A comparative study of liquid–liquid equilibria for aqueous mixtures of straight chain and branched chain carboxylic acids with methyl isobutyl carbinol

2020 ◽  
Vol 143 ◽  
pp. 106026 ◽  
Author(s):  
A. Ghanadzadeh Gilani ◽  
F. Amouzadeh ◽  
B. Ghalami-Choobar
Keyword(s):  
Comparative Study ◽  
Carboxylic Acids ◽  
Aqueous Mixtures ◽  
Methyl Isobutyl ◽  
Straight Chain ◽  
Branched Chain

Exploring substrate scope and stereoselectivity of P450 peroxygenase OleTJEin olefin-forming oxidative decarboxylation

2016 ◽  
Vol 52 (52) ◽  
pp. 8131-8133 ◽  
Author(s):  
Jian-bo Wang ◽  
Richard Lonsdale ◽  
Manfred T. Reetz
Keyword(s):  
Carboxylic Acids ◽  
Oxidative Decarboxylation ◽  
Straight Chain

The substrate scope of the mild olefin-forming oxidative decarboxylation of straight-chain C4–C22carboxylic acids catalyzed by P450 peroxygenase OleTJEhas been extended to include structurally diverse carboxylic acids.

scholarly journals The Peroxisomal Acyl-CoA Thioesterase Pte1p fromSaccharomyces cerevisiaeIs Required for Efficient Degradation of Short Straight Chain and Branched Chain Fatty Acids

2006 ◽  
Vol 281 (17) ◽  
pp. 11729-11735 ◽  
Author(s):  
Isamu Maeda ◽  
Syndie Delessert ◽  
Seiko Hasegawa ◽  
Yoshiaki Seto ◽  
Sophie Zuber ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Straight Chain ◽  
Branched Chain Fatty Acids ◽  
Branched Chain ◽  
Chain Fatty Acids

scholarly journals The homogeneous unimolecular decomposition of gaseous alkyl nitrites - IV—The decomposition of Iso -propyl nitrite

1935 ◽  
Vol 151 (874) ◽  
pp. 685-693 ◽  
Keyword(s):  
Activation Energy ◽  
Thermal Decomposition ◽  
Pressure Change ◽  
Methyl Ethyl ◽  
Unimolecular Decomposition ◽  
Decomposition Rates ◽  
Straight Chain ◽  
Alkyl Nitrites ◽  
Branched Chain ◽  
Reaction Vessels

It has already been shown that the first three straight chain members of the nitrite homologous series, i. e ., methyl, ethyl, and n -propyl nitrites, have exhibited in their thermal decomposition the characteristics pertaining to homogeneous unimolecular reactions. This paper deals with the investigation carried out on iso -propyl nitrite decomposition. This member of the series is particularly interesting as it allows comparison to be made between a straight-chain and a branched-chain isomer. The effect of these chemical configurations on the activation energy and the decomposition rates can be very effectively studies as no complications enter into the reactions to confuse measurements. Experimental Reaction velocities were measured as before by observing the rate of pressure change in a system at constant volume. The reaction vessels were Pyrex glass bulbs with a capacity of about 125 cc. The apparatus was similar to that used in previous experiments. The connecting tubing was heated to 105° C to prevent any of the products of the reaction condensing out. Control and measurement of the temperature was carried out as before. The temperature could be maintained constant to within 0·25° C.

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