Engineering oxygen vacancies via amorphization in conjunction with W-doping as an approach to boosting catalytic properties of Pt/Fe-W-O for formaldehyde oxidation

2021 ◽  
pp. 126224
Author(s):  
Muhua Chen ◽  
Yuping Qiu ◽  
Weizhen Wang ◽  
Xinyan Li ◽  
Jiajun Wang ◽  
...  
Keyword(s):  
Oxygen Vacancies ◽  
Catalytic Properties ◽  
Formaldehyde Oxidation ◽  
W Doping

Oxygen vacancies confined in nickel oxide nanoprism arrays for promoted electrocatalytic water splitting

2020 ◽  
Vol 44 (5) ◽  
pp. 1703-1706 ◽  
Author(s):  
Xiaoshuang Zhang ◽  
Xiaoqiang Du
Keyword(s):  
Nickel Oxide ◽  
Water Splitting ◽  
Adsorption Energy ◽  
Active Sites ◽  
Oxygen Vacancies ◽  
Dft Calculation ◽  
Catalytic Properties ◽  
Calculation Results

Experimental and DFT calculation results show that the presence of oxygen vacancies can decrease the adsorption energy of intermediates at active sites and facilitate the adsorption of intermediates, thus improving the catalytic properties.

Oxygen vacancy-confined CoMoO4@CoNiO2 nanorod arrays for oxygen evolution with improved performance

2019 ◽  
Vol 48 (27) ◽  
pp. 10116-10121 ◽  
Author(s):  
Xiaoqiang Du ◽  
Guangyu Ma ◽  
Xiaoshuang Zhang
Keyword(s):  
Oxygen Vacancy ◽  
Oxygen Evolution ◽  
Adsorption Energy ◽  
Active Sites ◽  
Oxygen Vacancies ◽  
Dft Calculation ◽  
Catalytic Properties ◽  
Nanorod Arrays ◽  
Calculation Results ◽  
Improved Performance

Experimental and DFT calculation results show that the presence of oxygen vacancies can decrease the adsorption energy of intermediates at active sites and facilitate the adsorption of intermediates, thus improving the catalytic properties.

A nickel molybdenum oxide nanoarray as an efficient and stable electrocatalyst for overall water splitting

2020 ◽  
Vol 44 (20) ◽  
pp. 8176-8182 ◽  
Author(s):  
Xiaoshuang Zhang ◽  
Hui Su ◽  
Xiaoqiang Du
Keyword(s):  
Water Splitting ◽  
Molybdenum Oxide ◽  
Adsorption Energy ◽  
Active Sites ◽  
Oxygen Vacancies ◽  
Dft Calculation ◽  
Catalytic Properties ◽  
Overall Water Splitting ◽  
Calculation Results

Experimental and DFT calculation results show that the presence of oxygen vacancies can decrease the adsorption energy of intermediates at active sites and facilitate their adsorption, thus improving the catalytic properties.

Surface oxygen vacancies on Co3O4 mediated catalytic formaldehyde oxidation at room temperature

2016 ◽  
Vol 6 (11) ◽  
pp. 3845-3853 ◽  
Author(s):  
Zhong Wang ◽  
Wenzhong Wang ◽  
Ling Zhang ◽  
Dong Jiang
Keyword(s):  
Catalytic Oxidation ◽  
Room Temperature ◽  
Oxygen Vacancies ◽  
Essential Role ◽  
Surface Oxygen ◽  
Oxidation Reactions ◽  
Major Activity ◽  
Formaldehyde Oxidation ◽  
The Common

This study reveals the essential role played by surface oxygen vacancies in catalytic oxidation reactions, and complements the common viewpoint that Co3+ is the major activity species in Co3O4-based systems.

Flexible nickel foam decorated with Pt/NiO nanoflakes with oxygen vacancies for enhanced catalytic formaldehyde oxidation at room temperature

2017 ◽  
Vol 4 (11) ◽  
pp. 2215-2224 ◽  
Author(s):  
Shuying Huang ◽  
Xiaofeng Zhu ◽  
Bei Cheng ◽  
Jiaguo Yu ◽  
Chuanjia Jiang
Keyword(s):  
Ambient Temperature ◽  
Catalytic Oxidation ◽  
Room Temperature ◽  
Oxygen Vacancies ◽  
Nickel Foam ◽  
Formaldehyde Oxidation

Flexible nickel foam coated with Pt/NiO nanoflakes was prepared for HCHO catalytic oxidation at ambient temperature.

scholarly journals Effect of Mo Dispersion on the Catalytic Properties and Stability of Mo–Fe Catalysts for the Partial Oxidation of Methanol

Molecules ◽  
2020 ◽  
Vol 25 (10) ◽  
pp. 2410
Author(s):  
Shuai Zhang ◽  
Minghan Han
Keyword(s):  
Surface Layer ◽  
Surface Area ◽  
Partial Oxidation ◽  
Active Sites ◽  
Oxygen Vacancies ◽  
Catalyst Surface ◽  
Catalytic Properties ◽  
Oxidation Of Methanol ◽  
Partial Oxidation Of Methanol ◽  
Fe Catalysts

Mo–Fe catalysts with different Mo dispersions were synthesized with fast (Cat-FS, 600 r·min−1) or slow stirring speed (Cat-SS, 30 r·min−1) by the coprecipitation method. Improving the stirring speed strengthened the mixing of the solution and increased the dispersion of particles in the catalyst, which exhibited favorable activity and selectivity. The byproduct (dimethyl ether (DME)) selectivity increased from 2.3% to 2.8% with Cat-SS, while it remained unchanged with Cat-FS in a stability test. The aggregation of particles and thin Mo-enriched surface layer decreased the catalyst surface area and slowed down the reoxidation of reduced active sites with Cat-SS, leaving more oxygen vacancies which promoted the formation of DME by the nonoxidative channel.

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