Thermodynamic performance limits of the organic Rankine cycle: Working fluid parameterization based on corresponding states modeling

2020 ◽  
Vol 217 ◽  
pp. 113011
Author(s):  
Fufang Yang ◽  
Fubin Yang ◽  
Qingfu Chu ◽  
Qiang Liu ◽  
Zhen Yang ◽  
...  
Keyword(s):  
Organic Rankine Cycle ◽  
Rankine Cycle ◽  
Corresponding States ◽  
Working Fluid ◽  
Performance Limits ◽  
Thermodynamic Performance

Performance Investigation of Solar Organic Rankine Cycle Systems With and Without Regeneration and With Zeotropic Working Fluid Mixtures for Use in Micro-Cogeneration

2020 ◽  
Author(s):  
Wahiba Yaïci ◽  
Evgueniy Entchev ◽  
Pouyan Talebizadeh Sardari
Keyword(s):  
Low Temperature ◽  
Heat Source ◽  
High Efficiency ◽  
Organic Rankine Cycle ◽  
Rankine Cycle ◽  
Industrial Wastes ◽  
Working Fluid ◽  
Condensation Temperature ◽  
Thermodynamic Performance ◽  
Cycle Efficiency

Abstract Globally there are several viable sources of renewable, low-temperature heat (below 130°C) particularly solar energy, geothermal energy, and energy generated from industrial wastes. Increased exploitation of these low-temperature options has the definite potential of reducing fossil fuel consumption with its attendant very harmful greenhouse gas emissions. Researchers have universally identified the organic Rankine cycle (ORC) as a practicable and promising system to generate electrical power from renewable sources based on its beneficial use of volatile organic fluids as working fluids (WFs). In recent times, researchers have also shown a preference for/an inclination towards deployment of zeotropic mixtures as ORC WFs because of their capacity to improve thermodynamic performance of ORC systems, a feat enabled by better matches of the temperature profiles of the WF and the heat source/sink. This paper demonstrates both the technical feasibility and the notable advantages of using zeotropic mixtures as WFs through a simulation study of an ORC system. The study examines the thermodynamic performance of ORC systems using zeotropic WF mixtures to generate electricity driven by low-temperature solar heat source for building applications. A thermodynamic model is developed with an ORC system both with and excluding a regenerator. Five zeotropic mixtures with varying compositions of R245fa/propane, R245fa/hexane, R245fa/heptane, pentane/hexane and isopentane/hexane are evaluated and compared to identify the best combinations of WF mixtures that can yield high efficiency in their system cycles. The study also investigates the effects of the volumetric flow ratio, and evaporation and condensation temperature glides on the ORC’s thermodynamic performance. Following a detailed analysis of each mixture, R245fa/propane is selected for parametric study to examine the effects of operating parameters on the system’s efficiency and sustainability index. For zeotropic mixtures, results showed that there is an optimal composition range within which binary mixtures are inclined to perform more efficiently than the component pure fluids. In addition, a significant increase in cycle efficiency can be achieved with a regenerative ORC, with cycle efficiency ranging between 3.1–9.8% and 8.6–17.4% for ORC both without and with regeneration, respectively. Results also showed that exploiting zeotropic mixtures could enlarge the limitation experienced in selecting WFs for low-temperature solar organic Rankine cycles.

Performance Investigation of Solar Organic Rankine Cycle System With Zeotropic Working Fluid Mixtures for Use in Micro-Cogeneration

2021 ◽  
Vol 143 (9) ◽  
Author(s):  
Wahiba Yaïci ◽  
Evgueniy Entchev ◽  
Pouyan Talebizadehsardari ◽  
Michela Longo
Keyword(s):  
Low Temperature ◽  
Power Output ◽  
Organic Rankine Cycle ◽  
Rankine Cycle ◽  
Working Fluid ◽  
Condensation Temperature ◽  
Source Temperature ◽  
Thermodynamic Performance ◽  
Net Power Output ◽  
Cycle Efficiency

