Adsorptive removal of 2-chlorophenol by low-cost coir pith carbon

2003 ◽  
Vol 98 (1-3) ◽  
pp. 257-274 ◽  
Author(s):  
C Namasivayam ◽  
D Kavitha
Keyword(s):  
Low Cost ◽  
Adsorptive Removal ◽  
Coir Pith

scholarly journals Adsorptive Removal of Phosphate from Aqueous Solutions Using Low-Cost Volcanic Rocks: Kinetics and Equilibrium Approaches

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1312
Author(s):  
Dereje Tadesse Mekonnen ◽  
Esayas Alemayehu ◽  
Bernd Lennartz
Keyword(s):  
Aqueous Solutions ◽  
Low Income ◽  
Low Cost ◽  
Volcanic Rocks ◽  
Phosphate Removal ◽  
Phosphate Adsorption ◽  
Adsorptive Capacity ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Adsorptive Removal

The contamination of surface and groundwater with phosphate originating from industrial and household wastewater remains a serious environmental issue in low-income countries. Herein, phosphate removal from aqueous solutions was studied using low-cost volcanic rocks such as pumice (VPum) and scoria (VSco), obtained from the Ethiopian Great Rift Valley. Batch adsorption experiments were conducted using phosphate solutions with concentrations of 0.5 to 25 mg·L−1 to examine the adsorption kinetic as well as equilibrium conditions. The experimental adsorption data were tested by employing various equilibrium adsorption models, and the Freundlich and Dubinin-Radushkevich (D-R) isotherms best depicted the observations. The maximum phosphate adsorption capacities of VPum and VSco were calculated and found to be 294 mg·kg−1 and 169 mg·kg−1, respectively. A pseudo-second-order kinetic model best described the experimental data with a coefficient of correlation of R2 > 0.99 for both VPum and VSco; however, VPum showed a slightly better selectivity for phosphate removal than VSco. The presence of competitive anions markedly reduced the removal efficiency of phosphate from the aqueous solution. The adsorptive removal of phosphate was affected by competitive anions in the order: HCO3− >F− > SO4−2 > NO3− > Cl− for VPum and HCO3− > F− > Cl− > SO4−2 > NO3− for VSco. The results indicate that the readily available volcanic rocks have a good adsorptive capacity for phosphate and shall be considered in future studies as test materials for phosphate removal from water in technical-scale experiments.

Low-Cost Magnetic Fe3O4/Chitosan Nanocomposites for Adsorptive Removal of Carcinogenic Diazo Dye

2020 ◽  
Vol 54 (4) ◽  
pp. 655-663
Author(s):  
Avinash Kadam ◽  
Jiseon Jang ◽  
Seong-Rin Lim ◽  
Dae Sung Lee
Keyword(s):  
Low Cost ◽  
Adsorptive Removal ◽  
Diazo Dye ◽  
Magnetic Fe3o4

scholarly journals Magnetic Fe3O4@Chitosan Carbon Microbeads: Removal of Doxycycline from Aqueous Solutions through a Fixed Bed via Sequential Adsorption and Heterogeneous Fenton-Like Regeneration

2018 ◽  
Vol 2018 ◽  
pp. 1-14 ◽  
Author(s):  
Bo Bai ◽  
Xiaohui Xu ◽  
Changchuan Li ◽  
Jianyu Xing ◽  
Honglun Wang ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
High Efficiency ◽  
Low Cost ◽  
Fixed Bed ◽  
Breakthrough Curves ◽  
Chitosan Hydrogel ◽  
Fixed Bed Column ◽  
Adsorptive Removal ◽  
Sequential Adsorption ◽  
Cracking Process

The adsorptive removal of antibiotics from aqueous solutions is recognized as the most suitable approach due to its easy operation, low cost, nontoxic properties, and high efficiency. However, the conventional regeneration of saturated adsorbents is an expensive and time-consuming process in practical wastewater treatment. Herein, a scalable adsorbent of magnetic Fe3O4@chitosan carbon microbeads (MCM) was successfully prepared by embedding Fe3O4 nanoparticles into chitosan hydrogel via an alkali gelation-thermal cracking process. The application of MCM composites for the adsorptive removal of doxycycline (DC) was evaluated using a fixed-bed column. The results showed that pH, initial concentration, flow rate, and bed depth are found to be important factors to control the adsorption capacity of DC. The Thomas and Yoon-Nelson models showed a good agreement with the experimental data and could be applied for the prediction of the fixed-bed column properties and breakthrough curves. More importantly, the saturated fixed bed can be easily recycled by H2O2 which shows excellent reusability for the removal of doxycycline. Thus, the combination of the adsorption advantage of chitosan carbon with catalytic properties of magnetic Fe3O4 nanoparticles might provide a new tool for addressing water treatment challenges.

scholarly journals Efficient Absorption of Antibiotic from Aqueous Solutions over MnO2@SA/Mn Beads and Their In Situ Regeneration by Heterogeneous Fenton-Like Reaction

2017 ◽  
Vol 2017 ◽  
pp. 1-13
Author(s):  
Yu Luo ◽  
Bo Bai ◽  
Honglun Wang ◽  
Yourui Suo ◽  
Yiliang Yao
Keyword(s):  
Adsorption Process ◽  
Low Cost ◽  
Physical Structure ◽  
Absorption Efficiency ◽  
Practical Application ◽  
Heterogeneous Fenton ◽  
Adsorptive Removal ◽  
Absorption Kinetic ◽  
Isotherm Equations

