Interface formation of epitaxial MgO/Co2MnSi(001) structures: Elemental segregation and oxygen migration

2017 ◽  
Vol 444 ◽  
pp. 383-389 ◽  
Author(s):  
Anthony McFadden ◽  
Nathaniel Wilson ◽  
Tobias Brown-Heft ◽  
Daniel Pennachio ◽  
Mihir Pendharkar ◽  
...  
2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Meng Meng ◽  
Yuanwei Sun ◽  
Yuehui Li ◽  
Qichang An ◽  
Zhenzhen Wang ◽  
...  

AbstractThe d-band-filling of transition metals in complex oxides plays an essential role in determining their structural, electronic and magnetic properties. Traditionally, at the oxide heterointerface, band-filling control has been achieved via electrostatic modification in the structure of field-effect transistors or electron transfer, which is limited to the quasi-two-dimension at the interface. Here we report a three-dimensional (3D) band-filling control by changing the local lattice coordination in a designed oxide heterostructure. At the LaCoO3/LaTiO3 heterointerface, due to the Fermi level mismatch, electrons transfer from LaTiO3 to LaCoO3. This triggers destabilisation of the CoO6 octahedrons, i.e. the formation of lattice configurations with a reduced Co valence. The associated oxygen migration results in the 3D topotactic phase transition of LaCoO3. Tuned by the thickness of LaTiO3, different crystalline phases and band-fillings of Co occur, leading to the emergence of different magnetic ground states.


1980 ◽  
Vol 17 (5) ◽  
pp. 952-957 ◽  
Author(s):  
K. M. Geib ◽  
C. W. Wilmsen

2019 ◽  
Vol 141 (37) ◽  
pp. 14496-14500 ◽  
Author(s):  
Faisal Saleem ◽  
Zhicheng Zhang ◽  
Xiaoya Cui ◽  
Yue Gong ◽  
Bo Chen ◽  
...  

1998 ◽  
Vol 416 (1-2) ◽  
pp. 295-304 ◽  
Author(s):  
A.B.M.O. Islam ◽  
K. Asai ◽  
K.K. Lim ◽  
T. Tambo ◽  
C. Tatsuyama

2010 ◽  
Vol 256 (19) ◽  
pp. 5740-5743 ◽  
Author(s):  
Simone Sanna ◽  
Wolf Gero Schmidt

1981 ◽  
Vol 108 (3) ◽  
pp. L465-L469 ◽  
Author(s):  
Joseph Cunningham ◽  
John P.J. Tobin ◽  
Paul Meriaudeau

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