Abstract Overall, there are numerous sustainable sources of renewable, low-temperature heat, principally solar energy, geothermal energy, and energy produced from industrial wastes. Extended utilization of these low-temperature alternatives has a certain capacity of decreasing fossil fuel use with its associated very hazardous greenhouse gas emissions. Researchers have commonly recognized the organic Rankine cycle (ORC) as a feasible and suitable system to produce electrical power from renewable sources based on its advantageous use of volatile organic fluids as working fluids (WFs). Researchers have similarly shown an affinity to the exploitation of zeotropic mixtures as ORC WFs due to their capability to enhance the thermodynamic performance of ORC systems, an achievement supported by improved fits of the temperature profiles of the WF and the heat source/sink. This paper determines both the technical feasibility and the benefits of using zeotropic mixtures as WFs by means of a simulation study of an ORC system. This study analyzes the thermodynamic performance of ORC systems using zeotropic WF mixtures to produce electricity driven by low-temperature solar heat sources for use in buildings. A thermodynamic model is created with an ORC system with and without a regenerator. Five zeotropic mixtures with diverse compositions between 0 and 1 in 0.2 increments of R245fa/propane, R245fa/hexane, R245fa/heptane, pentane/hexane, and isopentane/hexane are assessed and compared with identify the best blends of mixtures that are able to produce superior efficiency in their system cycles. Results disclosed that R245fa/propane (0.4/0.6) with regenerator produces the highest net power output of 7.9 kW and cycle efficiency of 9.4% at the operating condition with a hot source temperature of 85 °C. The study also investigates the effects of the volume flow ratio, and evaporation and condensation temperature glide on the ORC’s thermodynamic performance. Following a thorough analysis of each mixture, R245fa/propane is chosen for a parametric study to examine the effects of operating factors on the system’s efficiency and sustainability index. It was found that the highest cycle efficiency and highest second law cycle efficiency of around 10.5% and 84.0%, respectively, were attained with a mass composition of 0.6/0.4 at the hot source temperature of 95 °C and cold source temperature of 20 °C with a net power output of 9.6 kW. Moreover, results revealed that for zeotropic mixtures, there is an optimal composition range within which binary mixtures are tending to work more efficiently than the component pure fluids. In addition, a significant increase in cycle efficiency can be achieved with a regenerative ORC, with cycle efficiency in the range 3.1–9.8% versus 8.6–17.4% for ORC both without and with regeneration, respectively. In conclusion, utilizing zeotropic mixtures may well expand the restriction faced in choosing WFs for solar-powered ORC-based micro-combined heat and power (CHP) systems.

scholarly journals Thermodynamic, Economic and Sustainability Analysis of Solar Organic Rankine Cycle System with Zeotropic Working Fluid Mixtures for Micro-Cogeneration in Buildings

2020 ◽  
Vol 10 (21) ◽  
pp. 7925
Author(s):  
Wahiba Yaïci ◽  
Evgueniy Entchev ◽  
Pouyan Talebizadehsardari ◽  
Michela Longo
Keyword(s):  
Low Temperature ◽  
Heat Source ◽  
Organic Rankine Cycle ◽  
Rankine Cycle ◽  
Optimum Operating ◽  
Working Fluid ◽  
Condensation Temperature ◽  
Fluid Mixtures ◽  
Thermodynamic Performance ◽  
Cycle Efficiency

