Effects of curing conditions on structural evolution and mechanical properties of UV-curable polyurethane acrylate coatings

2018 ◽  
Vol 114 ◽  
pp. 58-67 ◽  
Author(s):  
Fei Dong ◽  
Suraj Maganty ◽  
Stephan J. Meschter ◽  
Junghyun Cho
Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 89
Author(s):  
Camilla Noè ◽  
Minna Hakkarainen ◽  
Marco Sangermano

Epoxy resins are among the most important building blocks for fabrication of thermosets for many different applications thanks to their superior thermo-mechanical properties and chemical resistance. The recent concerns on the environmental problems and the progressive depletion of petroleum feedstocks have drawn the research interest in finding biobased alternatives. Many curing techniques can be used to obtain the final crosslinked thermoset networks. The UV-curing technology can be considered the most environmentally friendly because of the absence of volatile organic compound (VOC) emissions and mild curing conditions. This review provides an overview of the state of the art of bio-based cationic UV-curable epoxy resins. Particular focus has been given to the sources of the bio-based epoxy monomers and the applications of the obtained products.


RSC Advances ◽  
2015 ◽  
Vol 5 (90) ◽  
pp. 73775-73782 ◽  
Author(s):  
Shuilai Qiu ◽  
Siyu Li ◽  
Youji Tao ◽  
Xiaming Feng ◽  
Bin Yu ◽  
...  

Poly(cyclotriphosphazene-co-4,4′-sulfonyldiphenol) (PZS) nanotubes with active hydroxyl groups were fabricated via an in situ template method under mild conditions, and then modified by acryloyl chloride to obtain the acryloyl-group functionalized PZS (f-PZS) nanotubes.


2006 ◽  
Vol 504 (1-2) ◽  
pp. 384-390 ◽  
Author(s):  
J.N. Tey ◽  
A.M. Soutar ◽  
S.G. Mhaisalkar ◽  
H. Yu ◽  
K.M. Hew

2019 ◽  
Vol 136 (43) ◽  
pp. 48147 ◽  
Author(s):  
Huajun Duan ◽  
Wenjing Dong ◽  
Xin Wang ◽  
Xiaoxiao Tao ◽  
Huiru Ma

2013 ◽  
Vol 773 ◽  
pp. 654-659 ◽  
Author(s):  
Qing Zhen Wen ◽  
Ying Zhang ◽  
Jin Hua Zhu

A series of UV-PUA films with different active diluents were prepared, The effect of the content of active diluent TPGDA or TMPTA on Photopolymerization kinetics and Mechanical properties was studied. The effect of formulation on mechanical properties was investigated. The results showed that when the content of oligomer PUA was 40%-45%, the content of HEA was 8%-10%, the content of TPGDA was 10%-14% and the content of TMPTA was 18%-25% ,PUA films with good mechanical properties were obtained.


e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 830-844
Author(s):  
Zekun Jing ◽  
Yakun Guo ◽  
Meng Ren ◽  
Xingtao Zhao ◽  
Hong Shao ◽  
...  

Abstract Parylene C (PC) films have been widely used in many fields, such as metal anti-corrosion, electronic packaging, etc. However, the relatively poor mechanical properties and the deteriorated water barrier performance due to the easy fracture under external stress have restricted their application. It is a relatively simple and good method to maintain the water vapor barrier and enhance the mechanical properties of PC film by covering a flexible coating on its surface. In this work, a new polyurethane acrylate (PUA) coating was prepared and coated on the PC film by ultraviolet curing technology to form the PC/PUA composite film. The results showed that the PUA coatings could improve the water vapor barrier and mechanical properties of the PC film simultaneously. The water vapor transmittance rate was reduced from 1.1791 g·(m−2·day−1) of the original PC film to 0.5636 g·(m−2·day−1) of the PC/PUA composite film. The elongation at break and the impact energy were increased to 48.36% and 41.67%, respectively, which would widen the application of PC films in the fields of flexible electronics or smart wear.


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