Mineralogical phase transformation of Fe containing sphalerite at acidic environments in the presence of Cu2+

Under the oxidative roasting process, pyrite, as a major mineral in sulfidic mine tailings, can transform to iron oxides. Generated iron oxides, if exhibiting enough magnetic properties, can be recovered via magnetic separation resulting in partial mine tailings valorization. However, due to the presence of various minerals and sintering possibility, it is advantageous to remove impurities and increase the pyrite content of mine tailings prior to the roasting procedure. In this case, hydrofluoric acid that has no influence on pyrite can be used to leach most inorganic minerals, including aluminosilicates. Therefore, this study investigated and compared the influence of the roasting process with and without hydrofluoric acid leaching pretreatment on mineralogical phase transformation of pyrite and magnetic properties of thermally generated minerals. Several tests and analyses were performed to study mineralogical phase transformation, morphology, elemental composition, surface characterization, and magnetic properties. Results of this study indicated that without acid leaching pretreatment, pyrite was mainly transformed to hematite. However, via acid leaching, fluorine, as a more electronegative element over oxygen, entered the compound and neglected the role of oxygen in thermal oxidation, instead reducing sulfur content of pyrite to only form pyrrhotite.

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The Effect of Microwave Heating on the Mineralogical Phase Transformation of Pyrite and Fe Leaching

Journal of the Mineralogical Society of Korea ◽

10.9727/jmsk.2015.28.3.233 ◽

2015 ◽

Vol 28 (3) ◽

pp. 233-244 ◽

Cited By ~ 1

Author(s):

Don-Sang You ◽

◽

Cheon-Young Park

Keyword(s):

Phase Transformation ◽

Microwave Heating ◽

Mineralogical Phase

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Phase Transformation In Ti-6al-4v Alloys

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100096175 ◽

1972 ◽

Vol 30 ◽

pp. 584-585

Author(s):

Shiro Fujishiro

Keyword(s):

Phase Transformation ◽

Grain Boundary ◽

Cryogenic Temperature ◽

Β Phase ◽

Heat Treated ◽

Mixed Microstructure ◽

Ductile Behavior

The Ti-6 wt.% Al-4 wt.% V commercial alloys have exhibited an improved formability at cryogenic temperature when the alloys were heat-treated prior to the tests. The author was interested in further investigating this unusual ductile behavior which may be associated with the strain-induced transformation or twinning of the a phase, enhanced at lower temperatures. The starting materials, supplied by RMI Co., Niles, Ohio were rolled mill products in the form of 40 mil sheets. The microstructure of the as-received materials contained mainly ellipsoidal α grains measuring between 1 and 5μ. The β phase formed an undefined grain boundary around the a grains. The specimens were homogenized at 1050°C for one hour, followed by aging at 500°C for two hours, and then quenched in water to produce the α/β mixed microstructure.

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Microstructural and Microchemical Characterization of Nickel Sulfide Inclusions in Plate Glass

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100089123 ◽

1991 ◽

Vol 49 ◽

pp. 962-963

Author(s):

J. Cooper ◽

O. Popoola ◽

W. M. Kriven

Keyword(s):

Thermal Expansion ◽

Phase Transformation ◽

Glass Matrix ◽

Nickel Sulfide ◽

Plate Glass ◽

Thermal Expansion Mismatch ◽

Volume Increase ◽

Β Phase ◽

Microchemical Characterization

Nickel sulfide inclusions have been implicated in the spontaneous fracture of large windows of tempered plate glass. Two alternative explanations for the fracture-initiating behaviour of these inclusions have been proposed: (1) the volume increase which accompanies the α to β phase transformation in stoichiometric NiS, and (2) the thermal expansion mismatch between the nickel sulfide phases and the glass matrix. The microstructure and microchemistry of the small inclusions (80 to 250 μm spheres), needed to determine the cause of fracture, have not been well characterized hitherto. The aim of this communication is to report a detailed TEM and EDS study of the inclusions.

