Electrochemical photoluminescence modulation of functional materials and their electrochemical devices

Author(s):  
Kazuki Nakamura ◽  
Kenji Kanazawa ◽  
Norihisa Kobayashi
2015 ◽  
Vol 832 ◽  
pp. 28-53 ◽  
Author(s):  
Hani Nasser Abdelhamid

Recently, numerous delafossite oxides in nanoscale have been reported for diverse applications. The present review summarized the recent overall views of delafossite nanoparticles in diverse applications such as energy, catalysis, photocatalysis, nanomedicine, sensors, electrochemical devices and environmental concerns. Delafossite nanoparticles possess unique features such as different and wide chemical composition, large surface area, small energy gap, ability for further functionalization, possess dual-active sites with different oxidation states (A+and M3+), and eager for doping with various species with feasibility to undergo structure modification. Thus, they provided promising application such as solar cell, photocatalysis, hydrogen production, bioactive materials, separation purposes and others. Pros, cons, current and future status were also reviewed.


Author(s):  
Yoichi Ishida ◽  
Hideki Ichinose ◽  
Yutaka Takahashi ◽  
Jin-yeh Wang

Layered materials draw attention in recent years in response to the world-wide drive to discover new functional materials. High-Tc superconducting oxide is one example. Internal interfaces in such layered materials differ significantly from those of cubic metals. They are often parallel to the layer of the neighboring crystals in sintered samples(layer plane boundary), while periodically ordered interfaces with the two neighboring crystals in mirror symmetry to each other are relatively rare. Consequently, the atomistic features of the interface differ significantly from those of cubic metals. In this paper grain boundaries in sintered high-Tc superconducting oxides, joined interfaces between engineering ceramics with metals, and polytype interfaces in vapor-deposited bicrystal are examined to collect atomic information of the interfaces in layered materials. The analysis proved that they are not neccessarily more complicated than that of simple grain boundaries in cubic metals. The interfaces are majorly layer plane type which is parallel to the compound layer. Secondly, chemical information is often available, which helps the interpretation of the interface atomic structure.


2020 ◽  
Vol 11 (48) ◽  
pp. 7603-7624
Author(s):  
Ismail Altinbasak ◽  
Mehmet Arslan ◽  
Rana Sanyal ◽  
Amitav Sanyal

This review provides an overview of synthetic approaches utilized to incorporate the thiol-reactive pyridyl-disulfide motif into various polymeric materials, and briefly highlights its utilization to obtain functional materials.


Planta Medica ◽  
2012 ◽  
Vol 78 (11) ◽  
Author(s):  
SH Kim ◽  
MJ Lee ◽  
J Han ◽  
CE Lee

2020 ◽  
Vol 64 (1-4) ◽  
pp. 201-210
Author(s):  
Yoshikazu Tanaka ◽  
Satoru Odake ◽  
Jun Miyake ◽  
Hidemi Mutsuda ◽  
Atanas A. Popov ◽  
...  

Energy harvesting methods that use functional materials have attracted interest because they can take advantage of an abundant but underutilized energy source. Most vibration energy harvester designs operate most effectively around their resonant frequency. However, in practice, the frequency band for ambient vibrational energy is typically broad. The development of technologies for broadband energy harvesting is therefore desirable. The authors previously proposed an energy harvester, called a flexible piezoelectric device (FPED), that consists of a piezoelectric film (polyvinylidene difluoride) and a soft material, such as silicon rubber or polyethylene terephthalate. The authors also proposed a system based on FPEDs for broadband energy harvesting. The system consisted of cantilevered FPEDs, with each FPED connected via a spring. Simply supported FPEDs also have potential for broadband energy harvesting, and here, a theoretical evaluation method is proposed for such a system. Experiments are conducted to validate the derived model.


2020 ◽  
Vol 4 (1) ◽  
pp. 17-29
Author(s):  
Isma Attique ◽  
Shabbir Hussain ◽  
Muhammad Amjad ◽  
Khalida Nazir ◽  
Muhammad Shahid Nazir

Fluorine has a useful positron transmitting isotope and it enjoys broad application in the medical field. It is utilized in fluorinated agents,therapeutic sciences and steroid field. Fluorine incorporation viafluoroalkylation is a useful approach in the development of new functional materials and in drug design. Fluorine also plays its role as an anticancer agent and is a successful chemotherapeutic agent for certain sorts of malignant growth. 5-fluorouracil plays a vital role in the treatment of cancer. 18 Facts as a radio label tracer atom in PET imaging. 19 F has the second most sensitive and stable NMR-active nucleus.


2019 ◽  
Author(s):  
Alexander Giovannitti ◽  
Reem B. Rashid ◽  
Quentin Thiburce ◽  
Bryan D. Paulsen ◽  
Camila Cendra ◽  
...  

<p>Avoiding faradaic side reactions during the operation of electrochemical devices is important to enhance the device stability, to achieve low power consumption, and to prevent the formation of reactive side‑products. This is particularly important for bioelectronic devices which are designed to operate in biological systems. While redox‑active materials based on conducting and semiconducting polymers represent an exciting class of materials for bioelectronic devices, they are susceptible to electrochemical side‑reactions with molecular oxygen during device operation. We show that this electrochemical side reaction yields hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>), a reactive side‑product, which may be harmful to the local biological environment and may also accelerate device degradation. We report a design strategy for the development of redox-active organic semiconductors based on donor-acceptor copolymers that prevent the formation of H<sub>2</sub>O<sub>2</sub> during device operation. This study elucidates the previously overlooked side-reactions between redox-active conjugated polymers and molecular oxygen in electrochemical devices for bioelectronics, which is critical for the operation of electrolyte‑gated devices in application-relevant environments.</p>


2020 ◽  
pp. 42-48
Author(s):  
Tatiana Safronova ◽  
◽  
Tatiana Shatalova ◽  
Snezhana Tikhonova ◽  
Yaroslav Filippov ◽  
...  

Powders of calcium pyrophosphate Ca2P2O7 in the form of γ- и β-modifications have been produced as a result of thermal conversion of brushite CaHPO4∙2H2O synthesized from phosphoric acid H3PO4 and calcium carbonate CaCO3 at the molar ratio P / Ca = 1.1. The resulting powders can be used for production of various functional materials including biocompatible and bioresorbable ones for the treatment of bone defects.


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