Production of benzene/toluene/ethyl benzene/xylene (BTEX) via multiphase catalytic pyrolysis of hazardous waste polyethylene using low cost fly ash synthesized natural catalyst

2018 ◽  
Vol 77 ◽  
pp. 114-130 ◽  
Author(s):  
Pramendra Gaurh ◽  
Hiralal Pramanik
Keyword(s):  
Fly Ash ◽  
Hazardous Waste ◽  
Catalytic Pyrolysis ◽  
Low Cost ◽  
Ethyl Benzene ◽  
Benzene Toluene ◽  
Waste Polyethylene

scholarly journals Catalytic Pyrolysis of a Residual Plastic Waste Using Zeolites Produced by Coal Fly Ash

Catalysts ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1113
Author(s):  
Marco Cocchi ◽  
Doina De Angelis ◽  
Leone Mazzeo ◽  
Piergianni Nardozi ◽  
Vincenzo Piemonte ◽  
...  
Keyword(s):  
Fly Ash ◽  
Energy Demand ◽  
Catalytic Pyrolysis ◽  
Low Cost ◽  
Coal Fly Ash ◽  
Plastic Waste ◽  
Scanning Calorimetry ◽  
Contact Mode ◽  
Degradation Temperature ◽  
Pyrolysis Oils

The plastic film residue (PFR) of a plastic waste recycling process was selected as pyrolysis feed. Both thermal and catalytic pyrolysis experiments were performed and coal fly ash (CFA) and X zeolites synthesized from CFA (X/CFA) were used as pyrolysis catalysts. The main goal is to study the effect of low-cost catalysts on yields and quality of pyrolysis oils. NaX/CFA, obtained using the fusion/hydrothermal method, underwent ion exchange followed by calcination in order to produce HX/CFA. Firstly, thermogravimetry and differential scanning calorimetry (TG and DSC, respectively) analyses evaluated the effect of catalysts on the PFR degradation temperature and the process energy demand. Subsequently, pyrolysis was carried out in a bench scale reactor adopting the liquid-phase contact mode. HX/CFA and NaX/CFA reduced the degradation temperature of PFR from 753 to 680 and 744 K, respectively, while the degradation energy from 2.27 to 1.47 and 2.07 MJkg−1, respectively. Pyrolysis runs showed that the highest oil yield (44 wt %) was obtained by HX/CFA, while the main products obtained by thermal pyrolysis were wax and tar. Furthermore, up to 70% of HX/CFA oil was composed by gasoline range hydrocarbons. Finally, the produced gases showed a combustion energy up to 8 times higher than the pyrolysis energy needs.

A Noble and Economical Method for the Synthesis of Low Cost Zeolites From Coal Fly Ash Waste

2021 ◽  
pp. 1-19
Author(s):  
Virendra Kumar Yadav ◽  
R Suriyaprabha ◽  
Gajendra Kumar Inwati ◽  
Nitin Gupta ◽  
Bijendra Singh ◽  
...  
Keyword(s):  
Fly Ash ◽  
Low Cost ◽  
Coal Fly Ash ◽  
Economical Method

scholarly journals Conditions chimiques contrôlant l'atténuation naturelle des BTEX et solvants chlorés : un état des connaissances

2005 ◽  
Vol 14 (4) ◽  
pp. 419-444 ◽  
Author(s):  
O. Atteia ◽  
M. Franceschi
Keyword(s):  
Cette Technique ◽  
Ethyl Benzene ◽  
Benzene Toluene

