Direct Comparison of Gamma, Electron Beam and X-ray Irradiation Doses on Characteristics of Low-density Polyethylene, Polypropylene Homopolymer, Polyolefin Elastomer and Chlorobutyl Rubber Medical Device Polymers

2021 ◽  
pp. 109505
Author(s):  
Leonard S. Fifield ◽  
Matt Pharr ◽  
David Staack ◽  
Suresh D. Pillai ◽  
Larry Nichols ◽  
...  
Keyword(s):  
Electron Beam ◽  
Medical Device ◽  
Low Density Polyethylene ◽  
Low Density ◽  
X Ray ◽  
Polyolefin Elastomer ◽  
Chlorobutyl Rubber

Surface and Adhesive Properties of Low-Density Polyethylene after Radiation Cross-Linking

2014 ◽  
Vol 606 ◽  
pp. 265-268 ◽  
Author(s):  
Martin Bednarik ◽  
David Manas ◽  
Miroslav Manas ◽  
Martin Ovsik ◽  
Jan Navratil ◽  
...  
Keyword(s):  
Electron Beam ◽  
High Performance ◽  
Chemical Properties ◽  
Low Density Polyethylene ◽  
Cross Linking ◽  
Low Density ◽  
X Rays ◽  
Radiation Processing ◽  
Adhesive Properties ◽  
Γ Rays

Radiation cross-linking gives inexpensive commodity plastics and technical plastics the mechanical, thermal, and chemical properties of high-performance plastic. This upgrading of the plastics enables them to be used in conditions which they would not be able to with stand otherwise. The irradiation cross-linking of thermoplastic materials via electron beam or cobalt 60 (gammy rays) is performed separately, after processing. Generally, ionizing radiation includes accelerated electrons, gamma rays and X-rays. Radiation processing with an electron beam offers several distinct advantages when compared with other radiation sources, particularly γ-rays and x-rays. The process is very fast, clean and can be controlled with much precision. There is no permanent radioactivity since the machine can be switched off. In contrast to γ-rays and x-rays, the electron beam can steered relatively easily, thus allowing irradiation of a variety of physical shapes. The energy-rich beta rays trigger chemical reactions in the plastics which results in networking of molecules (comparable to the vulcanization of rubbers which has been in industrial use for so long). The energy from the rays is absorbed by the material and cleavage of chemical bonds takes place. This releases free radicals which in next phase from desired molecular bonds. This article describes the effect of radiation cross-linking on the surface and adhesive properties of low-density polyethylene.

Effect of Functionalized MWCNTs with Surfactant and Coupling Agent on Properties of LDPE/POE Blends

2011 ◽  
Vol 43 (6) ◽  
pp. 543-558 ◽  
Author(s):  
Z. Chen ◽  
S. Chen ◽  
J. Zhang
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Tensile Strength ◽  
Multiwalled Carbon Nanotubes ◽  
Crystallization Behavior ◽  
Low Density Polyethylene ◽  
Favorable Effect ◽  
Low Density ◽  
Multiwalled Carbon ◽  
Polyolefin Elastomer

The surfactant, sodium dodecylbenzenesulfonate (NaDDBS) and coupling agents, γ-aminopropyltriethoxy sliane (KH550) and isopropyl dioleic(dioctylphosphate) titanate (NDZ101) were used to treat multiwalled carbon nanotubes in this work. The effects of surface modification of multiwalled carbon nanotubes on crystallization behavior, mechanical properties, and electrical properties of low density polyethylene/polyolefin elastomer/multiwalled carbon nanotubes composites were studied. The results showed that NaDDBS, KH550, and NDZ101 had a favorable effect of improving the dispersion of multiwalled carbon nanotubes, but it cannot improve the interfacial interactionbetween multiwalled carbon nanotubes and the matrix. The improvement in dispersion favored the crystallization behavior and mechanical properties. Modified multiwalled carbon nanotubes had a better acceleration nucleation effect than raw multiwalled carbon nanotubes on low density polyethylene/polyolefin elastomer blends at low content (≤1 wt%). The tensile strength of low density polyethylene/polyolefin elastomer/multiwalled carbon nanotubes composites with modified multiwalled carbon nanotubes increased with lower multiwalled carbon nanotubes content (≤1 wt%), and KH550 and NDZ101 led low density polyethylene/polyolefin elastomer/multiwalled carbon nanotubes composites to possess a higher tensile strength than that of NaDDBS with 1 wt% content. NaDDBS, KH550, and NDZ101 had a minor influence on the dielectric properties of the composites and even caused a decrease in the dielectric loss of composites with 10 wt% multiwalled carbon nanotubes content.

