scholarly journals A detailed study of the substitution mechanism for improved zinc-borate: high-performance and its crystal structure variation

2021 ◽  
Author(s):  
Rui Peng ◽  
Yuanxun Li ◽  
Hua Su ◽  
Yongcheng Lu ◽  
Chengyong Yu ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Performance ◽  
Zinc Borate ◽  
Structure Variation ◽  
Substitution Mechanism

Microstructure and Hydrogen Permeability of Duplex Phase M-ZrNi (M=V, Nb, Ta) Alloys

2006 ◽  
Vol 980 ◽  
Author(s):  
Kazuhiro Ishikawa ◽  
Naoshi Kasagami ◽  
Tomoyuki Takano ◽  
Kiyoshi Aoki
Keyword(s):  
Crystal Structure ◽  
Solid Solution ◽  
High Performance ◽  
Gas Flow ◽  
Hydrogen Permeation ◽  
Hydrogen Permeability ◽  
The Other ◽  
Cast State ◽  
X Ray ◽  
Scanning Electron

AbstractIn order to develop non-Pd based high performance hydrogen permeation alloys, microstructure, crystal structure and hydrogen permeability of duplex phase M-ZrNi (M=V and Ta) alloys were investigated using a scanning electron microscope, an X-ray diffractometer and a gas flow meter. These results were compared with those of Nb-ZrNi ones which have been previously published. The hydrogen permeation was impossible in the V-ZrNi alloys, because they were brittle in the as-cast state. On the other hand, duplex phase alloys consisting of the bcc-(Ta, Zr) solid solution and the orthorhombic ZrNi (Cmcm) intermetallic compound were formed and hydrogen permeable in the Ta-ZrNi system. The Ta40Zr30Ni30 alloy shows the highest value of hydrogen permeability of 4.1×10-8 [molH2m-1s-1Pa-0.5] at 673 K, which is three times higher than that of pure Pd.

High-performance electrical properties of La-based perovskite ceramics for the functional phase of thick film resistors

2020 ◽  
Author(s):  
Yongcheng Lu ◽  
Yuanxun Li ◽  
Daming Chen ◽  
Rui Peng ◽  
Qinghui Yang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Electrical Properties ◽  
Thick Film ◽  
High Performance ◽  
Composite Ceramics ◽  
X Ray Diffraction ◽  
X Ray ◽  
Alternative Material ◽  
Perovskite Ceramics ◽  
Scanning Electron

Abstract In order to explore an economical functional phase alternative material for thick film resistors, the crystal structure, microstructure, and electrical properties of (1-x)LSCN + xLCNZ (x = 0.0–1.0) composite ceramics were studied through solid-state reaction experiments. The composite ceramics were characterized by x–ray diffraction, scanning electron microscopy, energy dispersive x–ray spectroscopy, and DC four–probe method. Results suggested that the main phases of LSCN and LCNZ were formed, along with a small part of impurity phases. The addition of LCNZ to LSCN decreased the electrical conductivity and changed the TCR from positive to negative. Zero TCR could be achieved around 0.6 < x < 0.8 and relatively low absolute TCR values could be obtained for the samples of 0.4 ≤ x ≤ 0.8. The ceramic of 0.6LSCN + 0.4LCNZ showed the optimal performances of conductivity = 1923 S/cm, TCR = 379.54 ppm/℃, and relative density = 95.05%.

Crystal structure of nickel manganese-layered double hydroxide@cobaltosic oxides on nickel foam towards high-performance supercapacitors

CrystEngComm ◽  
2019 ◽  
Vol 21 (3) ◽  
pp. 470-477 ◽  
Author(s):  
Huihua Peng ◽  
Chuan Jing ◽  
Jie Chen ◽  
Deyi Jiang ◽  
Xiaoying Liu ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Crystal Structures ◽  
Layered Double Hydroxide ◽  
High Performance ◽  
Rational Design ◽  
Electrode Materials ◽  
Nickel Foam ◽  
Double Hydroxide ◽  
Nickel Manganese

Rational design of the crystal structures of electrode materials is considered as an important strategy to construct high-performance supercapacitors.

The crystal structure of two new developers for high-performance thermo-sensitive paper: H-bonded network in urea–urethane derivatives

2010 ◽  
Vol 85 (3) ◽  
pp. 139-142 ◽  
Author(s):  
Shinya Matsumoto ◽  
Sakiko Takeshima ◽  
Saori Satoh ◽  
Kazuo Kabashima
Keyword(s):  
Crystal Structure ◽  
High Performance

Crystal structure of high-performance thermoelectric materials by high resolution neutron powder diffraction

2018 ◽  
Vol 551 ◽  
pp. 64-68 ◽  
Author(s):  
Peng Wu ◽  
Yoshihisa Ishikawa ◽  
Masato Hagihala ◽  
Sanghyun Lee ◽  
Kunling Peng ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Resolution ◽  
Powder Diffraction ◽  
Thermoelectric Materials ◽  
High Performance ◽  
Neutron Powder Diffraction

