Solvent-free microwave-assisted synthesis of solketal from glycerol using transition metal ions promoted mordenite solid acid catalysts

2017 ◽  
Vol 434 ◽  
pp. 184-193 ◽  
Author(s):  
Samudrala Shanthi Priya ◽  
P.R. Selvakannan ◽  
Komandur V.R. Chary ◽  
Mannepalli Lakshmi Kantam ◽  
Suresh K. Bhargava
2010 ◽  
Vol 51 (10) ◽  
pp. 1356-1360 ◽  
Author(s):  
Aurore Richel ◽  
Pascal Laurent ◽  
Bernard Wathelet ◽  
Jean-Paul Wathelet ◽  
Michel Paquot

ChemInform ◽  
2007 ◽  
Vol 38 (44) ◽  
Author(s):  
Shainaz M. Landge ◽  
Valentina Atanassova ◽  
Muralidhara Thimmaiah ◽  
Bela Toeroek

RSC Advances ◽  
2015 ◽  
Vol 5 (127) ◽  
pp. 104715-104724 ◽  
Author(s):  
Avinash A. Chaugule ◽  
Amol R. Jadhav ◽  
Hern Kim

We have synthesized Brønsted solid acid catalysts which exhibited effective catalytic activity for acid catalyzed glycosylation reactions.


2018 ◽  
Vol 36 (8) ◽  
pp. 719-728 ◽  
Author(s):  
Indika Thushari ◽  
Sandhya Babel

Waste utilization is essential and challenging. Utilization of wastes gives environmental, economic, and social benefits. In this study, inexpensive, sulfonated solid acid catalysts were successfully prepared from palm empty fruit bunch (PEFB), coconut meal residue (CMR), and coconut coir husk (CH) waste by a simple protocol. It was found that prepared PEFB–BCS–SO3H, CMR–BCS–SO3H, and CH–BCS–SO3H catalysts have 4.79, 3.75, and 2.80 mmol g-1 acid density and 739.0, 89.77, and 61.49 m2 g-1 surface areas, respectively. Further, the presence of active functional groups on the surface of the catalysts was confirmed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Thermal stability of the catalysts was found below 150°C. Results show that biodiesel yield increases with increasing reaction time and methanol loading, when using microwave heating for biodiesel production from waste palm oil (WPO) and prepared catalysts. A maximum biodiesel yield of 95.5% was obtained by PEFB–BCS–SO3H in 60 minutes using 20:1 methanol:oil (molar ratio) at 70°C. CMR–BCS–SO3H and CH–BCS–SO3H obtained 88.7 and 88.5% biodiesel yields in 60 minutes, using 20:1 and 16:1 methanol:oil (molar ratio), at 70 and 110°C, respectively. Even though, the activity of the catalysts decreased during reuse, these are still of interest as the waste biomass of PEFB, CMR, and CH can be used for catalyst preparation and microwave-assisted biodiesel production from WPO.


2007 ◽  
Vol 48 (29) ◽  
pp. 5161-5164 ◽  
Author(s):  
Shainaz M. Landge ◽  
Valentina Atanassova ◽  
Muralidhara Thimmaiah ◽  
Béla Török

2016 ◽  
Vol 220 ◽  
pp. 457-463 ◽  
Author(s):  
Jie Cheng ◽  
Nan Wang ◽  
Dezhou Zhao ◽  
Dandan Qin ◽  
Wenqing Si ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document