L'atténuation naturelle des BTEX (Benzène, Toluène, Ethyl-benzène, Xylène) et des solvants chlorés est de plus en plus étudiée en raison des potentialités offertes par cette technique de gestion. Cet article, après avoir présenté les aspects abiotiques de l'atténuation détaille les conditions chimiques nécessaires à la réalisation des réactions de biodégradation des polluants organiques. Les aspects thermodynamiques sont abordés afin de décliner les réactions possibles et celles qui ne le sont pas selon les environnements chimiques. La dégradation des BTEX est focalisée sur le benzène, produit le plus toxique et le moins dégradable sur la plupart des sites. Les détails de la dégradation du benzène sur le terrain sont analysés dans la littérature et leur comparaison permet de décrire les mécanismes responsables de celle-ci. Dans le cas des solvants chlorés, l'attention est portée sur le TCE (Trichloréthylène), produit le plus couramment rencontré sur les sites pollués. Une mise en parallèle des évolutions de teneurs observées et des conditions chimiques locales permet de mettre en évidence les conditions nécessaires à la dégradation du TCE, et de ses congénères, ainsi que les cinétiques de dégradation dans différentes conditions. La mise en évidence du rôle prépondérant des conditions chimiques conduit à remettre en cause l'utilisation répandue des constantes de dégradation du premier ordre et donne des pistes pour les modèles nécessaires à une prédiction plus fine de l'atténuation naturelle.

scholarly journals Evolution of Wireless Sensor Network for Air Quality Measurements

Electronics ◽  
2018 ◽  
Vol 7 (12) ◽  
pp. 342 ◽  
Author(s):  
Patricia Arroyo ◽  
Jesús Lozano ◽  
José Suárez
Keyword(s):  
Air Quality ◽  
Sensor Network ◽  
Low Cost ◽  
Principal Component ◽  
Solar Panels ◽  
Success Rates ◽  
Sampling System ◽  
Air Quality Measurements ◽  
Zigbee Protocol ◽  
Benzene Toluene

This study addresses the development of a wireless gas sensor network with low cost, small size, and low consumption nodes for environmental applications and air quality detection. Throughout the article, the evolution of the design and development of the system is presented, describing four designed prototypes. The final proposed prototype node has the capacity to connect up to four metal oxide (MOX) gas sensors, and has high autonomy thanks to the use of solar panels, as well as having an indirect sampling system and a small size. ZigBee protocol is used to transmit data wirelessly to a self-developed data cloud. The discrimination capacity of the device was checked with the volatile organic compounds benzene, toluene, ethylbenzene, and xylene (BTEX). An improvement of the system was achieved to obtain optimal success rates in the classification stage with the final prototype. Data processing was carried out using techniques of pattern recognition and artificial intelligence, such as radial basis networks and principal component analysis (PCA).

scholarly journals DETERMINATION OF BTEX IN ENVIRONMENTAL SAMPLES: DEVELOPMENT AND PROTECTION OF TECHNOLOGIES AND ANALYTICAL METHODS

2019 ◽  
Vol 16 (31) ◽  
pp. 431-439
Author(s):  
Helilma de Andréa PINHEIRO ◽  
Ana Paula Mota FERREIRA ◽  
Ismael Carlos Braga ALVES ◽  
Antônio Fernandes SANTOS JÚNIOR ◽  
Raquel Bezerra dos Santos SAWCZUK ◽  
...  
Keyword(s):  
Petroleum Hydrocarbons ◽  
Environmental Samples ◽  
Low Cost ◽  
The United States ◽  
Operational Control ◽  
Toxic Compounds ◽  
Chromatographic Techniques ◽  
Benzene Toluene ◽  
And Storage

The contamination of water and soil by petroleum hydrocarbons is reported quite frequently, mainly due to accidents involving transport and storage of fuels. Among the most toxic compounds the most volatile benzene, toluene, ethylbenzene and xylene (BTEX). Residues of these compounds can cause serious environmental and public health troubles. Thus, more sensitive, selective and low-cost techniques, focused on the analysis and monitoring of these contaminants are being developed in order to establish operational control and to comply with local laws, but the intellectual property of such technologies is still unknown. The present study shows the panorama about patents, thesis and dissertations which have been already published on this theme. Together, the United States and China hold the largest number of patents, and most of thesis/dissertations describe methodologies for BTEX detection in water, although numerous environmental problems caused by oils in the soil had been reported. Also, the methods based on chromatographic techniques stand out in relation to the other techniques. It was possible to verify important advances in the field of sensors, especially the electrochemical ones, in order to solve the analytical gaps.

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