ternary cement performance was achieved, showing that the synergistic effect is more effective when the finer GBFS is used, probably due to a more adequate particle size distribution. Finally, a relationship between compressive strength, fineness, GBFS content and CFA content was found for each age.


2018 ◽  
Vol 199 ◽  
pp. 02008
Author(s):  
Jacob Olumuyiwa Ikotun

This study presents the results of a project undertaken to study the combined effects of concrete quality (binder type, w/b, and duration of initial moist curing) and natural Johannesburg environment on carbonation rate of concretes containing 100% PC, 35% fly ash (FA), 50% ground granulated blast-furnace slag (BS), 10% silica fume (SF) and (30% BS + 10% SF). The results show that apart from the SF blended concretes, the carbonation rate of the SCM blended concretes are higher than the PC concretes. Reducing the w/b and increasing the duration of initial moist curing reduced the carbonation rate in the concretes. The indoor exposed concretes have the highest carbonation rates and reducing the w/b ratio is more efficient and sustainable in lowering the carbonation rate rather than extending the duration of the initial moist curing.


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