Magnetic torque-induced suppression of van-der-Waals-driven thin liquid film rupture

2017 ◽  
Vol 813 ◽  
pp. 991-1006 ◽  
Author(s):  
E. Kirkinis
Keyword(s):  
Gas Phase ◽  
Thin Liquid Film ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
Solid Substrate ◽  
General Effect ◽  
Magnetic Torque ◽  
Film Rupture ◽  
Carrier Liquid ◽  
Collective Rotation

An ultra-thin film of a carrier liquid containing nanosize ferromagnetic particles sitting on a solid substrate and surrounded by an ambient gas phase can be acted upon, apart from viscous and capillary forces, by attractive van der Waals forces which may promote instability leading to film rupture and substrate dewetting. In this article we show that the collective rotation of the particles on the liquid–gas interface, due to a magnetic torque, competes against the instability induced by the van der Waals forces that tend to deepen depressions of the liquid. The competition between the two effects (forcing and instability) leads to the generation of a permanent nonlinear interfacial viscous–capillary wave. Thus, film rupture and substrate dewetting are both averted. This is a general effect that may also be employed to suppress other types of instabilities such as the Rayleigh–Taylor and thermocapillary instabilities. This effect has yet to be observed in experiment.

Droplet profiles under the influence of van der Waals forces

2001 ◽  
Vol 12 (3) ◽  
pp. 367-393 ◽  
Author(s):  
ELIJAHU MINKOV ◽  
AMY NOVICK-COHEN
Keyword(s):  
Cross Section ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
Solid Substrate ◽  
Liquid Droplets ◽  
Leading Order ◽  
Order Of Magnitude ◽  
Uniform Cross Section ◽  
Repulsive Forces ◽  
Parameter Values

We study the effect of van der Waals forces on globally energy minimizing profiles for liquid droplets which lie on a solid substrate in a vapour atmosphere and which are assumed to have a uniform cross-section. We prove that for repulsive van der Waals forces as well as for certain short range repulsive-long range attractive forces, there exists a unique globally minimizing profile. Although this profile necessarily contains vertical bounding segments, the height A of the vertical bounding segments can often be demonstrated to be order of magnitude smaller that the overall height B of the droplet. This is the case, in particular, when the droplet is sufficiently large, the Hamaker constant is sufficiently small, and the attractive forces are sufficiently mild. In the presence of repulsive forces only, A is on the order of angströms when B is on the order of millimeters, for realistic parameter values. Moreover, conditions are prescribed under which Young's law is satisfied to leading order despite the appearance of the vertical segments, when the contact angle is measured via an inscribed circle construction at a distance ξ0 from the edge of the droplet, where A [Lt ] ξ0 [Lt ] B.

Healing of thermocapillary film rupture by viscous heating

2019 ◽  
Vol 872 ◽  
pp. 308-326 ◽  
Author(s):  
E. Kirkinis ◽  
A. V. Andreev
Keyword(s):  
Surface Tension ◽  
Gas Phase ◽  
Liquid Films ◽  
Solid Substrate ◽  
Viscous Heating ◽  
Shear Stresses ◽  
Heating Effect ◽  
Film Rupture ◽  
Surface Shear ◽  
Ambient Gas

Thin liquid films sitting on a heated solid substrate and surrounded by a colder ambient gas phase are strongly affected by surface-shear stresses induced by surface tension and temperature gradients, as well as by viscous and capillary forces. The temperature dependence of surface tension may lead to thinning of liquid-film depressions promoting instability which takes place when a critical temperature difference $\unicode[STIX]{x0394}\unicode[STIX]{x1D717}_{cr}$ between the substrate and the ambient gas phase is exceeded. In this article we show theoretically that viscous heating, previously neglected in related literature, may delay or suppress the thermocapillary instability and leads to film healing. The viscous heating effect, by inhibiting heat transfer, prevents the system from reaching the critical value $\unicode[STIX]{x0394}\unicode[STIX]{x1D717}_{cr}$ required to bring about instability. As a consequence, the system remains within the stability region, suppressing film rupture. The presence of the viscous heating effect leads to a persistent circulating motion of two counter-rotating vortices lying diametrically opposite to a depression of the liquid–gas interface reducing the wavelength of disturbances to one half of its initial value. This effect has yet to be observed in experiment.

