Alkali conversion of Ni-Co nanoarrays on carbon cloth for a high-capacity supercapacitor electrode

2017 ◽  
Vol 248 ◽  
pp. 322-332 ◽  
Author(s):  
Xuecun Shao ◽  
Xiaoyu Zheng ◽  
Wenru Zou ◽  
Yunli Luo ◽  
Qingchun Cen ◽  
...  
2019 ◽  
Vol 10 ◽  
pp. 1923-1932 ◽  
Author(s):  
Shengming Zhang ◽  
Xuhui Wang ◽  
Yan Li ◽  
Xuemei Mu ◽  
Yaxiong Zhang ◽  
...  

We have successfully prepared iron oxide and nickel oxide on carbon nanotubes on carbon cloth for the use in supercapacitors via a simple aqueous reduction method. The obtained carbon cloth–carbon nanotube@metal oxide (CC-CNT@MO) three-dimensional structures combine the high specific capacitance and rich redox sites of metal oxides with the large specific area and high electrical conductivity of carbon nanotubes. The prepared CC-CNT@Fe2O3 anode reaches a high capacity of 226 mAh·g−1 at 2 A·g−1 with a capacitance retention of 40% at 40 A·g−1. The obtained CC-CNT@NiO cathode exhibits a high capacity of 527 mAh·g−1 at 2 A·g−1 and an excellent rate capability with a capacitance retention of 78% even at 40 A·g−1. The all-solid-state asymmetric supercapacitor fabricated with these two electrodes delivers a high energy density of 63.3 Wh·kg−1 at 1.6 kW·kg−1 and retains 83% of its initial capacitance after 5000 cycles. These results demonstrate that our simple aqueous reduction method to combine CNT and metal oxides reveals an exciting future in constructing high-performance supercapacitors.


Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1676 ◽  
Author(s):  
Pianpian Ma ◽  
Na Lei ◽  
Bo Yu ◽  
Yongkun Liu ◽  
Guohua Jiang ◽  
...  

La-based perovskite-type oxide is a new type of supercapacitor electrode material with great potential. In the present study, LaMnO3/MnO (LMO/MnO) nano-arrays supported by carbon cloth are prepared via a simple one-step electrodeposition as flexible supercapacitor electrodes. The structure, deposit morphology of LMO/MnO, and the corresponding electrochemical properties have been investigated in detail. Carbon cloth-supported LMO/MnO electrode exhibits a specific capacitance of 260 F·g−1 at a current density of 0.5 A·g−1 in 0.5 M Na2SO4 aqueous electrolyte solution. The cooperative effects of LMO and MnO, as well as the uniform nano-array morphology contribute to the good electrochemical performance. In addition, a symmetric supercapacitor with a wide voltage window of 2 V is fabricated, showing a high energy density of 28.15 Wh·kg−1 at a power density of 745 W·kg−1. The specific capacitance drops to 65% retention after the first 500 cycles due to the element leaching effect and partial flaking of LMO/MnO, yet remains stable until 5000 cycles. It is the first time that La-based perovskite has been exploited for flexible supercapacitor applications, and further optimization is expected.


2019 ◽  
Vol 8 (1) ◽  
pp. 35-49 ◽  
Author(s):  
Zhenhui Li ◽  
Ke Xu ◽  
Yusheng Pan

Abstract Supercapacitor has gained significant attention due to its fast charging/discharging speed, high power density and long-term cycling stability in contrast to traditional batteries. In this review, state-of-the-art achievements on supercapacitor electrode based on carbon materials is summarized. In all-carbon composite materials part, various carbon materials including graphene, carbon nanotube, carbon foam and carbon cloth are composited to fabricate larger specific surface area and higher electrical conductivity electrodes. However, obstacles of low power density as well as low cycling life still remain to be addressed. In metal-oxide composites part, carbon nanotube, graphene, carbon fiber fabric and hollow carbon nanofibers combine with MnO2 respectively, which significantly address drawbacks of all-carbon material electrodes. Additionally, TiO2 is incorporated into graphene electrode to overcome the low mechanical flexibility of graphene. In organic active compounds part, conducting polymers are employed to combinate with carbon materials to fabricate high specific capacitance, long-term thermal stability and outstanding electroconductivity flexible textile supercapacitors. In each part, innovation, fabrication process and performance of the resulting composites are demonstrated. Finally, future directions that could enhance the performance of supercapacitors are discussed.


RSC Advances ◽  
2015 ◽  
Vol 5 (60) ◽  
pp. 48631-48637 ◽  
Author(s):  
Rui Ding ◽  
Hong Gao ◽  
MingYi Zhang ◽  
Jing Zhang ◽  
XiTian Zhang

Aspect ratio and electrochemical properties of the Ni3−xCoxS4can be controlled by manipulating the Co/Ni molar ratio.


2017 ◽  
Vol 2017 ◽  
pp. 1-8 ◽  
Author(s):  
Shuang Xi ◽  
Yinlong Zhu ◽  
Yutu Yang ◽  
Ying Liu

MnO2 nanorod/carbon cloth (MnO2/CC) composites were prepared through in situ redox deposition as freestanding electrodes for flexible supercapacitors. The CC substrates possessing porous and interconnecting structures enable the uniform decoration of MnO2 nanorods on each fiber, thus forming conformal coaxial micro/nanocomposites. Three-dimensional CC can provide considerable specific surface area for high mass loading of MnO2, and the direct deposition process without using polymeric binders enables reliable electrical connection of MnO2 with CC. The effect of MnO2 decoration on the electrochemical performances was further investigated, indicating that the electrode prepared with 40 min deposition time shows high specific capacitance (220 F/g at a scan rate of 5 mV/s) and good cycling property (90% of the initial specific capacitance was maintained after 2500 cycles) in 1 M Na2SO4 aqueous solution. This enhanced electrochemical performance is ascribed to the synergistic effect of good conductivity of carbon substrates as well as outstanding pseudocapacitance of MnO2 nanorods. The obtained MnO2/CC compositing electrode with the advantages of low cost and easy fabrication is promising in applications of flexible supercapacitors.


RSC Advances ◽  
2020 ◽  
Vol 10 (38) ◽  
pp. 22606-22615
Author(s):  
Junxian Li ◽  
Jianwei Zhao ◽  
Lirong Qin ◽  
Qitao Zhang ◽  
Xiaolan Tang ◽  
...  

A hierarchical Co(OH)2@NiMoS4 nanocomposite was prepared on the surface of carbon cloth, which exhibited good electrochemical performance as a supercapacitor electrode.


2019 ◽  
Vol 497 ◽  
pp. 143795 ◽  
Author(s):  
D. Narsimulu ◽  
Goli Nagaraju ◽  
S. Chandra Sekhar ◽  
Bhimanaboina Ramulu ◽  
Jae Su Yu

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