PLGA nanoparticles loaded with quaternary ammonium silane and riboflavin for potential applications in adhesive dentistry

Various quaternary ammonium polyethylenimine (QA-PEI) derivatives have been synthesized in order to obtain nanoparticles. Due to their antibacterial activity and non-toxicity towards mammalian cells, the QA-PEI nanoparticles have been tested extensively regarding potential applications as biocidal additives in various dental composite materials. Their impact has been examined mostly for dimethacrylate-based restorative materials; however, dental cements, root canal pastes, and orthodontic adhesives have also been tested. Results of those studies showed that the addition of small quantities of QA-PEI nanoparticles, from 0.5 to 2 wt.%, led to efficient and long-lasting antibacterial effects. However, it was also discovered that the intensity of the biocidal activity strongly depended on several chemical factors, including the degree of crosslinking, length of alkyl telomeric chains, degree of N-alkylation, degree of N-methylation, counterion type, and pH. Importantly, the presence of QA-PEI nanoparticles in the studied dental composites did not negatively impact the degree of conversion in the composite matrix, nor its mechanical properties. In this review, we summarized these features and functions in order to present QA-PEI nanoparticles as modern and promising additives for dental materials that can impart unique antibacterial characteristics without deteriorating the products’ structures or mechanical properties.

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PLGA Nanoparticles Loaded with 1,10-epoxyparthenolide for Potential Applications in Tuberculosis Therapies

Microscopy and Microanalysis ◽

10.1017/s1431927618007560 ◽

2018 ◽

Vol 24 (S1) ◽

pp. 1416-1417

Author(s):

Karol Yesenia Hernández-Giottonini ◽

Cindy Alejandra Gutiérrez-Valenzuela ◽

Rosalva Josefina Rodríguez-Córdova ◽

Adriana Garibay-Escobar ◽

Paul Zavala-Rivera ◽

...

Keyword(s):

Plga Nanoparticles ◽

Potential Applications

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The Antioxidant Effect of PLGA Nanoparticles Encapsulated with Lutein in Rats Treated with Hypercaloric Diet

Materiale Plastice ◽

10.37358/mp.18.3.5015 ◽

2018 ◽

Vol 55 (3) ◽

pp. 291-294

Author(s):

Catalina Radulescu ◽

Daniela Miricescu ◽

Bogdan Calenic ◽

Radu Radulescu ◽

Iulia Stanescu ◽

...

Keyword(s):

Oxidative Stress ◽

Plga Nanoparticles ◽

Antioxidant Effect ◽

Oxidative Stress Parameters ◽

Cell Structures ◽

Oxidative Stress Status ◽

Potential Applications ◽

Vaccination Therapy ◽

Stress Damage ◽

Hypercaloric Diet

Poly lactic-co-glycolic acid (PLGA) is a biodegradable polymer that has been the focus of intense research due to its potential applications in medical research. Its uses in nanotechnology are underlined by its capability of targeting various cells and delivering active compounds to different human tissues. To date, PLGA nanoparticles are employed in areas such as vaccination therapy, diagnostic imaging procedure and various applications in various anticancer therapies. The aim of the present study is to measure and evaluate different correlations between oxidative stress parameters in spleen and liver following administration of nanoparticles encapsulated with lutein in an animal model. Our results show that acute oral administration of PLGA NPs induces a change in the oxidative stress status in both liver and spleen of rats, but does not induce oxidative stress damage to cell structures such as lipids or proteins.

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An in situ and ex situ TEM study of the formation of thin cobalt silicide films by molecular beam epitaxy on the silicon (100) surface

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010010648x ◽

1988 ◽

Vol 46 ◽

pp. 884-885

Author(s):

D. Loretto ◽

J. M. Gibson ◽

S. M. Yalisove ◽

R. T. Tung

Keyword(s):

Molecular Beam Epitaxy ◽

Molecular Beam ◽

Defect Density ◽

High Vacuum ◽

Ultra High Vacuum ◽

Ex Situ ◽

Metal Base ◽

In Situ Experiments ◽

Potential Applications

The cobalt disilicide/silicon system has potential applications as a metal-base and as a permeable-base transistor. Although thin, low defect density, films of CoSi2 on Si(111) have been successfully grown, there are reasons to believe that Si(100)/CoSi2 may be better suited to the transmission of electrons at the silicon/silicide interface than Si(111)/CoSi2. A TEM study of the formation of CoSi2 on Si(100) is therefore being conducted. We have previously reported TEM observations on Si(111)/CoSi2 grown both in situ, in an ultra high vacuum (UHV) TEM and ex situ, in a conventional Molecular Beam Epitaxy system.The procedures used for the MBE growth have been described elsewhere. In situ experiments were performed in a JEOL 200CX electron microscope, extensively modified to give a vacuum of better than 10-9 T in the specimen region and the capacity to do in situ sample heating and deposition. Cobalt was deposited onto clean Si(100) samples by thermal evaporation from cobalt-coated Ta filaments.