Zur Synthese und Kristallstruktur von Dibariumkaliumtrizinkborat Ba2KZn3(B3O6)(B6O13)/Synthesis and Crystal Structure of Di-barium Potassium Tri-zinc Borate Ba2KZn3(B3O6)(B6O13)

1996 ◽  
Vol 51 (3) ◽  
pp. 319-324 ◽  
Author(s):  
Silke Busche ◽  
Karsten Bluhm
Keyword(s):  
Crystal Structure ◽  
Single Crystals ◽  
Structure Type ◽  
Lattice Parameters ◽  
Zinc Borate ◽  
Synthesis And Crystal Structure ◽  
Space Group ◽  
X Ray ◽  
Unknown Structure

Abstract Single crystals of the new compound Ba2KZn3(B3O6)(B6O13) were obtained by using a B2O3 flux technique; they crystallize in an as yet unknown structure type. X-ray investigations led to the space group Ci1-P1̄ (Nr.2) with lattice parameters a = 705.2(2), b = 712.5(2), c = 1880.3(6), a = 93.43(3)°, β = 90.72(2)°, γ = 119.57(2)°, Z = 2. The structure contains (B3O6)3--rings and a new discrete (B6O13)8- anion, which is composed of two BO4 and two B2O5 units. Zn2+ is tetrahedrally coordinated by oxygen and two out of three tenfold coordinated Ba-sites are statistically occupied by Ba2+ and K+.

DETERMINATION OF CRYSTAL STRUCTURE AND CRYSTALLOGRAPHIC CHARACTERISTICS IN Ni-Mn-Ga FERROMAGNETIC SHAPE MEMORY ALLOYS

2009 ◽  
Vol 23 (06n07) ◽  
pp. 1771-1776
Author(s):  
D. Y. CONG ◽  
Y. D. ZHANG ◽  
C. ESLING ◽  
Y. D. WANG ◽  
X. ZHAO ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Shape Memory Alloys ◽  
Shape Memory ◽  
High Performance ◽  
Room Temperature ◽  
Martensitic Structure ◽  
Magnetic Shape Memory ◽  
Ferromagnetic Shape Memory Alloys ◽  
Electron Backscattered Diffraction ◽  
Ferromagnetic Shape Memory

Ni - Mn - Ga ferromagnetic shape memory alloys (FSMAs) have received great attention during the past decade due to their giant magnetic shape memory effect and fast dynamic response. The crystal structure and crystallographic features of two Ni - Mn - Ga alloys were precisely determined in this study. Neutron diffraction measurements show that Ni 48 Mn 30 Ga 22 has a Heusler austenitic structure at room temperature; its crystal structure changes into a seven-layered martensitic structure when cooled to 243K. Ni 53 Mn 25 Ga 22 has an I4/mmm martensitic structure at room temperature. Electron backscattered diffraction (EBSD) analyses reveal that there are only two martensitic variants with a misorientation of ~82° around <110> axis in each initial austenite grain in Ni 53 Mn 25 Ga 22. The investigation on crystal structure and crystallographic features will shed light on the development of high-performance FSMAs with optimal properties.

Zur Synthese und Kristallstruktur von Zinkboratoxiden mit isolierten, trigonal planaren BO3-Baugruppen: Zn5Mn(BO3)2O4 und ZnFe(BO3)O / Synthesis and Crystal Structure of Zinc Borate Oxides Containing Isolated Trigonal Planar BO3 Units: Zn5Mn(BO3)2O4 and ZnFe(BO3)O

1995 ◽  
Vol 50 (10) ◽  
pp. 1450-1454 ◽  
Author(s):  
Silke Busche ◽  
Karsten Bluhm
Keyword(s):  
Crystal Structure ◽  
Single Crystals ◽  
Zinc Borate ◽  
Synthesis And Crystal Structure ◽  
Space Group ◽  
X Ray ◽  
Octahedral Sites ◽  
Distorted Octahedral ◽  
New Compounds ◽  
Group D

Single crystals of the new compounds Zn5Mn(BO3)2O4 (A ) and ZnFe(BO3)O (B) were prepared by using a B2O3 flux technique. Zn5Mn(BO3)2O4 is isostructural with Ni5Ti(BO3)2O4 and ZnFe(BO3)O is isotypic with the mineral warwickite. X-ray investigations on single crystals led to (A ) space group D92h -Pbam, a = 926.41(10), b = 1236.67(8), c = 304.55(3) pm, Z = 2, and (B) space group D162h-Pnma, a = 924.62(4), b = 314.1(10), c = 935.3(2) pm, Z = 4. The structure of Zn5Mn(BO3)2O4 (A ) contains four octahedrally coordinated metal sites, one of these statistically occupied by Zn2+ and Mn4+. In the structure of ZnFe(BO3)O the ions Zn2+ and Fe3+ occupy statistically both distorted octahedral sites. Both structures contain isolated BO3 units and oxygen that is not coordinated to boron.

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