Leaching kinetics of lead from lead (II) sulphate in aqueous calcium chloride and magnesium chloride solutions

1997 ◽  
Vol 47 (1) ◽  
pp. 137-147 ◽  
Author(s):  
Dragan Sinadinović ◽  
Željko Kamberović ◽  
Aleksandar Šutić
Keyword(s):  
Calcium Chloride ◽  
Magnesium Chloride ◽  
Leaching Kinetics ◽  
Chloride Solutions ◽  
Kinetics Of

scholarly journals Obtaining artificial carnallites from magnesium chloride brines

2020 ◽  
Vol 56 (2) ◽  
pp. 229-234
Author(s):  
V. V. Shevchuk ◽  
T. N. Potkina ◽  
A. I. Vaitenka ◽  
O. V. Smetanina
Keyword(s):  
Calcium Chloride ◽  
Magnesium Chloride ◽  
Calcium Sulfate ◽  
Raw Materials ◽  
Potassium Sulfate ◽  
Sulfate Ions ◽  
Chloride Solutions ◽  
Excess Concentration ◽  
Almost All ◽  
Complete Precipitation

The excess of magnesium chloride brines is formed during the polymineral ores processing in order to obtain potassium sulfate. One way to regenerate such brines is to produce artificial carnallite. It is necessary to purify these brines from sulfates for their further use as raw materials for the artificial carnallite production. In this work, the process of desulfurization of magnesium chloride brines with a solution of calcium chloride is studied. The temperature and the processing time, the magnesium chloride solutions concentration and the consumption of desulfurizing agent (calcium chloride) influence on the degree of magnesium chloride solutions purification from sulfate ions was determined. It has been established that almost all sulfate ions interact with calcium ion in 15 minutes and the desulfurization degree reaches 98,08 %. The increase in duration of the suspension mixing is necessary in order to establish equilibrium in the system and relieve the supersaturation in the solution. It has been shown that with increasing solutions saturation with MgCl2, the degree of the magnesium chloride brines purification from SO4 2– ion increases. Complete precipitation of calcium sulfate requires a certain excess concentration of calcium chloride.

KINETICS OF CALCIUM ION ABSORPTION INTO CARROT TISSUE DURING IMMERSION IN CALCIUM CHLORIDE SOLUTIONS

2003 ◽  
Vol 27 (2) ◽  
pp. 75-85 ◽  
Author(s):  
A. QUINTERO-RAMOS ◽  
M. C. BOURNE ◽  
J. BARNARD ◽  
A. ANZALDÚA-MORALES ◽  
R. GONZÁLEZ-LAREDO ◽  
...  
Keyword(s):  
Calcium Chloride ◽  
Calcium Ion ◽  
Chloride Solutions ◽  
Ion Absorption ◽  
Kinetics Of

Study on leaching kinetics of hexavalent chromium from aged calcium-free chromium slag

2021 ◽  
pp. 1-13
Author(s):  
Quan Qi ◽  
Liang Li ◽  
Liangyu Wei ◽  
Baoming Hu ◽  
Zheng Liu ◽  
...  
Keyword(s):  
Hexavalent Chromium ◽  
Resource Utilization ◽  
Scientific Basis ◽  
Diffusion Reaction ◽  
Leaching Kinetics ◽  
Leaching Rate ◽  
Chromium Slag ◽  
Leaching Solution ◽  
Main Components ◽  
Kinetics Of

To provide a scientific basis for the resource utilization of chromium slag, this article studies the release law of hexavalent chromium in the aged calcium-free chromium slag. XRD (X-ray diffractometer) and MLA (Mineral Liberation Analyzer) were used to analyze the composition of the chromium slag; using sulfuric acid-nitric acid as the leaching solution, the release law of hexavalent chromium in chromium slag and the leaching kinetics were studied. The results show that main components of the chromium slag are magnesioferrite, chromite, hematite, hydrargillite, and spinel; chromium is mainly present in chromite and magnesioferrite; the leaching rate of hexavalent chromium increases with the increase of temperature or the decrease of pH. The analysis of leaching kinetics shows the leaching rate is controlled by the internal diffusion reaction, and the apparent activation energy is 11.93 kJ·mol–1. The chromium slag is aged in high temperature seasons, which is conducive to the precipitation of hexavalent chromium in the chromium slag, can increase the yield of chromate in the roasting kiln, and is conducive to resource utilization; chromium slag should be stored in order to prevent acid rain erosion which leads to environmental pollution risk (e.g. drinking water).

Kinetics of reaction between plutonium(III) and chlorine in chloride solutions

1962 ◽  
Vol 24 (12) ◽  
pp. 1617-1621 ◽  
Author(s):  
A.S. Ghosh Mazumdar ◽  
K.P.R. Pisharody ◽  
R.N. Singh
Keyword(s):  
Chloride Solutions ◽  
Kinetics Of Reaction ◽  
Kinetics Of

Leaching kinetics of copper and valuable metal extraction from copper-cadmium residues of zinc hydrometallurgy by oxidation acid leaching

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jihao Guo ◽  
Hongao Xu ◽  
Bo Li ◽  
Yonggang Wei ◽  
Hua Wang
Keyword(s):  
Hydrogen Peroxide ◽  
Acid Concentration ◽  
Acid Leaching ◽  
Metal Extraction ◽  
Agitation Rate ◽  
Leaching Kinetics ◽  
Solid Ratio ◽  
Zinc Hydrometallurgy ◽  
Kinetics Of ◽  
Leaching Efficiency

Abstract Multiple purification of zinc sulfate solution is an important process for zinc hydrometallurgy, and large quantities of copper-cadmium residues are generated as byproducts in this process. Copper-cadmium residues contain a large number of valuable metals that must be recovered. A comprehensive extraction process has been proposed using sulfuric acid as the leaching reagent and hydrogen peroxide as the oxidizing reagent. The effects of acid concentration, leaching temperature, leaching time, liquid-to-solid ratio, hydrogen peroxide dosage and stirring speed on the leaching efficiency were investigated. The optimum conditions were determined as an acid concentration of 150 g/L, liquid-to-solid ratio of 4:1, hydrogen peroxide amount of 20 mL, time of 60 min, temperature of 30 °C, particle size of −d75 μm, and agitation rate of 300 r/min. It was concluded that the leaching efficiency of copper and cadmium reached 97%, but because of the existence of zinc sulfide in the residues, a lower leaching efficiency of zinc was obtained. Furthermore, the leaching kinetics of copper was also studied based on the shrinking core model. The activation energy for copper leaching was 5.06 kJ/mol, and the leaching process was controlled by the diffusion through the product layer.

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