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Microstructure of laser-irradiated, conducting Kapton polyimide

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100138889 ◽

1995 ◽

Vol 53 ◽

pp. 502-503

Author(s):

D. L. Callahan ◽

Z. Ball ◽

H. M. Phillips ◽

R. Sauerbrey

Keyword(s):

Electron Microscopy ◽

Phase Transition ◽

Transmission Electron Microscopy ◽

Cross Section ◽

Film Surface ◽

Cross Sectional ◽

General Utility ◽

Transmission Electron ◽

Considerable Debate ◽

Potential Applications

Ultraviolet laser-irradiation can be used to induce an insulator-to-conductor phase transition on the surface of Kapton polyimide. Such structures have potential applications as resistors or conductors for VLSI applications as well as general utility electrodes. Although the percolative nature of the phase transformation has been well-established, there has been little definitive work on the mechanism or extent of transformation. In particular, there has been considerable debate about whether or not the transition is primarily photothermal in nature, as we propose, or photochemical. In this study, cross-sectional optical microscopy and transmission electron microscopy are utilized to characterize the nature of microstructural changes associated with the laser-induced pyrolysis of polyimide.Laser-modified polyimide samples initially 12 μm thick were prepared in cross-section by standard ultramicrotomy. Resulting contraction in parallel to the film surface has led to distortions in apparent magnification. The scale bars shown are calibrated for the direction normal to the film surface only.

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Fabrication and characterization - by High Resolution Electron Microscopy and atom probe microanalysis - of Co-based metallic multilayer films

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010017699x ◽

1990 ◽

Vol 48 (4) ◽

pp. 772-773

Author(s):

Amanda K. Petford-Long ◽

A. Cerezo ◽

M.G. Hetherington

Keyword(s):

Electron Microscopy ◽

High Resolution ◽

High Resolution Electron Microscopy ◽

Atom Probe ◽

Multilayer Films ◽

Interface Roughness ◽

Probe Field ◽

Resolution Electron ◽

Potential Applications ◽

Field Ion Microscope

The fabrication of multilayer films (MLF) with layer thicknesses down to one monolayer has led to the development of materials with unique properties not found in bulk materials. The properties of interest depend critically on the structure and composition of the films, with the interfacial regions between the layers being of particular importance. There are a number of magnetic MLF systems based on Co, several of which have potential applications as perpendicular magnetic (e.g Co/Cr) or magneto-optic (e.g. Co/Pt) recording media. Of particular concern are the effects of parameters such as crystallographic texture and interface roughness, which are determined by the fabrication conditions, on magnetic properties and structure.In this study we have fabricated Co-based MLF by UHV thermal evaporation in the prechamber of an atom probe field-ion microscope (AP). The multilayers were deposited simultaneously onto cobalt field-ion specimens (for AP and position-sensitive atom probe (POSAP) microanalysis without exposure to atmosphere) and onto the flat (001) surface of oxidised silicon wafers (for subsequent study in cross-section using high-resolution electron microscopy (HREM) in a JEOL 4000EX. Deposi-tion was from W filaments loaded with material in the form of wire (Co, Fe, Ni, Pt and Au) or flakes (Cr). The base pressure in the chamber was around 8×10−8 torr during deposition with a typical deposition rate of 0.05 - 0.2nm/s.

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Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries

Energy & Environmental Science ◽

10.1039/c9ee03828k ◽

2020 ◽

Vol 13 (5) ◽

pp. 1429-1461 ◽

Cited By ~ 21

Author(s):

Xiaona Li ◽

Jianwen Liang ◽

Xiaofei Yang ◽

Keegan R. Adair ◽

Changhong Wang ◽

...

Keyword(s):

Energy Storage ◽

Solid State ◽

Lithium Batteries ◽

Electrochemical Stability ◽

Superionic Conductors ◽

Fundamental Understanding ◽

Potential Applications ◽

Synthesis Routes

This review focuses on fundamental understanding, various synthesis routes, chemical/electrochemical stability of halide-based lithium superionic conductors, and their potential applications in energy storage as well as related challenges.

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Porphyrin-functionalized coordination star polymers and their potential applications in photodynamic therapy

Polymer Chemistry ◽

10.1039/c9py01391a ◽

2019 ◽

Vol 10 (45) ◽

pp. 6116-6121 ◽

Cited By ~ 3

Author(s):

Tan Ji ◽

Lei Xia ◽

Wei Zheng ◽

Guang-Qiang Yin ◽

Tao Yue ◽

...

Keyword(s):

Photodynamic Therapy ◽

Self Assembly ◽

Star Polymers ◽

New Family ◽

Potential Applications

We present a new family of porphyrin-functionalized coordination star polymers prepared through combination of coordination-driven self-assembly and post-assembly polymerization. Their self-assembly behaviour in water and potential for photodynamic therapy were demonstrated.

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Catalyst- and oxidant-free electrochemical para-selective hydroxylation of N-arylamides in batch and continuous-flow

Green Chemistry ◽

10.1039/d0gc02294b ◽

2020 ◽

Vol 22 (19) ◽

pp. 6437-6443

Author(s):

Cheng-Kou Liu ◽

Meng-Yi Chen ◽

Xin-Xin Lin ◽

Zheng Fang ◽

Kai Guo

Keyword(s):

Ammonium Salt ◽

Quaternary Ammonium ◽

Continuous Flow ◽

Quaternary Ammonium Salt ◽

Selective Hydroxylation

A catalyst-, oxidant-, acidic solvent- and quaternary ammonium salt-free electrochemical para-selective hydroxylation of N-arylamides at rt in batch and continuous-flow was developed.

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