scholarly journals Oil-based mud waste reclamation and utilisation in low-density polyethylene composites

2020 ◽  
Vol 38 (12) ◽  
pp. 1331-1344
Author(s):  
Shohel Siddique ◽  
Kyari Yates ◽  
Kerr Matthews ◽  
Laszlo J Csetenyi ◽  
James Njuguna
Keyword(s):  
Inductively Coupled Plasma ◽  
Oil And Gas ◽  
Microscopic Analysis ◽  
Optical Emission ◽  
Fluorescence Analysis ◽  
Xrd Analysis ◽  
Low Density Polyethylene ◽  
Emission Spectrometry ◽  
Low Density ◽  
X Ray

Oil-based mud (OBM) waste from the oil and gas exploration industry can be valorised to tailor-made reclaimed clay-reinforced low-density polyethylene (LDPE) nanocomposites. This study aims to fill the information gap in the literature and to provide opportunities to explore the effective recovery and recycling techniques of the resources present in the OBM waste stream. Elemental analysis using inductively coupled plasma–optical emission spectrometry (ICP-OES) and X-ray fluorescence analysis, chemical structural analysis by Fourier transform infrared (FTIR) spectroscopy, and morphological analysis of LDPE/organo-modified montmorillonite (LDPE/MMT) and LDPE/OBM slurry nanocomposites by scanning electron microscopy (SEM) have been conducted. Further analysis including calorimetry, thermogravimetry, spectroscopy, microscopy, energy dispersive X-ray analysis and X-ray diffraction (XRD) was carried out to evaluate the thermo-chemical characteristics of OBM waste and OBM clay-reinforced LDPE nanocomposites, confirming the presence of different clay minerals including inorganic salts in OBM slurry powder. The microscopic analysis revealed that the distance between polymer matrix and OBM slurry filler is less than that of MMT, which suggests better interfacial adhesion of OBM slurry compared with the adhesion between MMT and LDPE matrix. This was also confirmed by XRD analysis, which showed the superior delamination structure OBM slurry compared with the structure of MMT. There is a trend noticeable for both of these fillers that the nanocomposites with higher percentage filler contents (7.5 and 10.0 wt% in this case) were indicated to act as a thermal conductive material. The heat capacity values of nanocomposites decreased about 33% in LDPE with 7.5 wt% MMT and about 17% in LDPE with 10.0 wt% OBM slurry. It was also noted, for both nanocomposites, that the residue remaining after 1000°C increases with the incremental wt% of fillers in the nanocomposites. There is a big difference in residue amount (in %) left after thermogravimetric analysis in the two nanocomposites, indicating that OBM slurry may have significant influence in decomposing LDPE matrix; this might be an interesting area to explore in the future. The results provide insight and opportunity to manufacture waste-derived renewable nanocomposites with enhanced structural and thermal properties.

scholarly journals Three-Phase Characterization of Uniaxially Stretched Linear Low-Density Polyethylene

2011 ◽  
Vol 2011 ◽  
pp. 1-7 ◽  
Author(s):  
Blerina Kolgjini ◽  
Gustaaf Schoukens ◽  
Paul Kiekens
Keyword(s):  
Raman Spectra ◽  
Draw Ratio ◽  
Phase Morphology ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Linear Low Density Polyethylene ◽  
Structure Variation ◽  
X Ray ◽  
Three Phase ◽  
Cold Draw

This study comprises a detailed morphological study of cold-drawn polyethylene monofilaments by Raman spectroscopy, differential scanning calorimetry (DSC) and X-ray measurements. The structure of the three-phase morphology of the linear low-density polyethylene monofilaments was investigated by combining these measurements. It was found that the most important structure variation was found in the intermediate or rigid amorphous phase, whereby the amounts of crystalline and amorphous phases were nearly constant and almost independent of the cold-draw ratio. The intermediate third phase contains gauche and transmolecules, and the amount of transmolecules was increased with the cold-draw ratio and was directly related to this cold-draw ratio. It was found that the two peaks in the Raman spectra, respectively, at 1303 and 1295 cm-1, can be correlated to the amount of gauche and transmolecules in the polyethylene monofilaments. A good and new insight into the three-phase morphology was obtained by combining the DSC and X-ray measurements with the amounts of trans- and gauche molecules from the Raman spectra analysis.

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