Self-Assembly of a Chiral Cubic Three-Connected Net from the High Symmetry Molecules C60 and SnI4

2020 ◽  
Author(s):  
Daniel B. Straus ◽  
Robert J. Cava
Keyword(s):  
Organic Synthesis ◽  
Self Assembly ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
High Symmetry ◽  
Molecular Chirality ◽  
Chiral Materials ◽  
Self Assembled ◽  
Chiral Centers

The design of new chiral materials usually requires stereoselective organic synthesis to create molecules with chiral centers. Less commonly, achiral molecules can self-assemble into chiral materials, despite the absence of intrinsic molecular chirality. Here, we demonstrate the assembly of high-symmetry molecules into a chiral van der Waals structure by synthesizing crystals of C<sub>60</sub>(SnI<sub>4</sub>)<sub>2</sub> from icosahedral buckminsterfullerene (C<sub>60</sub>) and tetrahedral SnI4 molecules through spontaneous self-assembly. The SnI<sub>4</sub> tetrahedra template the Sn atoms into a chiral cubic three-connected net of the SrSi<sub>2</sub> type that is held together by van der Waals forces. Our results represent the remarkable emergence of a self-assembled chiral material from two of the most highly symmetric molecules, demonstrating that almost any molecular, nanocrystalline, or engineered precursor can be considered when designing chiral assemblies.

scholarly journals Nanotube‐Based 1D Heterostructures Coupled by van der Waals Forces

Small ◽  
2021 ◽  
pp. 2102585
Author(s):  
Sofie Cambré ◽  
Ming Liu ◽  
Dmitry Levshov ◽  
Keigo Otsuka ◽  
Shigeo Maruyama ◽  
...  
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Forces

scholarly journals Tuning adlayer-substrate interactions of graphene/h-BN heterostructures on Cu(111)–Ni and Ni(111)–Cu surface alloys

RSC Advances ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1916-1927
Author(s):  
Jianmei Huang ◽  
Qiang Wang ◽  
Pengfei Liu ◽  
Guang-hui Chen ◽  
Yanhui Yang
Keyword(s):  
Long Range ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
Alloy Surface ◽  
Surface Alloys ◽  
Substrate Interactions

The evolution of the interface and interaction of h-BN and graphene/h-BN (Gr/h-BN) on Cu(111)–Ni and Ni(111)–Cu surface alloys versus the Ni/Cu atomic percentage on the alloy surface were comparatively studied by DFT-D2, including critical long-range van der Waals forces.

Condensation energies for metals on glass and other substrates

1959 ◽  
Vol 252 (1270) ◽  
pp. 418-430 ◽  
Keyword(s):  
Sodium Chloride ◽  
Single Crystal ◽  
Physical Adsorption ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
Potassium Bromide ◽  
Binding Energies ◽  
Adhesive Energy ◽  
Good Agreement

Earlier work on condensation phenomena is briefly reviewed, and existing measurements of condensation energies are summarized. Measurements of condensation energies have been made for aluminium, silver and cadmium on glass and for aluminium and silver on single-crystal cleavage surfaces of sodium chloride and potassium bromide. Adhesive energies or binding energies between film and substrate have been calculated in each case. Association energies for nucleation are obtained by difference and shown to be consistent. Results for cadmium show good agreement with earlier work, but results for aluminium do not agree with the earlier results of Rhodin who measured the condensation energies for aluminium on various substrates, obtaining values which suggest chemisorption. These results appear to be too high and a possible explanation is given. It is concluded that the adhesive energy is due to physical adsorption and can be explained in terms of van der Waals forces only.

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