Reaction Process of Chromium Slag Reduced by Industrial Waste in Solid Phase

2007 ◽  
Vol 14 (1) ◽  
pp. 12-15 ◽  
Author(s):  
Yu-min Shi ◽  
Xing-hong Du ◽  
Qing-jia Meng ◽  
Shi-wei Song ◽  
Zhi-tong Sui
2011 ◽  
Vol 402 ◽  
pp. 61-65
Author(s):  
Yu Min Shi ◽  
Tong Wang ◽  
Cheng Hu ◽  
Lin Bai ◽  
Zhi Tong Sui

A particular industrial waste was selected as reducer for detoxified chromium slag in solid phase. Oxidation resisting was also tested. The results showed that concentration of Cr(Ⅵ)in the products was related to experimental condition, such as the proportion of chromium slag, the granularity of reactants, the reaction temperature and time . The leached Cr(Ⅵ)in the products was remained below 0.5 ppm of GB8978-1996 limits.


2021 ◽  
Author(s):  
Pan Zhang ◽  
Yirui Shu ◽  
Yanjun Zhong ◽  
Lin Yang ◽  
Xiushan Yang

Abstract Aiming at devloping novel low cost and high performance catalyst for degradation of methylene blue in industrial waste water. Waste ferrous sulfater which is a industrial waste produced in the process of producing titanium dioxide, CoZnFeO4 is synthesized from waste ferrous sulfate by solid phase method. The experimental results show that CoZnFeO4 has better catalytic performance than other control samplesc: the degradation rate of methylene blue reaches 100% within 8 min, which maintains high catalytic activity after 5 cycles. Zeta potential and ICP-MS tests show that the degradation reaction occurs in the catalyst. The degradation pathway of methylene blue is verified by ESI-MS. These findings provide a low cost and simple strategy for rational design and modulation of catalysts for the industrial degradation of organic pollutants. It not only realizes the use of waste to treat waste, but also accords with the current concept of green chemistry.


RSC Advances ◽  
2015 ◽  
Vol 5 (60) ◽  
pp. 48492-48499 ◽  
Author(s):  
Jing Xu ◽  
Hua Tang ◽  
Yanqiu Chu ◽  
Changsheng Li

MoS2 nanomaterials with different morphologies such as nanoplates, nanowalls, and 3D microspheres composed of ultrathin nanoflakes were synthesized via a simple solid-phase reaction process.


2021 ◽  
Vol 13 (1) ◽  
pp. 135-150
Author(s):  
Vera YURAK ◽  
◽  
Raphail APAKASHEV ◽  
Niyaz VALIEV ◽  
Maxim LEBZIN ◽  
...  

Abstract. The sorbent-based method is one of the key methods for solving the problem of limiting the mobility of pollutants and the effective implementation of reclamation works. Despite the level of knowledge of the problem, the use of the sorbent-based method is of a fragmented experimental nature. Objective: to study the experience of implementing the sorbent-based method for the adsorption of heavy metals in order to determine the most promising compositions of sorbents for further research work on their improvement. Methods: General scientific methods were used, such as dialectical, historical, analysis, synthesis, comparison, grouping, as well as systematic and empirical approaches. Results: The presence of pluralism of definitions in relation to the term “heavy metals”was revealed. The main criterion for attribution is the relative atomic mass of more than 50 g/mol. An additional criterion is the density, which is approximately equal to or greater than the density of iron (rounded 8 g / cm3). There are other classifications that rely on threshold density or atomic mass values. It is proved that the main role of the immobilization of heavy metals is their transfer to new, more geochemical stable phases by sorption, precipitation, and complex formation processes. The widespread use of the sorbent-based method, which solves the problem of converting heavy metals into a sedentary form and difficult-to-dissolve compounds, has been identified. It is revealed that an important process affecting the mobility of heavy metals in the soil is their fixation with humus. It is established that rocks and minerals have pronounced sorption properties. The most common rocks are clays. They are characterized by a significant sorption capacity and a high specific surface area. In order to increase the sorption properties, the materials can be subjected to various modifications. Peat occupies a special place among effective natural sorbents. The development of technologies for the creation and use of new sorbents made from industrial waste is a promising direction. A method of remediation based on the use of ameliorants–stabilizers of heavy metals has been developed: among the mineral elements of the solid phase, fine clay and ferrous minerals are isolated; compost and manure are often used as organic stabilizers. The possibility of rerational use of industrial waste components as meliorants-stabilizers of heavy metals is investigated, and the sediments of water treatment at filtration stations are of interest in this regard. The remediation potential of water treatment sediments can be enhanced by joint application with natural or modified peat.


