Non-linear kinetic analysis on GaAs selective area MOVPE combined with macro-scale analysis to extract major reaction mechanism

2007 ◽  
Vol 298 ◽  
pp. 32-36 ◽  
Author(s):  
Haizheng Song ◽  
Ik-Tae Im ◽  
Masakazu Sugiyama ◽  
Yoshiaki Nakano ◽  
Yukihiro Shimogaki
1999 ◽  
Vol 39 (4) ◽  
pp. 301-308 ◽  
Author(s):  
Tao Xiaojie ◽  
Hiroyuki Fukuyama ◽  
Masahiro Susa ◽  
Kazuhiro Nagata

2017 ◽  
Vol 19 (5) ◽  
pp. 3606-3615 ◽  
Author(s):  
Alexey L. Pomerantsev ◽  
Alla V. Kutsenova ◽  
Oxana Ye. Rodionova

A novel non-linear regression method for modeling non-isothermal thermogravimetric data is proposed.


2008 ◽  
Vol 3 (1) ◽  
Author(s):  
Ik-Tae Im ◽  
Masakazu Sugiyama ◽  
Yukihiro Shimogaki ◽  
Yoshyaki Nakano

As a successive work to clarify the film growth kinetics of GaAs, a new lumped model for computer simulation of film growth during MOCVD process is proposed. The film growth process in a horizontal reactor using trimethylgallium (TMGa) and tertiarybutylarsine (TBAs) is considered. Analyzing methodologies at two different scales have been used to revise our previous simulation model. One is the micro-scale analysis using a selective-area growth method and the other is the reactor-scale macro analysis using numerical simulation. Species concentration profiles are obtained from the macro-scale computational fluid dynamics study incorporated with chemical reactions. Surface reaction rate constants are extracted from the selective-area growth experiments. From the multi-scale analysis that combined the two-scale analyses, surface formation from the source gas, TMGa, is included to the previous model. The kinetic data for the surface reaction of TMGa are deduced from the quantitative analysis for the species concentrations from both of the analyses. Simulation results using the new model show that monomethylgallium is the major source of film deposition, but deposition from TMGa is important in the upstream region of the reactor.


2008 ◽  
Vol 1 ◽  
pp. 071102 ◽  
Author(s):  
Tomonari Shioda ◽  
Masakazu Sugiyama ◽  
Yukihiro Shimogaki ◽  
Yoshiaki Nakano

2014 ◽  
Vol 624 ◽  
pp. 70-75 ◽  
Author(s):  
M. Ogawa ◽  
R.-Y. Liu ◽  
C.-H. Lin ◽  
S. Yamamoto ◽  
R. Yukawa ◽  
...  

2005 ◽  
Vol 70 (8-9) ◽  
pp. 1105-1111 ◽  
Author(s):  
P. Prakash ◽  
Mary Francisca

A kinetic analysis of the reaction between peracetic acid (AcOOH), and tetrakis (pentafluorophenyl) - 21H, 23H-porphine iron(III) chloride Fe(F20TPP)Cl, in acetonitrile showed that the peracetic acid oxidatively destroys Fe(F20TPP)Cl. This is in contrast to an assumption that the oxidative degradation of metalloporphyrins can be prevented by the introduction of electron-withdrawing substituents into the phenyl groups of the porphyrin ligand. A UV-visible spectroscopic study showed a degree of macro cycle destruction of the tetrapyrrole conjucation of the metalloporphyrin. The degradation takes place via oxoperferryl species. The first step of the reaction mechanism is the reversible formation of an adduct ?X? (k1/k-1) between Fe(F20TPP)Cl and peracetic acid, followed by an irreversible step (k2) for the formation of oxoperferryl species.


2018 ◽  
Vol 13 (4) ◽  
pp. 691-701 ◽  
Author(s):  
Katsumi Matsushima ◽  
Makoto Hyodo ◽  
Noriyuki Shibata ◽  
Yoshihiro Shimizu ◽  
◽  
...  

A field demonstration project on flexible dam operation at the Managawa dam in the Kuzuryu River Basin has been implemented since 2000. The goal is to restore flow and sediment regimes in the Managawa River, which flows along the Ono-city and is located below the dam. Flexible dam operation stores inflow discharge into a reservoir, which generally uses part of the flood control capacity and appropriately discharges the stored water to the river, also known as the “flood pulse,” for restoring dynamic fluvial systems and the resulting ecological processes. In addition, other options have been carried out in combination with flexible dam operation, for example, sediment replenishment since 2003 and channel rehabilitation since 2007. This article reveals the positive impacts and effectiveness of flexible dam operation, sediment replenishment, and channel rehabilitation, and discusses challenges and future prospects toward translating the field demonstration project into dam management on the ground level. First, we classified reach types to identify the impact of various management options, e.g., flexible dam operation, sediment replenishment, and channel rehabilitation. These management options can influence respected reaches. We conducted a macro-scale analysis to understand the relationship between the aforementioned management options and dynamic fluvial systems, addressing changes in gravel riverbed, vegetation, and habitat types (riffles and pools). Second, a micro-scale analysis was conducted to understand the relationship between the management option and changes in attached algae to sediment and macro-invertebrates, etc. The results show the effectiveness of the middle-scale flood pulse to restore dynamic fluvial systems, increase habitat diversity, and sustain ecological processes. Furthermore, we discussed the impacts of such options on the flow and sediment regimes in Managawa River and revealed that flexible dam operation reduces the occurrence of low flow and midscale floods. It was also revealed methods such as sediment replenishment and channel rehabilitation play an important role in increasing the effectiveness of the middle-scale flood pulse and restoring dynamic fluvial systems, even though sediment replenishment is not sufficient to restore sediment regimes (i.e., bring then back to pre-dam conditions).


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