Globally there are several viable sources of renewable, low-temperature heat (below 130 °C), particularly solar energy, geothermal energy, and energy generated from industrial wastes. Increased exploitation of these low-temperature options has the definite potential of reducing fossil fuel consumption with its attendant very harmful greenhouse gas emissions. Researchers have universally identified the organic Rankine cycle (ORC) as a practicable and suitable system to generate electrical power from renewable sources based on its beneficial usage of volatile organic fluids as working fluids (WFs). In recent times, researchers have also shown a preference towards deployment of zeotropic mixtures as ORC WFs because of their capacity to improve thermodynamic performance of ORC systems, a feat enabled through the greater matching of the temperature profiles of the WF and the heat source/sink. This paper demonstrates the thermodynamic, economic and sustainability feasibility, and the notable advantages of using zeotropic mixtures as WFs through a simulation study of an ORC system. The study examines first the thermodynamic performance of ORC systems using zeotropic mixtures to generate electricity powered by a low-temperature solar heat source for building applications. A thermodynamic model is developed with a solar-driven ORC system both with and excluding a regenerator. Twelve zeotropic mixtures with varying compositions are evaluated and compared to identify the best combinations of mixtures that can yield high performance and high efficiency in their system cycles. The study also examines the effects of the volume flow ratio, and evaporation and condensation temperature glides on the ORC’s thermodynamic performance. Following a detailed analysis of each mixture, R245fa/propane and butane/propane are selected for parametric study to investigate the influence of operating parameters on the system’s efficiency and sustainability index. For zeotropic mixtures, results disclosed that there is an optimal composition range within which binary mixtures are inclined to perform more efficiently than the component pure fluids. In addition, a substantial enhancement in cycle efficiency can be obtained by a regenerative ORC, with cycle efficiency ranging between 3.1–9.8% and 8.6–17.4% for ORC both without and with regeneration, respectively. Results also revealed that exploiting zeotropic mixtures could enlarge the limitation experienced in selecting WFs for low-temperature solar ORCs. Moreover, a detailed economic with a sensitivity analysis of the solar ORC system was performed to evaluate the cost of the electricity and other economic criteria. The outcome of this investigation should be useful in the thermo-economic feasibility assessments of solar-driven ORC systems using working fluid mixtures to find the optimum operating range for maximum performance and minimum cost.

scholarly journals Conversion of Low-Grade Heat from Multiple Streams in Methanol to Olefin (MTO) Process Based on Organic Rankine Cycle (ORC)

2020 ◽  
Vol 10 (10) ◽  
pp. 3617 ◽  
Author(s):  
Danchen Wei ◽  
Cheng Liu ◽  
Zhongfeng Geng
Keyword(s):  
Organic Rankine Cycle ◽  
Rankine Cycle ◽  
Exergy Efficiency ◽  
Working Fluid ◽  
Low Grade ◽  
Maximum Output ◽  
Methanol To Olefin ◽  
Thermodynamic Performance ◽  
Selection Of ◽  
Mto Process

The organic rankine cycle (ORC) has been widely used to convert low-grade thermal energy to electricity. The selection of the cycle configuration, working fluid, and operating parameters is crucial for the economic profitability of the ORC system. In the methanol to olefin (MTO) process, multi-stream low-temperature waste heat has not been effectively utilized. The previous study mostly focused on the optimization of a single stream system and rarely considered the comprehensive optimization of multi-stream ORC systems which have multi-temperature heat sources. This paper proposes five kinds of system design schemes, and determines the optimal output work and the highest exergy efficiency through the selection of working fluid and optimization of system parameters. In addition, the influence of mixed working fluid on the thermodynamic performance of the system was also investigated. It is found that there is an optimal evaporation temperature due to the restriction of pinch temperature. At the optimal temperature the ORC system obtains the maximum net output power of 4.95 MW. The optimization results show that the working fluid R227EA selected from seven candidate working fluids shows the optimal thermodynamic performance in all the five design schemes, and obtains the maximum output work and exergy efficiency.

scholarly journals Thermodynamic Performance Analysis of an Improved Two-Stage Organic Rankine Cycle

Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2864 ◽  
Author(s):  
Xinyu Li ◽  
Tao Liu ◽  
Lin Chen
Keyword(s):  
Heat Exchange ◽  
Output Power ◽  
Thermal Efficiency ◽  
Organic Rankine Cycle ◽  
Rankine Cycle ◽  
Exergy Efficiency ◽  
Working Fluid ◽  
Outlet Temperature ◽  
Two Stage ◽  
Thermodynamic Performance

