Half-Life Determination of 41Ca and Some Other Radioisotopes

Radiocarbon ◽  
1992 ◽  
Vol 34 (3) ◽  
pp. 436-446 ◽  
Author(s):  
Walter Kutschera ◽  
Irshad Ahmad ◽  
Michael Paul

We have performed a new determination of the half-life of 41Ca by measuring the specific activity of an enriched Ca material with known 41Ca abundance. We measured the activity via the 3.3-keV X-rays emitted in the electron capture decay of 41Ca, and the 41Ca abundance was measured by low-energy mass spectrometry. The result, t1/2 = (1.01 ± 0.10) × 105 yr, agrees with the recent ‘geological’ half-life of Klein et al., (1991), t1/2 = (1.03 ± 0.07) × 105 yr, and with the corrected value of Mabuchi et al. (1974), t1/2 = (1.13 ± 0.12) × 105 yr. We recommend the weighted mean of these three measurements, t1/2 = (1.04 ± 0.05) × 105 yr, as the most probable half-life of 41Ca. We also discuss the situation of the radioisotopes, 32Si, 44Ti, 79Se and 126Sn, whose half-lives, though still uncertain, are potentially interesting for future AMS studies and other applications.

1972 ◽  
Vol 55 (1) ◽  
pp. 85-92 ◽  
Author(s):  
David Firestone ◽  
John Ress ◽  
N L Brown ◽  
R P Barron ◽  
J N Damico

Abstract Twenty-one commercial chlorophenols were examined for the presence of polychlorodibenzo- p-dioxins (chlorodioxins) and related compounds. The chlorophenols were dissolved in aqueous alkali, extracted with petroleum ether, and fractionated on an alumina column. Alumina fractions were examined by electron capture gas chromatography and combined gas chromatography-mass spectrometry. Chlorodioxin content was estimated by electron capture gas chromatography. The presence of chlorodioxins, polychlorodibenzofurans (chlorofurans), and polychlorodiphenyl ethers (chloroethers) was confirmed by combined gas chromatography-mass spectrometry. The 2,3,-7,8-tetrachlorodioxin was found in 3 of 6 samples of 2,4,5-trichlorophenol but was not detected in any of the 11 samples of tetra- and pentachlorophenol that were examined. Hexachlorodioxin was present at levels ranging from 0.17 to 39 ppm in all 8 pentachlorophenols examined. Hexa-, hepta-, and octachlorodioxins as well as a wide variety of chlorofurans and chloroethers of varying chlorine content were present in most of the tetra- and pentachlorophenols. In addition, the gas chromatographic- mass spectrometric data suggested that some of the chlorophenols contained methoxy- and dimethoxypolychlorofurans and methoxypolychloroethers as well as polychlorohy droxybiphenyl.


1973 ◽  
Vol 12 (66) ◽  
pp. 411-416 ◽  
Author(s):  
Henrik B. Clausen

32Si dating of glacier ice has hitherto been complicated by the poor knowledge of the half life. Furthermore, fall-out of bomb-produced 32Si impedes the determination of the specific activity of cosmic-ray produced 32Si in recent precipitation. Measurements on well-dated pre-bomb samples from the Greenland ice sheet establish a calibration for 32Si dating of up to 1 000 year old polar ice samples of the magnitude of 1 metric ton. If the technique is used on temperate glaciers, samples of pre-bomb deposits (or from after 1970) must be collected for comparison with samples of old ice, using an apparent half life of 295±25 years. Due to secular cosmic-ray flux variations, the true half life of 32Si is estimated at the slightly higher value of 330±40 years.


Atomic Energy ◽  
1960 ◽  
Vol 6 (1) ◽  
pp. 41-41
Author(s):  
Ya. P. Dokuchaev ◽  
I. S. Osipov
Keyword(s):  

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