Eu3+-to-Cr3+ energy transfer for the improved Cr3+- characteristic near-infrared (NIR) phosphorescence in the Cr(III)-Eu(III)-Salen complex

Author(s):  
Siyu Hou ◽  
Yan Guo ◽  
Yan Zhang ◽  
Baowen Wang ◽  
Wentao Li ◽  
...  
2021 ◽  
Vol 57 (15) ◽  
pp. 1927-1930
Author(s):  
Zhao Gao ◽  
Lulu Shi ◽  
Xiao Ling ◽  
Ze Chen ◽  
Qingsong Mei ◽  
...  

A hybrid supramolecular system with near-infrared photon-excited energy transfer has been successfully constructed, relying on the assistance of upconversion nanoparticles in platinum(ii)-based supramolecular polymers.


2021 ◽  
pp. 118170
Author(s):  
Jia Cui ◽  
Panlai Li ◽  
Lingwei Cao ◽  
Xuejiao Wang ◽  
Yao Yao ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 937
Author(s):  
Katarzyna Halubek-Gluchowska ◽  
Damian Szymański ◽  
Thi Ngoc Lam Tran ◽  
Maurizio Ferrari ◽  
Anna Lukowiak

Looking for upconverting biocompatible nanoparticles, we have prepared by the sol–gel method, silica–calcia glass nanopowders doped with different concentration of Tm3+ and Yb3+ ions (Tm3+ from 0.15 mol% up to 0.5 mol% and Yb3+ from 1 mol% up to 4 mol%) and characterized their structure, morphology, and optical properties. X-ray diffraction patterns indicated an amorphous phase of the silica-based glass with partial crystallization of samples with a higher content of lanthanides ions. Transmission electron microscopy images showed that the average size of particles decreased with increasing lanthanides content. The upconversion (UC) emission spectra and fluorescence lifetimes were registered under near infrared excitation (980 nm) at room temperature to study the energy transfer between Yb3+ and Tm3+ at various active ions concentrations. Characteristic emission bands of Tm3+ ions in the range of 350 nm to 850 nm were observed. To understand the mechanism of Yb3+–Tm3+ UC energy transfer in the SiO2–CaO powders, the kinetics of luminescence decays were studied.


2011 ◽  
Vol 131 (1) ◽  
pp. 134-137 ◽  
Author(s):  
Jian-Xin Meng ◽  
Wen-Jiao Wan ◽  
Li-Li Fan ◽  
Chuang-Tao Yang ◽  
Qing-Qing Chen ◽  
...  

2000 ◽  
Vol 15 (2) ◽  
pp. 278-281 ◽  
Author(s):  
Yong Gyu Choi ◽  
Kyong Hon Kim ◽  
Yong Seop Han ◽  
Jong Heo

We have demonstrated that an efficient energy transfer takes place from Yb3+ to Cr4+ in calcium aluminate glasses. Yb3+ improves excitation efficiency at around 980 nm, enhancing emission intensity of Cr4+ fluorescence at 1.2–1.6 μm. Nonradiative energy transfer via electric dipole–dipole interaction between ytterbium and chromium ions was found to be dominant over radiative Yb3+ → Cr4+ energy transfer. A diffusionlimited energy transfer mechanism well explains the decay behavior of Yb3+/Cr4+- codoped glasses. This codoping scheme may be applicable to other Cr4+-containing crystals and glasses.


2011 ◽  
Vol 11 (11) ◽  
pp. 9543-9549 ◽  
Author(s):  
Xueqin Cao ◽  
Li Li ◽  
Xiantao Wei ◽  
Yonghu Chen ◽  
Weiping Zhang ◽  
...  

2016 ◽  
Vol 45 (1) ◽  
pp. 78-84 ◽  
Author(s):  
Tuhin Samanta ◽  
Shyam Sarkar ◽  
Venkata. N. K. B. Adusumalli ◽  
Athma E. Praveen ◽  
Venkataramanan Mahalingam

We report the enhancement of both visible and near infrared (NIR) emissions from Nd3+ionsviaCe3+sensitization in colloidal nanocrystals for the first time.


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