Surface evaluation of titanium oxynitride coatings used for developing layered cardiovascular stents

2019 ◽  
Vol 99 ◽  
pp. 405-416 ◽  
Author(s):  
Natalia Beshchasna ◽  
Au Yeung Kwan Ho ◽  
Muhammad Saqib ◽  
Honorata Kraśkiewicz ◽  
Łukasz Wasyluk ◽  
...  
Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 77
Author(s):  
Enric Casanova-Batlle ◽  
Antonio J. Guerra ◽  
Joaquim Ciurana

Bioresorbable cardiovascular applications are increasing in demand as fixed medical devices cause episodes of late restenosis. The autologous treatment is, so far, the gold standard for vascular grafts due to the similarities to the replaced tissue. Thus, the possibility of customizing each application to its end user is ideal for treating pathologies within a dynamic system that receives constant stimuli, such as the cardiovascular system. Direct Ink Writing (DIW) is increasingly utilized for biomedical purposes because it can create composite bioinks by combining polymers and materials from other domains to create DIW-printable materials that provide characteristics of interest, such as anticoagulation, mechanical resistance, or radiopacity. In addition, bioinks can be tailored to encounter the optimal rheological properties for the DIW purpose. This review delves into a novel emerging field of cardiovascular medical applications, where this technology is applied in the tubular 3D printing approach. Cardiovascular stents and vascular grafts manufactured with this new technology are reviewed. The advantages and limitations of blending inks with cells, composite materials, or drugs are highlighted. Furthermore, the printing parameters and the different possibilities of designing these medical applications have been explored.


2006 ◽  
Vol 80A (4) ◽  
pp. 861-873 ◽  
Author(s):  
Chun‐Che Shih ◽  
Chun‐Ming Shih ◽  
Kuang‐Yi Chou ◽  
Shing‐Jong Lin ◽  
Yea‐Yang Su

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 566
Author(s):  
Pham Hong Quan ◽  
Iulian Antoniac ◽  
Florin Miculescu ◽  
Aurora Antoniac ◽  
Veronica Manescu (Păltânea) ◽  
...  

Fluoride conversion coatings on Mg present many advantages, among which one can find the reduction of the corrosion rate under “in vivo” or “in vitro” conditions and the promotion of the calcium phosphate deposition. Moreover, the fluoride ions released from MgF2 do not present cytotoxic effects and inhibit the biofilm formation, and thus these treated alloys are very suitable for cardiovascular stents and biodegradable orthopedic implants. In this paper, the biodegradation behavior of four new magnesium biodegradable alloys that have been developed in the laboratory conditions, before and after surface modifications by fluoride conversion (and sandblasting) coatings, are analyzed. We performed structural and surface analysis (XRD, SEM, contact angle) before and after applying different surface treatments. Furthermore, we studied the electrochemical behavior and biodegradation of all experimental samples after immersion test performed in NaCl solution. For a better evaluation, we also used LM and SEM for evaluation of the corroded samples after immersion test. The results showed an improved corrosion resistance for HF treated alloy in the NaCl solution. The chemical composition, uniformity, thickness and stability of the layers generated on the surface of the alloys significantly influence their corrosion behavior. Our study reveals that HF treatment is a beneficial way to improve the biofunctional properties required for the studied magnesium alloys to be used as biomaterials for manufacturing the orthopedic implants.


2017 ◽  
Vol 9 (1) ◽  
pp. 56
Author(s):  
A.D. Kruchinina ◽  
O.D. Lyubchenko ◽  
Y.P. Yastremskaya ◽  
A.N. Shatrov

2017 ◽  
Vol 35 (1) ◽  
pp. 254-264
Author(s):  
Joanna Piwowarczyk ◽  
Roman Jędrzejewski ◽  
Jolanta Baranowska

AbstractThe paper presents results of the investigation on the influence of deposition parameters, such as substrate temperature, total gas pressure and reactive gas composition on the structure, chemical composition and mechanical properties of aluminum oxynitride coatings obtained by pulsed laser deposition (PLD) method. Selection of process parameter ranges, which could be promising for aluminum oxynitride (ALON) coatings deposition, was the main objective of the work. Two series of experiments were carried out with varied pressure and temperature. It was found that from the chemical composition viewpoint, the most promising are atmospheres containing 20 % to 40 % oxygen. The nitrogen to oxygen ratios in the coatings can be controlled by increasing the total pressure or substrate temperature. However, increasing the pressure has a negative effect on the O + N:Al ratio, mechanical properties and quality of the coatings. The influence of temperature is much less drastic and more controllable. Increasing the deposition temperature is much more beneficial since it improves the mechanical properties and can compensate to some extent the negative effect of the total pressure. From the coating quality viewpoint, it is possible to establish an optimum temperature range for which the coatings are characterized by a compact structure and a limited number of droplets.


Biomaterials ◽  
2019 ◽  
Vol 204 ◽  
pp. 36-45 ◽  
Author(s):  
Yonghong Fan ◽  
Yu Zhang ◽  
Qian Zhao ◽  
Yinhong Xie ◽  
Rifang Luo ◽  
...  

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