scholarly journals Polyimide/mesoporous silica nanocomposites: Characterization of mechanical and thermal properties and tribochemistry in dry sliding condition

2016 ◽  
Vol 108 ◽  
pp. 538-550 ◽  
Author(s):  
Jian Ma ◽  
Xiaowen Qi ◽  
Yuanliang Zhao ◽  
Yu Dong ◽  
Laizhou Song ◽  
...  
2019 ◽  
pp. 089270571987822
Author(s):  
Saud Aldajah ◽  
Mohammad Y Al-Haik ◽  
Waseem Siddique ◽  
Mohammad M Kabir ◽  
Yousef Haik

This study reveals the enhancement of mechanical and thermal properties of maleic anhydride-grafted polypropylene (PP- g-MA) with the addition of nanocrystalline cellulose (NCC). A nanocomposite was manufactured by blending various percentages of PP, MA, and NCC nanoparticles by means of a twin-screw extruder. The influence of varying the percentages of NCC on the mechanical and thermal behavior of the nanocomposite was studied by performing three-point bending, nanoindentation, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and Fourier-transform infrared (FTIR) spectroscopy tests. The novelty of this study stems on the NCC nanoparticles and their ability to enhance the mechanical and thermal properties of PP. Three-point bending and nanoindentation tests revealed improvement in the mechanical properties in terms of strength, modulus, and hardness of the PP- g-MA nanocomposites as the addition of NCC increased. SEM showed homogeneity between the mixtures which proved the presence of interfacial adhesion between the PP- g-MA incorporated with NCC nanoparticles that was confirmed by the FTIR results. DSC and TGA measurements showed that the thermal stability of the nanocomposites was not compromised due to the addition of the coupling agent and reinforced nanoparticles.


2014 ◽  
Vol 343 (1) ◽  
pp. 88-95 ◽  
Author(s):  
Reinaldo Yoshio Morita ◽  
Juliana Regina Kloss ◽  
Ronilson Vasconcelos Barbosa

2014 ◽  
Vol 215 (8) ◽  
pp. 716-724 ◽  
Author(s):  
Jenny Bandomir ◽  
André Schulz ◽  
Satomi Taguchi ◽  
Lena Schmitt ◽  
Hiroyuki Ohno ◽  
...  

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Manasa Nayani ◽  
Subhashini Gunashekar ◽  
Nidal Abu-Zahra

In this study polyurethane (PUR)-nanoclay composites were synthesized using methylene diphenyl diisocyanate, polyol, and hectorite clay. The weight percentage of hectorite clay was varied at three different levels to study its effect on the properties of the thermoplastic polyurethane nanocomposite. The nanocomposite polyurethane foam was synthesized in a 2-step reaction process. The first step involved the addition and dispersion of nanoclay into the isocyanate. The mixture was then mixed with the polyol, and the foam was cast in a preheated closed mold. The PUR-nanocomposite foams were analyzed for cell structure, physical, mechanical, and thermal properties. The composite foam showed significant increase in tensile and flexural strengths, abrasion resistance, and thermal properties.


e-Polymers ◽  
2016 ◽  
Vol 16 (4) ◽  
pp. 323-329 ◽  
Author(s):  
J. Sahari ◽  
M.A. Maleque

AbstractThis research was carried out to evaluate the effect of oil palm ash (OPA) on the mechanical and thermal properties of biocomposites. Different compositions of OPA (i.e. 0, 10, 20 and 30 vol%) were introduced to unsaturated polyester (UPE) by using simple casting method with methyl ethyl ketone peroxide (MEKP) as a hardener. The specimens were prepared based on ASTM D5083 standards for tensile testing. From the results, it was found that the mechanical properties of UPE/OPA composites were improved in modulus with increasing the OPA content. The physical properties of UPE/OPA were also investigated where the density of biocomposites decrease with increasing OPA while the water absorption of UPE/OPA increase with increasing OPA. The thermal and morphological characterization of the UPE/OPA composites have been done using TGA, DSC and SEM.


2012 ◽  
Vol 32 (8-9) ◽  
pp. 493-502 ◽  
Author(s):  
Kyeong Hoon Jang ◽  
Eung-Soo Kim ◽  
Young Ho Jeon ◽  
Jin-San Yoon

Abstract Na+ montmorillonite (MMT) was modified with benzyldimethyltetradecylammonium chloride (B13) and further with (3-mercaptopropyl)triethoxysilane and vinyltrimethoxysilane to prepare B13-MMT, mercaptomethylorthosilicate modified MMT (MTMO), and vinyltrimethoxysilane modified MMT (VTMO), respectively. The pristine and modified clays were compounded with an HTV-type silicone rubber (GP-30®), and the physical properties and morphology of the resulting rubber composites were examined. Both HTV/MTMO and HTV/VTMO exhibited an intercalated/exfoliated coexisting morphology, but the degree of exfoliation of the former composite was higher than that of the latter. Moreover, the thermal stability, as assessed by the onset temperature of thermal degradation, as well as the tensile stress, elongation at the break, and tear strength of HTV/MTMO was higher than those of HTV/B13-MMT and HTV/VTMO. However, the cross-linking density of HTV/MTMO was the lowest among the composites examined because the thiol groups of MTMO extinguished and abstracted the radicals formed by the curing agent. Accordingly, the improved mechanical and thermal properties of HTV/MTMO were attributed to the enhanced interactions between HTV and MTMO due to the chemical reaction between the thiol groups of MTMO and the vinyl groups of HTV.


Sign in / Sign up

Export Citation Format

Share Document