Alginate has been extensively used as absorbents due to its excellent properties. However, the practical application of pure alginate has been restricted since the saturated adsorbent has weak physical structure and could not be regenerated easily. In this study, a low-cost and renewable composite MnO2@alginate/Mn adsorbent has been prepared facilely for the absorptive removal of antibiotic wastewater. FE-SEM, FTIR, and XRD analyses were used to characterize the samples. The norfloxacin (NOR) was used as an index of antibiotics. More specifically, the batch absorption efficiency of the adsorbents was evaluated by pH, contact time with different NOR concentration, and the temperature. Thus, the performance of absorption kinetic dynamics and isotherm equations were estimated for the adsorptive removal process. Parameters includingΔG0,ΔH0, andΔS0were utilized to describe the feasible adsorption process. To regenerate the saturated absorptive sites of the adsorbent, the heterogeneous Fenton-like reactions were trigged by introduction of H2O2. The results showed that the in situ regenerating has exhibited an excellent recycling stability. The high activity and the simple fabrication of the adsorbents make them attractive for the treatment of wastewater containing refractory organic compound and also provide fundamental basis and technology for further practical application.

scholarly journals Investigation on the Properties of Sustainable Reactive Powder Concrete by Utilization of Coir Pith Aggregates and Pyrogenic Silica

2021 ◽  
Author(s):  
Oorkalan A ◽  
Chithra S
Keyword(s):  
Silica Fume ◽  
Low Cost ◽  
Autogenous Shrinkage ◽  
Drying Shrinkage ◽  
Particle Packing ◽  
Reactive Powder Concrete ◽  
Fine Aggregate ◽  
Coir Pith ◽  
Pyrogenic Silica ◽  
Reactive Powder

Abstract The present study investigates the properties of RPC developed using low cost eco-friendly materials such as pyrogenic silica (PS) and coir pith (CP) fine aggregates. This study investigates the effects of PS as silica fume replacement which is the main constituent for the production of reactive powder concrete which contained coir pith as a fine aggregate replacement instead of quartz sand up to 25%. The use of silica fume increases the particle packing density of RPC but increases the shrinkage phenomenon in RPC due to the minimum w/b ratio adopted. Therefore, in this research PS is used as a partial substitute for SF up to 30% and its effect on the mechanical and durability properties of coir pith containing RPC is studied. The test results showed that the mechanical strength values decreased with an increase in the addition of CP aggregate beyond 5% whereas the decrement in compressive strength was partially reduced when PS is used as silica fume replacement up to a maximum of 30%. The chloride penetration resistance was also improved with increasing PS substitution in RPC containing CP aggregates. The autogenous shrinkage and drying shrinkage were also significantly reduced due to the internal curing ability of the CP aggregates in combination with PS. The development of dense CSH gels from hydration is also evident from low CaO/ SiO2 ratio obtained from the EDS analysis. Hence the combination of PS with CP aggregates can reduce the shrinkage characteristics of RPC thereby providing eco-friendly sustainable concrete at low cost.

scholarly journals CuAl LDH/Rice Husk Biochar Composite for Enhanced Adsorptive Removal of Cationic Dye from Aqueous Solution

2020 ◽  
Vol 15 (2) ◽  
pp. 525-537 ◽  
Author(s):  
Neza Rahayu Palapa ◽  
Tarmizi Taher ◽  
Bakri Rio Rahayu ◽  
Risfidian Mohadi ◽  
Addy Rachmat ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Surface Area ◽  
Malachite Green ◽  
Rice Husk ◽  
Low Cost ◽  
Bet Surface Area ◽  
Maximum Adsorption Capacity ◽  
Cationic Dye ◽  
X Ray ◽  
Adsorptive Removal

The preparation of CuAl LDH and biochar (BC) composite derived from rice husk and its application as a low-cost adsorbent for enhanced adsorptive removal of malachite green has been studied. The composite was prepared by a one-step coprecipitation method and characterized by X-ray Diffraction (XRD), Fourier Transform Infra Red (FTIR), Brunauer-Emmett-Teller (BET), and Scanning Electron Microscopy - Energy Dispersive X-ray (SEM−EDX). The result indicated that CuAl LDH was successfully incorporated with the biochar that evidenced by the broadening of XRD peak at 2θ = 24° and the appearance of a new peak at 1095 cm−1 on the FTIR spectra. The BET surface area analysis revealed that CuAl/BC composite exhibited a larger surface area (200.9 m2/g) that the original CuAl LDH (46.2 m2/g). Surface morphological changes also confirmed by SEM image, which showed more aggregated particles. The result of the adsorption study indicated the composite material was efficient in removing malachite green with Langmuir maximum adsorption capacity of CuAl/BC reaching 470.96 mg/g, which is higher than the original CuAl LDH 59.523 mg/g. The thermodynamic analysis suggested that the adsorption of malachite green occurs spontaneously (ΔG < 0 at all tested temperature) and endothermic nature. Moreover, the CuAl/BC composite showed strong potential as a low-cost adsorbent for cationic dye removal since it showed not only a high adsorption capacity but also good reusability. Copyright © 2020 BCREC Group. All rights reserved

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