Prediction of organic carbon and total nitrogen contents in organic wastes and their composts by Infrared spectroscopy and partial least square regression

Talanta ◽  
2017 ◽  
Vol 167 ◽  
pp. 352-358 ◽  
Author(s):  
M. Sisouane ◽  
M.M. Cascant ◽  
S. Tahiri ◽  
S. Garrigues ◽  
M. EL Krati ◽  
...  
2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Freddy Bangelesa ◽  
Elhadi Adam ◽  
Jasper Knight ◽  
Inos Dhau ◽  
Marubini Ramudzuli ◽  
...  

Soil organic carbon constitutes an important indicator of soil fertility. The purpose of this study was to predict soil organic carbon content in the mountainous terrain of eastern Lesotho, southern Africa, which is an area of high endemic biodiversity as well as an area extensively used for small-scale agriculture. An integrated field and laboratory approach was undertaken, through measurements of reflectance spectra of soil using an Analytical Spectral Device (ASD) FieldSpec® 4 optical sensor. Soil spectra were collected on the land surface under field conditions and then on soil in the laboratory, in order to assess the accuracy of field spectroscopy-based models. The predictive performance of two different statistical models (random forest and partial least square regression) was compared. Results show that random forest regression can most accurately predict the soil organic carbon contents on an independent dataset using the field spectroscopy data. In contrast, the partial least square regression model overfits the calibration dataset. Important wavelengths to predict soil organic contents were localised around the visible range (400–700 nm). This study shows that soil organic carbon can be most accurately estimated using derivative field spectroscopy measurements and random forest regression.


2020 ◽  
Vol 28 (3) ◽  
pp. 153-162
Author(s):  
Lijun Wu ◽  
Baoxing Wang ◽  
Lei Zhang ◽  
Rumin Duan ◽  
Rui Gao ◽  
...  

Near infrared spectroscopy coupled with sample set partitioning based on joint X-Y distances combined with partial least square regression was applied to the quantitative analysis of six routine chemicals, five physical indices and four macromolecular substances in reconstituted tobacco. The quantitative regression models of these indices were established by joint X-Y distances combined with partial least square regression. Results showed remarkable correlation between predicted and measured values of the 15 indices. The root mean square error of prediction of all the indices was low, and the correlation coefficients of these PLS models were all greater than 0.85. This was the first study in which NIR spectroscopy had been used to determine the macromolecular substances as well as certain physical indices in reconstituted tobacco. Results showed that this method could be feasibly applied for rapid detection of these properties of industrial products.


Author(s):  
PATTEERA SODATA ◽  
JOMJAI PEERAPATTANA

Objective: This study aimed to apply near-infrared spectroscopy along with a thief as a tool to determine the endpoint of the blending process. Methods: The calibration model was constructed by partial least square regression. The best model was applied to determine the endpoint of the blending process, also the effect of loading order on the endpoint for the blending of the formulation containing a low concentration of the active pharmaceutical ingredient. Results: The best partial least square regression model yielded the lowest root mean square error of calibration of 1.4004, the lowest root mean square error of prediction of 1.4108 and the highest correlation coefficient of 0.9921. Validation study revealed the reference values were not statistically different from those of the predicted values. The model could predict the endpoint of the blending process with acceptable precision and accuracy. Standard deviation of the content of active pharmaceutical ingredients was ≤ 3% of the target after eighteen minutes of the blending process, which indicated the uniformity of powder blends. Additionally, the model revealed the order of powder loading slightly affected the blending time. The protocol that loaded the active pharmaceutical ingredient first or last needed a longer time to achieve the uniformity of blend. Conclusion: NIR spectroscopy is the rapid and effective tools that could be applied to study the blending process in the pharmaceutical manufacturing.


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