scholarly journals Rare earth elements in uranium ore deposits from Namibia: A nuclear forensics tool

2021 ◽  
Vol 237 ◽  
pp. 106668
Author(s):  
Dakalo Madzunya ◽  
Vera Uushona ◽  
Manny Mathuthu ◽  
Wanke Heike
Author(s):  
Xiaotong Ding ◽  
Wenting Bu ◽  
Youyi Ni ◽  
Xuepeng Shao ◽  
Ke Xiong ◽  
...  

The distribution of rare earth elements (REEs) in nuclear ore samples provided basic and important information for nuclear forensics. A method was developed for the determination of REEs in uranium...


Minerals ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 55 ◽  
Author(s):  
Veronica C. Bradley ◽  
Benjamin T. Manard ◽  
Benjamin D. Roach ◽  
Shalina C. Metzger ◽  
Kayron T. Rogers ◽  
...  

The determination of trace elements, particularly rare earth elements, in uranium ore concentrates (UOCs) is important as the pattern can be indictive ore characteristics. Presented here is a methodology for accurately quantifying rare earth elements (REE) in UOCs. To improve the measurement uncertainty, isotope dilution mass spectrometry (IDMS) was utilized over other quantification techniques such as external calibration or standard addition. The isotopic determinations were measured by inductively coupled plasma-mass spectrometry (ICP-MS). To obtain high-fidelity isotopic measurements, separation of the REE from the uranium matrix was achieved by high-performance ion chromatography (HPIC), reducing the isobaric interferences. After separation, the target analytes were analyzed in two different modalities. For high precision analysis, the separated analytes were collected and measured by ICP-MS in an “offline” fashion. For a rapid approach, the separated analytes were sent directly into an ICP-MS for “online” analysis. These methods have been demonstrated to accurately quantify the REE content in a well-characterized UOC sample.


Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 455 ◽  
Author(s):  
Claire McLeod ◽  
Barry Shaulis

The abundance of the rare earth elements (REEs) in Earth’s crust has become the intense focus of study in recent years due to the increasing societal demand for REEs, their increasing utilization in modern-day technology, and the geopolitics associated with their global distribution. Within the context of chemically evolved igneous suites, 122 REE deposits have been identified as being associated with intrusive dike, granitic pegmatites, carbonatites, and alkaline igneous rocks, including A-type granites and undersaturated rocks. These REE resource minerals are not unlimited and with a 5–10% growth in global demand for REEs per annum, consideration of other potential REE sources and their geological and chemical associations is warranted. The Earth’s moon is a planetary object that underwent silicate-metal differentiation early during its history. Following ~99% solidification of a primordial lunar magma ocean, residual liquids were enriched in potassium, REE, and phosphorus (KREEP). While this reservoir has not been directly sampled, its chemical signature has been identified in several lunar lithologies and the Procellarum KREEP Terrane (PKT) on the lunar nearside has an estimated volume of KREEP-rich lithologies at depth of 2.2 × 108 km3. This reservoir therefore offers a prospective location for future lunar REE exploration. Within the context of chemically evolved lithologies, lunar granites are rare with only 22 samples currently classified as granitic. However, these extraterrestrial granites exhibit chemical affinities to terrestrial A-type granites. On Earth, these anorogenic magmatic systems are hosts to U-Th-REE-ore deposits and while to date only U-Th regions of enrichment on the lunar surface have been identified, future exploration of the lunar surface and interior may yet reveal U-Th-REE regions associated with the distribution of these chemically distinct, evolved lithologies.


Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 860
Author(s):  
Konstantina Pyrgaki ◽  
Vasiliki Gemeni ◽  
Christos Karkalis ◽  
Nikolaos Koukouzas ◽  
Petros Koutsovitis ◽  
...  

Μining waste, processing by-products and mine water discharges pose a serious threat to the environment as in many cases they contain high concentrations of toxic substances. However, they may also be valuable resources. The main target of the current review is the comparative study of the occurrence of rare earth elements (REE) in mining waste and mine water discharges produced from the exploitation of coal, bauxite, phosphate rock and other ore deposits. Coal combustion ashes, bauxite residue and phosphogypsum present high percentages of critical REEs (up to 41% of the total REE content) with ΣREY content ranging from 77 to 1957.7 ppm. The total REE concentrations in mine discharges from different coal and ore mining areas around the globe are also characterised by a high range of concentrations from 0.25 to 9.8 ppm and from 1.6 to 24.8 ppm, respectively. Acid mine discharges and their associated natural and treatment precipitates seem to be also promising sources of REE if their extraction is coupled with the simultaneous removal of toxic pollutants.


2020 ◽  
pp. 42-46
Author(s):  
A. O. Kalashnikov ◽  
◽  
N. G. Konopleva ◽  
G. Yu. Ivanyuk ◽  
◽  
...  

Minerals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1012
Author(s):  
Liu Xiqiang ◽  
Zhang Hui ◽  
Tang Yong ◽  
Liu Yunlong

Phosphorite-type rare earth deposits, which are one of the important types of rare earth elements (REE) ore deposits, have attracted increasing attention because of the extreme enrichments in heavy rare earth elements (HREE), including Yttrium (Y). In this study, in situ geochemical analyses of apatite grains from Zhijin phosphorites were conducted using electron probe microanalysis (EMPA) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Based on EPMA mapping analysis, we show that rare earth elements and Yttrium (REY) entering into the crystal lattice by isomorphism rather than by inclusions of REY-bearing accessory minerals. The post-Archean Australian Shales (PAAS)-normalized REY patterns of the apatite grains are characterized by hat-shaped MREE-enriched patterns. We interpret that this pattern may reflect the REE distribution of seawater at that time. We propose that in a local, reducing environment, dramatically increased the concentration of REY in seawater, and resulted in the MREE-enriched patterns in the ancient ocean. The main mechanism for the genesis of the Zhijin phosphorite deposit is the apatite crystallizes during the mixing process of REY- and P-rich fluid and oxidizing seawater.


1988 ◽  
Vol 22 (2) ◽  
pp. 47-54 ◽  
Author(s):  
Hiroshi Hidaka ◽  
Akimasa Masuda ◽  
Isao Fujii ◽  
Hiroshi Shimizu

1984 ◽  
Vol 21 (7) ◽  
pp. 775-780 ◽  
Author(s):  
D. F. Strong

Rare earth elements (REE) were determined for 57 samples representative of the range of stratigraphic units, both mineralized and unmineralized, associated with the high-grade polymetallic volcanogenic sulphide deposits at Buchans, Newfoundland. These data do not indicate any features indicative of magmatic fractionation processes, e.g., enrichment of total REE or any europium depletion anomaly, in the mineralized relative to the unmineralized volcanics, suggesting that such processes did not play an important role in the formation of these ore deposits. These results also emphasize the need for caution in any attempts to use the rare earth elements as a general tool for discrimination between barren and mineralized volcanic sequences.


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