2016 ◽  
Vol 34 (7-8) ◽  
pp. 439-454 ◽  
Author(s):  
Jagdish Shantilal Patel ◽  
Darshan H Patel ◽  
Rucha Desai ◽  
Sunil Shah ◽  
Piyush Chudasama ◽  
...  

2021 ◽  
Vol 33 (2) ◽  
pp. 350-358
Author(s):  
Eegala Bheema Shankar ◽  
Challa Gangu Naidu ◽  
CH. N.S. Sai Pavan Kumar ◽  
Kasturi Rajashekhar

The present work describes a sensitive, simple, cost-effective and fast analytical procedure to detect the parabens in industrial waste effluent water samples using novel activated carbon nanofiber (CNF) modified filter paper based solid phase extraction technique coupled with liquid chromatography with photodiode array detector (UPLC-PDA). The carbon nanofiber coated filter paper was used as an adsorbent and also characterized by field emission scanning electron microscope (FESEM) showed superior porous structure. Various factors effecting the adsorption and desorption process were studied. The optimum parameters which improve the efficiency are paper length 1 cm × 2 cm, adsorption time 15 min, eluent methanol, eluent volume 5 mL, sample pH 7, desorption time 2 min, 2% salt addition and 300 rpm stirring rate respectively. The parabens exhibited superior linearity ranging from 0.1-50 ng mL-1. The regression coefficient (R2) value ranging from 0.9981-0.9989. This method exhibited good sensitivity with the quantification limit (LOQ) between 0.5-0.75 ng mL-1 and detection limit (LOD) over the range of 0.1-0.25 ng mL-1. The precision was expressed from the RSDs values from 0.74-0.97 %. The spiked analytes revealed excellent recoveries in the range of 95.30-116.72 % with RSD less than 5.72 % for all the water samples also applied for real samples.


2006 ◽  
Vol 45 ◽  
pp. 2229-2234
Author(s):  
G. Costa ◽  
M.J. Ribeiro ◽  
Tito Trindade ◽  
Joao A. Labrincha

The preparation of ceramic pigments using industrial waste, a galvanizing sludge from the Cr/Ni plating process, as primary source is here reported. The ceramic pigments were prepared using the common solid state reaction process, investigating the optimal formulation, milling and firing conditions. The main focus will be given on the synthesis of chrome-tin red malayaite Ca(Cr,Sn)SiO5 pigment that was fully characterised and then tested in a standard ceramic glaze. Typical working conditions and colour development will be also reported.


2020 ◽  
Vol 977 ◽  
pp. 223-228
Author(s):  
Chirakit Chobtham ◽  
Somyote Kongkarat

Aluminium dross is a waste from aluminium melting process, containing approximately 70 wt% of Al2O3. Disposal of dross in landfill causes soil and ground water pollutions, leading to the difficulty of waste management. This work aims to utilize aluminium dross as a source of Al2O3 for the synthesis of hercynite (FeAl2O4). Aluminium dross was heated at 1200°C for 1 hour in air and then compacted into a substrate using a hydraulic press. The substrate was brought into contact with two different types of iron chip at 1550°C in air for 6 hours. Pure iron chip and iron chips containing 0.8 wt% carbon were employed in this experiment in order to investigate the effect of carbon content in the iron chip on the formation of hercynite. The samples after reactions were characterized using XRD, SEM and EDS techniques. It was found that the final product is hercynite having a dark grey solid phase. The formation of hercynite was due to the interaction of Al2O3 in the dross with Fe and/or FeO in the system. FeO came from the oxidization of iron chip due to the excess of oxygen in the system. Carbon content in the iron was found to effect the formation of FeO in the system, which in turn effect the formation of hercynite. This research is one of the possible way to recycling aluminium dross instead of bury in a landfill.


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