In China, sintering flue gas has become the most important source of air pollution rather than burning coal-fired flue gas.The emission characteristics and removal efficiencies of various gaseous pollutants were studiedon a 180 m2 sintering equipped with a semi-dry oxidative desulfurization and denitrification system in Tangshang, Hebei province. The emission concentrations of particulate matter, fluoride,NOX and SO2were measured in the flue gas whilepolychlorinated dibenzo-p-dioxins and dibenzofurans(PCDD/Fs) were tested in both flue gas and dust ash at 100% and 60% loadconditions. The collections and analyses ofpollutantswere used by smoke sampler, TESTO350 and dioxin sampleraccording to national standards of China. The results shown that the average emission concentration of particulate matter, fluoride, NOX and SO2 in the inlet of the flue gas purification system were 47.4 mg/m3, 0.12 mg/m3, 150 mg/m3 and 521 mg/m3 while the emission concentrations in the outlet were 1.2 mg/m3, 0.07 mg/m3, 24 mg/m3 and 20 mg/m3,respectively. Through the flue gas purification system, the PCDD/Fs concentrations were reduced from 23.12 ng/m3to 1.14 ng/m3at100% load and from 12.25 ng/m3 to 0.84 ng/m3at60% load. The PCDD/Fs concentrations in the dust ash were about 178.56~197.21 ng/kg. Thedesulfurization and denitrification system significant reduced effect on the emission of particulate matter, fluoride, NOX, SO2 and PCDD/Fs with the value 97.5%, 41.7%, 84.0%, 96.2% and 95.1% at 100% load, respectively.The removal affects increases along the chlorination degree of PCDD/Fs. Meanwhile,the different load influenced the emission concentrations and removal rates of PCDD/Fs in the flue gas, the removal effects increases as the load increases. Although the desulfurization and denitrification system has good removal effects on various pollutants, the dioxins were enriched in the dust ashso as to cause secondary pollution.