Porous structure and adsorptive properties of activated carbon derived from Bambusa vulgaris striata by two-stage KOH/NaOH mixture activation for Hg2+ removal

2021 ◽  
Vol 43 ◽  
pp. 102294
Author(s):  
Tata Alfatah ◽  
Eka Marya Mistar ◽  
Muhammad Dani Supardan
1987 ◽  
Vol 19 (3-4) ◽  
pp. 471-482 ◽  
Author(s):  
W. J. Weber ◽  
B. E. Jones ◽  
L. E. Katz

The addition of powdered activated carbon (PAC) to activated sludge treatment systems to enhance removal of specific toxic organic compounds from wastewater was evaluated. Nine organic compounds encompassing a range of solubility, volatility, biodegradability, and adsorptive properties were studied. Kate and equilibrium investigations were conducted to quantify the removal mechanisms of volatilization, biodegradation, biosorption, and carbon adsorption. Results from steady-state bioreactor studies showed that the addition of less than 100 mg/ℓ powdered activated carbon to the influent did not enhance the removal of the biodegradable target compounds investigated: benzene, toluene, ethylbenzene, o-xylene, chlorobenzene, and nitrobenzene. Significantly improved removals of the poorly degradable and non-biodegradable compounds 1,2-dichlorobenzene, 1,2,4-trichlorobenzene, and lindane occurred at influent powdered carbon concentrations in the 12.5 to 25 mg/ℓ range. Influent powdered carbon concentrations of 100 mg/ℓ effected overall removals of greater than 90%. The addition of powdered activated carbon not only reduced effluent concentrations but also reduced the amounts of the volatile compounds stripped to the atmosphere.


2019 ◽  
Vol 30 (3) ◽  
pp. 325-329 ◽  
Author(s):  
Mirosław Kwiatkowski ◽  
Dimitrios Kalderis

Abstract This paper presents the results of the analysis of the porous structure of biochars produced from biomass, namely eucalyptus, wood chips, pruning waste and rice husk. The structural analysis was carried out using the BET, the t-plot, the NLDFT and the LBET methods, which yielded not only complementary information on the adsorptive properties of obtained biochars from these materials, but also information on the usefulness of the structural analysis methods in question for the research into an effect of the technology of carbonaceous adsorbent preparation.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2951
Author(s):  
Mirosław Kwiatkowski ◽  
Jarosław Serafin ◽  
Andy M. Booth ◽  
Beata Michalkiewicz

This paper presents the results of a computer analysis of the effect of activation process temperature on the development of the microporous structure of activated carbon derived from the leaves of common polypody (Polypodium vulgare) via chemical activation with phosphoric acid (H3PO4) at activation temperatures of 700, 800, and 900 °C. An unconventional approach to porous structure analysis, using the new numerical clustering-based adsorption analysis (LBET) method together with the implemented unique gas state equation, was used in this study. The LBET method is based on unique mathematical models that take into account, in addition to surface heterogeneity, the possibility of molecule clusters branching and the geometric and energy limitations of adsorbate cluster formation. It enabled us to determine a set of parameters comprehensively and reliably describing the porous structure of carbon material on the basis of the determined adsorption isotherm. Porous structure analyses using the LBET method were based on nitrogen (N2), carbon dioxide (CO2), and methane (CH4) adsorption isotherms determined for individual activated carbon. The analyses carried out showed the highest CO2 adsorption capacity for activated carbon obtained was at an activation temperature of 900 °C, a value only slightly higher than that obtained for activated carbon prepared at 700 °C, but the values of geometrical parameters determined for these activated carbons showed significant differences. The results of the analyses obtained with the LBET method were also compared with the results of iodine number analysis and the results obtained with the Brunauer–Emmett–Teller (BET), Dubinin–Radushkevich (DR), and quenched solid density functional theory (QSDFT) methods, demonstrating their complementarity.


2019 ◽  
Vol 170 ◽  
pp. 722-731 ◽  
Author(s):  
Bing Yang ◽  
Yucheng Liu ◽  
Qingling Liang ◽  
Mingyan Chen ◽  
Lili Ma ◽  
...  

2020 ◽  
Vol 36 (4) ◽  
Author(s):  
Anatálya dos Santos Ribeiro ◽  
Alexssandra Jéssica Rondon de Figueiredo ◽  
Gabriela Cristina Rech Tormen ◽  
André Luís Lopes da Silva ◽  
Wellington Ferreira Campos ◽  
...  

Bamboo species are an alternative for the composition of forest plantations. However, their potential has not been explored due to the hard time in producing large-scale clonal plants. Thus, the aim this work was to evaluate the in vitro establishment, bud multiplication and ex vitro rooting of Bambusa vulgaris. The first experiment tested different systemic and contact fungicide solutions, based on exposure time, during the establishment phase. Established explants were subjected to evaluation of residual fungicide effect on subcultures during the multiplication and elongation phases. The second experiment evaluated the influence of activated carbon on ex vitro survival and on adventitious rooting. Explant immersion in liquid culture medium added with 1.0 mL of fungicide for 120 hours has favored the in vitro establishment and reduced fungal contamination. On the other hand, it favored the shoot emission of shoots per explant during the multiplication phase. Both rooting induction culture medium and mini-incubator system use were effective in enabling adventitious root formation. The presence of activated carbon in the rooting induction culture medium resulted in a higher clonal plant survival rate.  


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