The effect of lid driven convective transport on lateral solute segregation in the vicinity of a crucible wall

2012 ◽  
Vol 361 ◽  
pp. 195-200 ◽  
Author(s):  
J.P. Garandet ◽  
N. Kaupp ◽  
D. Pelletier
Keyword(s):  
Solute Segregation ◽  
Convective Transport ◽  
Crucible Wall

High-resolution x-ray analysis of dislocation networks nn tilt boundaries

1988 ◽  
Vol 46 ◽  
pp. 612-613
Author(s):  
J. R. Michael ◽  
C. H. Lin ◽  
S. L. Sass
Keyword(s):  
Grain Boundaries ◽  
Analytical Electron Microscopy ◽  
Solute Segregation ◽  
X Ray ◽  
Periodic Arrays ◽  
Analytical Electron ◽  
Primary Dislocation ◽  
Tilt Boundaries ◽  
Polycrystalline Solids ◽  
Twist Boundaries

The segregation of solute atoms to grain boundaries in polycrystalline solids can be responsible for embrittlement of the grain boundaries. Although Auger electron spectroscopy (AES) and analytical electron microscopy (AEM) have verified the occurrence of solute segregation to grain boundaries, there has been little experimental evidence concerning the distribution of the solute within the plane of the interface. Sickafus and Sass showed that Au segregation causes a change in the primary dislocation structure of small angle [001] twist boundaries in Fe. The bicrystal specimens used in their work, which contain periodic arrays of dislocations to which Au is segregated, provide an excellent opportunity to study the distribution of Au within the boundary by AEM.The thin film Fe-0.8 at% Au bicrystals (composition determined by Rutherford backscattering spectroscopy), ∼60 nm thick, containing [001] twist boundaries were prepared as described previously. The bicrystals were analyzed in a Vacuum Generators HB-501 AEM with a field emission electron source and a Link Analytical windowless x-ray detector.

Mass Transport Modelling in Porous Media Using Delay Differential Equations

2006 ◽  
Vol 258-260 ◽  
pp. 586-591
Author(s):  
António Martins ◽  
Paulo Laranjeira ◽  
Madalena Dias ◽  
José Lopes
Keyword(s):  
Porous Media ◽  
Differential Equations ◽  
Mass Transport ◽  
Delay Differential Equations ◽  
Dispersion Model ◽  
Flow Characteristics ◽  
Convective Transport ◽  
Transport Modelling ◽  
Flow Field Characteristics ◽  
Delay Differential

In this work the application of delay differential equations to the modelling of mass transport in porous media, where the convective transport of mass, is presented and discussed. The differences and advantages when compared with the Dispersion Model are highlighted. Using simplified models of the local structure of a porous media, in particular a network model made up by combining two different types of network elements, channels and chambers, the mass transport under transient conditions is described and related to the local geometrical characteristics. The delay differential equations system that describe the flow, arise from the combination of the mass balance equations for both the network elements, and after taking into account their flow characteristics. The solution is obtained using a time marching method, and the results show that the model is capable of describing the qualitative behaviour observed experimentally, allowing the analysis of the influence of the local geometrical and flow field characteristics on the mass transport.

scholarly journals Control of Oxygen Impurities in a Continuous-Feeding Czochralski-Silicon Crystal Growth by the Double-Crucible Method

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 264
Author(s):  
Wenhan Zhao ◽  
Jiancheng Li ◽  
Lijun Liu
Keyword(s):  
Oxygen Concentration ◽  
Silicon Crystal ◽  
Cost Effective ◽  
Czochralski Method ◽  
Crucible Wall ◽  
Oxygen Impurity ◽  
Continuous Feeding ◽  
The Impact ◽  
Oxygen Impurities ◽  
Crystal Interface

The continuous-feeding Czochralski method is a cost-effective method to grow single silicon crystals. An inner crucible is used to prevent the un-melted silicon feedstock from transferring to the melt-crystal interface in this method. A series of global simulations were carried out to investigate the impact of the inner crucible on the oxygen impurity distributions at the melt-crystal interface. The results indicate that, the inner crucible plays a more important role in affecting the O concentration at the melt-crystal interface than the outer crucible. It can prevent the oxygen impurities from being transported from the outer crucible wall effectively. Meanwhile, it also introduces as a new source of oxygen impurity in the melt, likely resulting in a high oxygen concentration zone under the melt-crystal interface. We proposed to enlarge the inner crucible diameter so that the oxygen concentration at the melt-crystal interface can be controlled at low levels.

Origin of twin-like {336¯4} tilt boundary and associated solute segregation in a high strain rate deformed Mg-Y alloy

2021 ◽  
Vol 201 ◽  
pp. 113982
Author(s):  
Huan Zhang ◽  
Yangxin Li ◽  
Zhigang Ding ◽  
Tian Xie ◽  
Ruixue Liu ◽  
...  
Keyword(s):  
High Strain Rate ◽  
Strain Rate ◽  
High Strain ◽  
Solute Segregation ◽  
Tilt Boundary

An atom probe tomography study of grain boundary segregation in nanocrystalline Ni-W

2005 ◽  
Vol 903 ◽  
Author(s):  
Andrew Detor ◽  
Michael K. Miller ◽  
Christopher A. Schuh
Keyword(s):  
Grain Boundary ◽  
Atom Probe Tomography ◽  
Boundary Segregation ◽  
Atom Probe ◽  
Solute Segregation ◽  
Grain Boundary Segregation ◽  
Distribution Analysis ◽  
Grain Sizes ◽  
Composition Fluctuations ◽  
20 Nm

AbstractAtom probe tomography is used to observe the solute distribution in electrodeposited nanocrystalline Ni-W alloys with three different grain sizes (3, 10, and 20 nm) and the results are compared with atomistic computer simulations. The presence of grain boundary segregation is confirmed by detailed analysis of composition fluctuations in both experimental and simulated structures, and its extent quantified by a frequency distribution analysis. In contrast to other nanocrystalline alloys, the present Ni-W alloys exhibit only a subtle amount of solute segregation to the intergranular regions. This finding is consistent with quantitative predictions for these alloys based upon a thermodynamic model of grain boundary segregation.

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