Enhancement of mechanical property and corrosion resistance of 316L stainless steels by low temperature arc plasma nitriding

2016 ◽  
Vol 298 ◽  
pp. 64-72 ◽  
Author(s):  
W.J. Yang ◽  
M. Zhang ◽  
Y.H. Zhao ◽  
M.L. Shen ◽  
H. Lei ◽  
...  
2019 ◽  
Vol 63 (3) ◽  
pp. 214-219 ◽  
Author(s):  
Dorina Kovács ◽  
János Dobránszky

Austenitic stainless steels have low corrosion resistance in applications where strong acids and vapors attack the surface, typically in food and chemical industries. This drawback can be improved by surface treatments. Salt bath, gaseous or plasma-based surface treatments are a diffusion process for improving the hardness of the surface layer of stainless steels without significantly affecting their corrosion resistance. Low temperature nitriding and carburizing process can form a diffusion zone or/and compound phase. The corrosion-wear resistance of austenitic stainless steels can also improve with low temperature plasma nitriding and carburizing. The effect of these treatments on hardness and corrosion resistance was investigated in this research. Optical microscopy and Vickers hardness test were used for the characterization of the surface and potentiodynamic tests were performed to determine the corrosion rate. The results show that the hardness of the kolsterised sample is higher compared to the plasma nitride one. Beside this property, the corrosion rate is similar, but pitting corrosion was observed on the surface, due to the Cr2N formation.


Metals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1845
Author(s):  
Francesca Borgioli ◽  
Emanuele Galvanetto ◽  
Tiberio Bacci

Low-temperature nitriding allows to improve surface hardening of austenitic stainless steels, maintaining or even increasing their corrosion resistance. The treatment conditions to be used in order to avoid the precipitation of large amounts of nitrides are strictly related to alloy composition. When nickel is substituted by manganese as an austenite forming element, the production of nitride-free modified surface layers becomes a challenge, since manganese is a nitride forming element while nickel is not. In this study, the effects of nitriding conditions on the characteristics of the modified surface layers obtained on an austenitic stainless steel having a high manganese content and a negligible nickel one, a so-called nickel-free austenitic stainless steel, were investigated. Microstructure, phase composition, surface microhardness, and corrosion behavior in 5% NaCl were evaluated. The obtained results suggest that the precipitation of a large volume fraction of nitrides can be avoided using treatment temperatures lower than those usually employed for nickel-containing austenitic stainless steels. Nitriding at 360 and 380 °C for duration up to 5 h allows to produce modified surface layers, consisting mainly of the so-called expanded austenite or gN, which increase surface hardness in comparison with the untreated steel. Using selected conditions, corrosion resistance can also be significantly improved.


Coatings ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 98 ◽  
Author(s):  
Francesca Borgioli ◽  
Emanuele Galvanetto ◽  
Tiberio Bacci

Low-temperature nitriding of austenitic stainless steels produces modified surface layers, consisting mainly of the S phase, which improve surface hardness and corrosion resistance. Because of the localized plastic deformations, owing to modified layer formation, and ion bombardment occurring during the process itself, this treatment produces also modifications of surface morphology and roughness, which can affect wettability and corrosion behavior. In this study the effects of plasma nitriding, performed using different treatment conditions, on the surface morphology and roughness, and thus on wettability and corrosion resistance, of AISI 202 specimens with different initial finishings (2D and polished finishing) were investigated. Different probe liquids, having both high (bi-distilled water and solution of 3.5% NaCl) and low (ethanol and rapeseed oil) surface tension, were employed for assessing the wetting behavior with the sessile drop method. The contact angle values for water increased markedly when nitriding was performed on polished samples, while this increase was smaller for 2D samples, and on selected specimens a hydrophobic behavior was observed. Very low contact angle values were registered using low surface tension liquids, suggesting an oleophilic behavior. Corrosion resistance in a 5% NaCl solution was assessed, and it depended on the characteristics of the nitrided specimens.


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