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AEM of reaction-bonded SiC

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100122125 ◽

1992 ◽

Vol 50 (1) ◽

pp. 344-345

Author(s):

K Das Chowdhury ◽

R. W. Carpenter ◽

W. Braue

Keyword(s):

Mechanical Properties ◽

Phase Transformation ◽

High Temperature ◽

Epitaxial Growth ◽

Liquid Silicon ◽

Structural Ceramic ◽

Few Data

Research on reaction-bonded SiC (RBSiC) is aimed at developing a reliable structural ceramic with improved mechanical properties. The starting materials for RBSiC were Si,C and α-SiC powder. The formation of the complex microstructure of RBSiC involves (i) solution of carbon in liquid silicon, (ii) nucleation and epitaxial growth of secondary β-SiC on the original α-SiC grains followed by (iii) β>α-SiC phase transformation of newly formed SiC. Due to their coherent nature, epitaxial SiC/SiC interfaces are considered to be segregation-free and “strong” with respect to their effect on the mechanical properties of RBSiC. But the “weak” Si/SiC interface limits its use in high temperature situations. However, few data exist on the structure and chemistry of these interfaces. Microanalytical results obtained by parallel EELS and HREM imaging are reported here.

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Phase transformation and layer evolution in molybdenum disilicide-silicon carbide nanolayered coatings

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100170426 ◽

1994 ◽

Vol 52 ◽

pp. 538-539

Author(s):

H. Kung ◽

T. R. Jervis ◽

J.-P. Hirvonen ◽

M. Nastasi ◽

T. E. Mitchell ◽

...

Keyword(s):

Phase Transformation ◽

High Temperature ◽

Oxidation Resistance ◽

Elevated Temperatures ◽

Matrix Material ◽

Molybdenum Disilicide ◽

High Temperature Strength ◽

Cross Sectional ◽

Good Oxidation Resistance ◽

Structural Applications

MoSi2 is a potential matrix material for high temperature structural composites due to its high melting temperature and good oxidation resistance at elevated temperatures. The two major drawbacksfor structural applications are inadequate high temperature strength and poor low temperature ductility. The search for appropriate composite additions has been the focus of extensive investigations in recent years. The addition of SiC in a nanolayered configuration was shown to exhibit superior oxidation resistance and significant hardness increase through annealing at 500°C. One potential application of MoSi2- SiC multilayers is for high temperature coatings, where structural stability ofthe layering is of major concern. In this study, we have systematically investigated both the evolution of phases and the stability of layers by varying the heat treating conditions.Alternating layers of MoSi2 and SiC were synthesized by DC-magnetron and rf-diode sputtering respectively. Cross-sectional transmission electron microscopy (XTEM) was used to examine three distinct reactions in the specimens when exposed to different annealing conditions: crystallization and phase transformation of MoSi2, crystallization of SiC, and spheroidization of the layer structures.

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Ferroelectric Domain Structure of Pb(Zr.52Ti.48)03

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s1431927600000933 ◽

1980 ◽

Vol 38 ◽

pp. 214-215

Author(s):

E.K. Goo ◽

R.K. Mishra

Keyword(s):

Phase Transformation ◽

Domain Structure ◽

Tetragonal Phase ◽

Ferroelectric Domain ◽

Cubic Phase ◽

Ion Milling ◽

Thin Foils ◽

Ferroelectric Domain Structure ◽

Ferroelectric Domains

Ferroelectric domains are twins that are formed when PZT undergoes a phase transformation from a non-ferroelectric cubic phase to a ferroelectric tetragonal phase upon cooling below ∼375°C.,1 The tetragonal phase is spontaneously polarized in the direction of c-axis, making each twin a ferroelectric domain. Thin foils of polycrystalline Pb (Zr.52Ti.48)03 were made by ion milling and observed in the Philips EM301 with a double tilt stage.

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