A comparative investigation of metal-support interactions on the catalytic activity of Pt nanoparticles for ethanol oxidation in alkaline medium

The SMSI between Fe and oxygen vacancies in Ce0.8Sm0.2O2−δ helps to weaken and break the strong NN bonds in N2, increasing the catalytic activity. Materials with anion vacancies improve oxygenate tolerance property of ammonia synthesis catalysts.

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Fabrication, characterization, and stability of supported single-atom catalysts

Catalysis Science & Technology ◽

10.1039/c7cy00723j ◽

2017 ◽

Vol 7 (19) ◽

pp. 4250-4258 ◽

Cited By ~ 53

Author(s):

Yaxin Chen ◽

Zhiwei Huang ◽

Zhen Ma ◽

Jianmin Chen ◽

Xingfu Tang

Keyword(s):

Catalytic Activity ◽

Single Atom ◽

Metal Support ◽

Metal Support Interactions

Strong metal–support interactions are key requirements for development of stable single-atom catalysts with pronounced catalytic activity.

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High Catalytic Activity of Pt/Al2O3 Catalyst in CO Oxidation at Room Temperature—A New Insight into Strong Metal–Support Interactions

Catalysts ◽

10.3390/catal11121475 ◽

2021 ◽

Vol 11 (12) ◽

pp. 1475

Author(s):

Ireneusz Kocemba ◽

Izabela Śmiechowicz ◽

Marcin Jędrzejczyk ◽

Jacek Rogowski ◽

Jacek Michał Rynkowski

Keyword(s):

Catalytic Activity ◽

Co Oxidation ◽

Room Temperature ◽

Oxygen Adsorption ◽

High Catalytic Activity ◽

Adsorption Sites ◽

Co Oxidation Reaction ◽

Metal Support ◽

Metal Support Interactions ◽

Al2o3 Catalyst

The concept of very strong metal–support interactions (VSMSI) was defined in regard to the interactions that influence the catalytic properties of catalysts due to the creation of a new phase as a result of a solid-state chemical reaction between the metal and support. In this context, the high catalytic activity of the 1%Pt/Al2O3 catalyst in the CO oxidation reaction at room temperature was explained. The catalyst samples were reduced at different temperatures ranging from 500 °C to 800 °C and characterized using TPR, O2/H2 titration, CO chemisorption, TPD-CO, FTIR-CO, XRD, and TOF-SIMS methods. Based on the obtained results, it was claimed that with very high temperature reduction (800 °C), nonstoichiometric platinum species [Pt(Cl)Ox] strongly anchored to Al2O3 surface are formed. These species act as the oxygen adsorption sites.

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Bi-modified Pd/C catalyst via irreversible adsorption and its catalytic activity for ethanol oxidation in alkaline medium

Electrochimica Acta ◽

10.1016/j.electacta.2013.03.059 ◽

2013 ◽

Vol 99 ◽

pp. 22-29 ◽

Cited By ~ 71

Author(s):

Jindi Cai ◽

Yiyin Huang ◽

Yonglang Guo

Keyword(s):

Catalytic Activity ◽

Alkaline Medium ◽

Ethanol Oxidation ◽

Irreversible Adsorption

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Electrocatalytic oxidation of ethanol at Pd, Pt, Pd/Pt and Pt/Pd nano particles supported on poly 1,8-diaminonaphthalene film in alkaline medium

RSC Advances ◽

10.1039/c7ra13694c ◽

2018 ◽

Vol 8 (28) ◽

pp. 15417-15426 ◽

Cited By ~ 10

Author(s):

K. M. Hassan ◽

A. A. Hathoot ◽

R. Maher ◽

M. Abdel Azzem

Keyword(s):

Alkaline Medium ◽

Oxidation Reaction ◽

Electrocatalytic Oxidation ◽

Ethanol Oxidation ◽

Pt Nanoparticles ◽

Nano Particles ◽

Composite Catalyst ◽

Ethanol Oxidation Reaction ◽

Oxidation Of Ethanol

An ethanol oxidation reaction (EOR) in alkaline medium was carried out at palladium (Pd) or platinum (Pt) nanoparticles/poly 1,8-diaminonaphthalene (p1,8-DAN) composite catalyst electrodes.

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