In order to improve the two-stage organic Rankine cycle of two heat exchanges of exhaust gas, a two-stage organic Rankine cycle with a regenerator is proposed. Toluene, benzene, cyclohexane and R245fa were selected as the working fluids of the cycle. The thermal efficiency, exergy efficiency and net output power of the cycle were selected as the objective function of the system. The influence of the regenerative performance on the thermodynamic performance of the system was analyzed. The influence of the temperature change of the primary heat exchange outlet on the thermodynamic performance of the system is discussed. The research shows that the regenerator can increase the net power and thermal efficiency of the cycle output. For the selected working fluid, as the efficiency of the regenerator increases, the thermal efficiency of the cycle and the net output power increase. When the primary heat exchange outlet temperature of the exhaust gas increases, the net output power and the exergy efficiency of the cycle increase. For the selected working fluid, when the exhaust heat exchange outlet temperature was increased from 410 K to 490 K, the net output power of the cycle increased up to 10.76 kW, and the exergy efficiency increased up to 7.85%.

scholarly journals Thermodynamic Performance Analysis of Turbine-Bleeding Organic Rankine Cycle with and without Regeneration

2018 ◽  
Vol 2 (1) ◽  
pp. 23-28
Author(s):  
Keyword(s):  
Performance Analysis ◽  
System Performance ◽  
Organic Rankine Cycle ◽  
Rankine Cycle ◽  
Inlet Pressure ◽  
Working Fluid ◽  
Low Grade ◽  
System Parameters ◽  
Turbine Inlet ◽  
Thermodynamic Performance

This paper presents a thermodynamic performance analysis of turbine-bleeding organic Rankine cycle (ORC) with and without regeneration using internal heat exchanger based on the first and second thermodynamic laws for the recovery of low-grade finite heat source. The effects of the important system parameters including turbine bleeding pressure, turbine inlet pressure, and working fluid on the system performance were intensively investigated. Results showed that there exists an optimum turbine bleeding pressure for the maximum second-law efficiency. The system performance under the optimal condition is significantly influenced by the turbine inlet pressure, regeneration, and working fluid. The greatest exergy destruction of the system varies depending on the system parameters.

Model, simulation and experiments for a Buoyancy Organic Rankine Cycle

2020 ◽  
Vol 92 (1) ◽  
pp. 10906
Author(s):  
Jeroen Schoenmaker ◽  
Pâmella Gonçalves Martins ◽  
Guilherme Corsi Miranda da Silva ◽  
Julio Carlos Teixeira
Keyword(s):  
Model Simulation ◽  
Organic Rankine Cycle ◽  
Thermodynamic Cycle ◽  
Rankine Cycle ◽  
Test Body ◽  
Working Fluid ◽  
Proof Of Concept ◽  
Energy Scenario ◽  
New Type ◽  
Fluid Reservoir

Organic Rankine Cycle (ORC) systems are increasingly gaining relevance in the renewable and sustainable energy scenario. Recently our research group published a manuscript identifying a new type of thermodynamic cycle entitled Buoyancy Organic Rankine Cycle (BORC) [J. Schoenmaker, J.F.Q. Rey, K.R. Pirota, Renew. Energy 36, 999 (2011)]. In this work we present two main contributions. First, we propose a refined thermodynamic model for BORC systems accounting for the specific heat of the working fluid. Considering the refined model, the efficiencies for Pentane and Dichloromethane at temperatures up to 100 °C were estimated to be 17.2%. Second, we show a proof of concept BORC system using a 3 m tall, 0.062 m diameter polycarbonate tube as a column-fluid reservoir. We used water as a column fluid. The thermal stability and uniformity throughout the tube has been carefully simulated and verified experimentally. After the thermal parameters of the water column have been fully characterized, we developed a test body to allow an adequate assessment of the BORC-system's efficiency. We obtained 0.84% efficiency for 43.8 °C working temperature. This corresponds to 35% of the Carnot efficiency calculated for the same temperature difference. Limitations of the model and the apparatus are put into perspective, pointing directions for further developments of BORC systems.

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