A porous biochar supported nanoscale zero-valent iron material highly efficient for the simultaneous remediation of cadmium and lead contaminated soil

2022 ◽  
Vol 113 ◽  
pp. 231-241
Author(s):  
Wei Qian ◽  
Jing-Yi Liang ◽  
Wen-Xuan Zhang ◽  
Shi-Ting Huang ◽  
Zeng-Hui Diao
Keyword(s):  
Contaminated Soil ◽  
Zero Valent Iron ◽  
Highly Efficient ◽  
Nanoscale Zero Valent Iron ◽  
Cadmium And Lead ◽  
Iron Material

scholarly journals Application of nanoscale zero-valent iron in hexavalent chromium-contaminated soil: A review

2020 ◽  
Vol 9 (1) ◽  
pp. 736-750
Author(s):  
Xilu Chen ◽  
Xiaomin Li ◽  
Dandan Xu ◽  
Weichun Yang ◽  
Shaoyuan Bai
Keyword(s):  
Heavy Metal ◽  
Hexavalent Chromium ◽  
Contaminated Soil ◽  
Zero Valent Iron ◽  
Toxic Heavy Metal ◽  
Factors Affecting ◽  
Metal Pollutants ◽  
Nanoscale Zero Valent Iron ◽  
Low Toxicity ◽  
Heavy Metal Pollutants

AbstractChromium (Cr) is a common toxic heavy metal that is widely used in all kinds of industries, causing a series of environmental problems. Nanoscale zero- valent iron (nZVI) is considered to be an ideal remediation material for contaminated soil, especially for heavy metal pollutants. As a material of low toxicity and good activity, nZVI has been widely applied in the in situ remediation of soil hexavalent chromium (Cr(vi)) with mobility and toxicity in recent years. In this paper, some current technologies for the preparation of nZVI are summarized and the remediation mechanism of Cr(vi)-contaminated soil is proposed. Five classified modified nZVI materials are introduced and their remediation processes in Cr(vi)-contaminated soil are summarized. Key factors affecting the remediation of Cr(vi)-contaminated soil by nZVI are studied. Interaction mechanisms between nZVI-based materials and Cr(vi) are explored. This study provides a comprehensive review of the nZVI materials for the remediation of Cr(vi)-contaminated soil, which is conducive to reducing soil pollution.

scholarly journals Highly efficient and rapid removal of arsenic(iii) from aqueous solutions by nanoscale zero-valent iron supported on a zirconium 1,4-dicarboxybenzene metal–organic framework (UiO-66 MOF)

RSC Advances ◽  
2019 ◽  
Vol 9 (67) ◽  
pp. 39475-39487 ◽  
Author(s):  
Tingyi Liu ◽  
Zhengchao Zhang ◽  
Zhaohui Wang ◽  
Zhong-Liang Wang ◽  
Richard Bush
Keyword(s):  
Aqueous Solutions ◽  
Metal Organic Framework ◽  
Zero Valent Iron ◽  
Highly Efficient ◽  
Nanoscale Zero Valent Iron ◽  
Metal Organic ◽  
Rapid Removal ◽  
Removal Of Arsenic ◽  
Organic Framework

A zirconium 1,4-dicarboxybenzene metal–organic framework (UiO-66 MOF) was successfully used as a template to enhance the distribution and activity of nanoscale zero-valent iron (NZVI).

scholarly journals A porous biochar supported nanoscale zero-valent iron highly efficient for the remediation of cadmium and lead contaminated soil

2021 ◽  
Author(s):  
Wei Qian ◽  
Zeng-Hui Diao
Keyword(s):  
Heavy Metals ◽  
Clayey Soil ◽  
Zero Valent Iron ◽  
Nanoscale Zero Valent Iron ◽  
Cadmium And Lead ◽  
Concentration Levels ◽  
Pb Immobilization ◽  
Better Than ◽  
Cd Species ◽  
Simultaneous Immobilization

Abstract Risk associated with heavy metals in soil has been received widespread attention. In this study, a porous biochar supported nanoscale zero-valent iron (BC-nZVI) was applied to immobilize cadmium (Cd) and/or lead (Pb) in clayey soil. Experiment results indicated that the immobilization of Cd or Pb by BC-nZVI process was better than that of BC or nZVI process, and about 80 % of heavy metals immobilization was obtained in BC-nZVI process. Addition of BC-nZVI could increase soil pH and organic matter (SOM). Cd or Pb immobilization was inhibited with coexisting organic compound 2,4-dichlorophenol (2,4-DCP), but 2,4-DCP could be removed in a simultaneous manner with Cd or Pb immobilization at low concentration levels. Simultaneous immobilization of Cd and Pb was achieved in BC-nZVI process, and both Cd and Pb availability significantly decreased. Stable Cd species inculding Cd(OH)2, CdCO3 and CdO were formed, whereas stable Pb species such as PbCO3, PbO and Pb(OH)2 were produced with BC-nZVI treatment. Simultaneous immobilization mechanism of Cd and Pb in soil by BC-nZVI was thereby proposed. This study well demonstrates that BC-nZVI has been emerged as a potential technology for the remediation of multiple metals in soil.

scholarly journals Degradation of Trichloroethylene Contaminated Soil by Zero-Valent Iron Nanoparticles

2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
Amira Kamal Ibrahem ◽  
Thanaa Abdel Moghny ◽  
Yasser Mohamed Mustafa ◽  
Nermine Elsyed Maysour ◽  
Farida Mohamed Saad El Din El Dars ◽  
...  
Keyword(s):  
Rate Constant ◽  
Contaminated Soil ◽  
Chlorinated Solvents ◽  
Chloride Ion ◽  
Zero Valent Iron ◽  
Specific Rate ◽  
Iron Nanoparticle ◽  
Nanoscale Zero Valent Iron ◽  
Tce Degradation ◽  
Zero Valent Iron Nanoparticles

Trichloroethylene (TCE) contaminated soil has received extensive attention in the environmental issues. Nanoscale zero-valent iron (NZVI) is considered as an excellent reduction catalyst due to fast degradation of chlorinated solvents. Therefore, this paper aims to evaluate TCE removal from soil by surfactant modified nanoscale zero-valent iron (SNZVI). In this respect, fixed 500 g soil having a diameter range 0.5–1 mm was polluted with 10 mL TCE and put inside glass column of 2.5 cm diameter × 300 cm length. The NZVI solution was prepared from reduction of FeCL3 by NaBH4 and coating with 2.5 g nonionic surfactant (Tween 85) to produce iron nanoparticle concentration of 0.1 g/L. The prepared iron nanoparticle was poured into contaminated soil and left to stir at a constant rate for 24 days. The reductive dechlorination of TCE was measured as a function of increasing chloride ion. It was found that the TCE dechlorination in the presence of iron surfaces displayed pseudo first-order kinetics. The TCE degradation rate constant () is . Also, about 30% of TCE was removed within initial 6 days. The obtained specific rate constant () was and is lower than other studies carried into aqueous phase by about 23 orders of magnitude. Finally, the SNZVI was found to be effective and fully removed to TCE within 456 hours.

Efficiency of nanoscale zero-valent iron on the enhanced low molecular weight organic acid removal Pb from contaminated soil

Chemosphere ◽  
2014 ◽  
Vol 117 ◽  
pp. 617-624 ◽  
Author(s):  
Guiyin Wang ◽  
Shirong Zhang ◽  
Xiaoxun Xu ◽  
Ting Li ◽  
Yun Li ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Organic Acid ◽  
Contaminated Soil ◽  
Zero Valent Iron ◽  
Low Molecular Weight ◽  
Nanoscale Zero Valent Iron
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