In this work, two cyclometalated ligands 2-(pyridin-2-yl)indolo[3,2,1-jk]carbazole (pyidcz) and 2-(4-(trifluoromethyl)pyridin-2-yl)indolo[3,2,1-jk]carbazole (tfpyidcz) using indolo[3,2,1-jk]carbazole unit were synthesized for highly efficient iridium(III) complexes (pyidcz)2Ir(tmd) and (tfpyidcz)2Ir(tmd) (tmd = 2,2,6,6-tetramethyl-3,5-heptanedione). The two Ir(III)...
AbstractAn efficient Cu-catalyzed synthesis of carbazole derivatives is reported, which proceeds by double C–N coupling reactions of 2,2′-dibromobiphenyl and amines in the presence of air. The reaction is robust, proceeds in high yields, and tolerates a series of amines including neutral, electron-rich, electron-deficient aromatic amines and aliphatic amines.
Herein, we report the first examples of N-polyaromatic compounds bearing up to 13 fused aromatic rings, including 23H-benzo[12,1]tetrapheno[8,9-b]benzo[12,1]tetrapheno[9,8-h]carbazole derivatives.
Robust, reliable and cost-effective paper-based analytical device for potentiometric pholcodine (opiate derivative drug) ion sensing has been prepared and characterized.
A metal–organic nanosystem constructed via coordination bonding-induced self-assembly is used for fluorescence and scattering ratiometric sensing of bromide and iodide ions.