Effective recovery of casein from its aqueous solution by ultrasonic treatment assisted foam fractionation: Inhibiting molecular aggregation

2020 ◽  
Vol 284 ◽  
pp. 110042
Author(s):  
Yi Zhang ◽  
Ruipeng Di ◽  
Huixin Zhang ◽  
Wenjun Zhang ◽  
Zhaoliang Wu ◽  
...  
2019 ◽  
Vol 946 ◽  
pp. 129-133
Author(s):  
Vitaly Smolko ◽  
Elizaveta Antoshkina

The article describes the problem of the experimental determination of complex dielectric permittivity for natural, activated, and modified quartz systems. The results of determination of specific surface, complex dielectric permittivity, sands porosity are presented in this article. The authors obtained the empirical equation of complex dielectric permittivity calculation for natural, activated, and modified quartz sands, taking into account the effect of moisture, specific surface, porosity, impurities content into consideration. The modification of the sand surface by means of mechanical beneficiation and ultrasonic treatment leads to reduction of complex dielectric permittivity and specific surface, thus contributing to the increase of the active centers quantity on the sands surface. The modification of the sand surface by polyvinyl alcohol aqueous solution leads to increase of complex dielectric permittivity. Polyvinyl alcohol aqueous solution modification envisages the creation of new active centers by oligomers inoculation to the surface and blocking the clay component and authigenous film ingredients. Among the considered methods, ultrasonic treatment in aqueous solution and mechanical beneficiation are the most efficient and technologically acceptable ways of activation.


Desalination ◽  
2009 ◽  
Vol 249 (2) ◽  
pp. 503-506 ◽  
Author(s):  
Jian Zhang ◽  
Yingjun Jing ◽  
Zhaoliang Wu ◽  
Qian Li

2006 ◽  
Vol 13 (1) ◽  
pp. 13-18 ◽  
Author(s):  
Eileen C. Bernardo ◽  
Tadashi Fukuta ◽  
Takafumi Fujita ◽  
Erwin P. Ona ◽  
Yoshihiro Kojima ◽  
...  

2013 ◽  
Vol 48 (5) ◽  
pp. 757-765 ◽  
Author(s):  
Visarut Rujirawanich ◽  
Manutchanok Triroj ◽  
Orathai Pornsunthorntawee ◽  
Jittipan Chavadej ◽  
Sumaeth Chavadej

Author(s):  
John Kunzler ◽  
Leen Samha ◽  
Renwu Zhang ◽  
Hussein Samha

The aggregation of the cyanine dye, 3,3’-disulfobutyl-5,5’-dichloro thiacarbocyanine triethylamine, (NK-3796) in aqueous solution was investigated using absorption and emission spectroscopy. The equilibrium, n(monomer) ⇆ n(dimer) ⇆ (H-aggregate)n , was observed over a series of dye concentrations ranging from 10-4 mM to 0.1mM. At concentrations <10-3 mM, the dye exists in solution mostly in the monomeric form. However, dimers become more significant when the concentration of the dye exceeds 10-2 mM. Unlike the substituted dye in the 9th position, the NK-3796 dye tends to form H-aggregates at higher concentration (>10-1 mM). Monomers and dimers exhibit strong emission in the visible region. Also notable, is that the emission from the H-aggregates was very weak due to self quenching.


Author(s):  
Максим Евгеньевич Григорьев ◽  
Роман Викторович Бровко ◽  
Евгений Олегович Долуда

В работе рассмотрена возможность использование ультразвука при получении рутений содержащей каталитической системы Ru/СПС MN 100. Проведено кинетическое тестирование данного катализатора и сравнение его активности с таким же катализатором, но синтезированным без использования ультразвука, в процессе гидрирования ксилозы и лактозы до соответствующих полиолов - ксилита и лактита. Процесс гидрирования осуществлялся в реакторе периодического и непрерывного действия при оптимальных условиях (температуре, концентрации моно- и дисахарида, парциальном давлении водорода, скорости подачи водного раствора ксилозы и лактозы и скорости подачи водорода). Установлено, что ультразвуковая обработка рутениевого катализатора способствует повышению его активности, что отражается на увеличении конверсии моно- и дисахарида при проведении процесса в периодических условиях, при этом практически не происходит изменения конверсии субстратов при их гидрировании в реакторе проточного типа. The paper considers the possibility of using ultrasound in the production of ruthenium-containing catalytic system Ru/SPS MN 100. Kinetic testing of this catalyst was carried out and its activity was compared with the same catalyst, but synthesized without the use of ultrasound, in the process of hydrogenation of xylose and lactose to the corresponding polyols - xylitol and lactite. The hydrogenation process was carried out in a periodic and continuous reactor under optimal conditions (temperature, concentration of mono - and disaccharide, partial pressure of hydrogen, the rate of supply of an aqueous solution of xylitol and lactite and the rate of supply of hydrogen). It was found that ultrasonic treatment of the ruthenium catalyst contributes to an increase in its activity, which is reflected in an increase in the conversion of mono - and disaccharide during the process under periodic conditions, while there is practically no change in the conversion of substrates during their hydrogenation in a flow-type reactor.


Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1734 ◽  
Author(s):  
Alfassi ◽  
Rein ◽  
Shpigelman ◽  
Cohen

Cellulose acetate is one of the most important cellulose derivatives. The use of ionic liquids in cellulose processing was recently found to act both as a solvent and also as a reagent. A recent study showed that cellulose dissolution in the ionic liquid 1-ethyl-3-methylimidazoliumacetate (EMIMAc) mixed with dichloromethane (DCM) resulted in controlled homogenous cellulose acetylation; yielding water-soluble cellulose acetate (WSCA). This research investigated the properties of cellulose acetate prepared in this manner, in an aqueous solution. The results revealed that WSCA fully dissolves in water, with no significant sign of molecular aggregation. Its conformation in aqueous solution exhibited a very large persistence length, estimated as over 10 nm. The WSCA exhibited surface activity, significantly reducing the surface tension of water. Because of the molecular dissolution of WSCA in water, augmented by its amphiphilicity, aqueous solutions of WSCA exhibited an overwhelmingly high rate of enzymatic hydrolysis.


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