scholarly journals On the Star Formation in Early Stage of Galactic Evolution

1981 ◽  
Vol 93 ◽  
pp. 68-69
Author(s):  
Y. Yoshii ◽  
Y. Sabano

Evolution and fragmentation of a gas cloud are investigated for the primordial chemical composition which is the same as the products of the Big Bang. A pure-hydrogen gas cloud collapses isothermally at 500–1000 K when a low fraction of molecular hydrogen works as a coolant, and breaks into small subcondensations with mass less than 10 M⊙ due to thermal instability associated with molecular dissociation. On the other hand a pure-hydrogen gas cloud which contains no molecular hydrogen collapses isothermally at 6000–8000 K in a thermally stable condition, and enters the region where thermal energy exceeds radiation energy when thermal equilibrium between matter and radiation is achieved in the cloud. Consideration of energetics in the subsequent stage of the cloud evolution leads to the mass range of 0.1–20 M⊙ for the stable nuclear-burning protostars of the first generation. The thermal behavior of a gas cloud in the regime of z (the ratio of heavy element abundance to solar one) less than 10−4 is essentially similar to that in the case of no heavy element, and the heavy element cooling brings about thermal instability in a wide range of parameters in the regime of z greater than 10−3. Linear perturbation analysis gives growth time of the instability much shorter than the free-fall time, and suggests the efficient excitation of density fluctuation driven by thermal instability. Thus the possibility of the initial mass function relatively enhanced in massive star at early times is denied, and the slow rate of metal enrichment in the interstellar medium is suggested.

1996 ◽  
Vol 152 ◽  
pp. 217-222
Author(s):  
Jean Dupuis ◽  
Stéphane Vennes

We present an analysis of the extreme ultraviolet (EUV) spectroscopy of a sample of 10 DA white dwarfs observed by the Extreme Ultraviolet Explorer (EUVE). We have selected white dwarfs cooler than about 50,000 K and with presumably low heavy element abundances. The goal of this study is to determine the fundamental atmospheric parameters, namely the effective temperature and chemical composition, of these stars by fitting their continua with synthetic spectra computed from pure hydrogen LTE/line-blanketed model atmospheres. The question of the presence (or absence) of trace elements is explored by comparing EUV-determined effective temperatures to the one obtained from a fit of hydrogen balmer lines. It is found that the majority of the DA in the sample are consistent with having a pure hydrogen atmosphere. One of the star, MCT0027-634, is another possible example of a HZ 43-type white dwarf, having an effective temperature above 50000 K and a low heavy element abundance, i.e., much lower than predicted by diffusion theory.


1982 ◽  
Vol 4 (4) ◽  
pp. 396-400 ◽  
Author(s):  
J. Lattanzio

Duley (1974) has shown that, at the temperatures usually associated with interstellar gas clouds, we would expect CNO grains to be present. During gravitational collapse these grains migrate to the centre of the gas cloud, leading to an enhancement of the heavy-element abundance in the core (Prentice 1976, 1978). It was Krautschneider (1977) who verified such a scenario, by considering the dynamical collapse of gas and grain clouds. If such an initial radial abundance inhomogeneity existed, Prentice (1976a) showed that this configuration may well survive the later convective mixing phase and thus approach the zero-age main-sequence (ZAMS) with a small (-v 3% by mass) metal enhanced core.


Author(s):  
Mohammad Arif Khan ◽  
Yitung Chen ◽  
Robert Boehm ◽  
Sean Hsieh

A process analysis and simulation model has been developed in the framework of the process simulator ASPEN PLUSTM in order to produce solar thermo-chemical hydrogen. Hydrogen is an environmentally attractive transportation fuel that has the potential to replace fossil fuels. Chemical mass balance, conversion rate, operating temperature and pressure are comparatively assessed for a wide range of hydrogen production processes, including processes which are hydrocarbon based (methane cracking and steam methane reforming), non-hydrocarbon based (water electrolysis) and integrated process (combined hydrocarbon and non-hydrocarbon based processes). The process analysis and simulation also provide a quantitative tool for insight and understanding the process. The project collaborators among General Atomics, NREL, SNL, UCB and UNLV have done the selection screening from all available thermochemical processes. Then a process analysis and simulation model by using ASPEN PLUS has been built up with the help of detailed reactions, additional data, reactor dimensions, rate laws, parameter values and specific reaction rate and equilibrium constants to find an economically feasible and environmentally suitable process to generate pure hydrogen gas which can be used in fuel cell and automobiles.


Author(s):  
Francis Bainier ◽  
Rainer Kurz

Abstract Gas Transport System Operators (TSO1) are considering injecting hydrogen gas in their networks. Blending hydrogen into the existing natural gas pipeline network appears to be a strategy for storing and delivering renewable energy to markets [1], [2],[3]. In comparison to methane, hydrogen gas (dihydrogen or molecular hydrogen) has a higher mass calorific value than methane gas. Because of this property, molecular hydrogen is appreciated for space shuttle engines. A second property is that hydrogen gas has a lower mass density than methane gas. The result of the second property is that the volume calorific value is in favor of methane gas. The list of differences between methane and hydrogen is long. In the relevant range of pressures and temperatures, the Joule-Thomson coefficient has a different sign for hydrogen and methane, and the compressibility factor has the opposite trend when the gas is compressed. The dynamic viscosity is also significantly different, and finally, heat capacity, isentropic exponent, and the thermal conductivity are also different. What are the impacts of these hydrogen characteristics on the transport capacity and its efficiency in the case of blending in a gas transport network? The first part of the paper is a review of the differences in characteristics between Hydrogen Gas and a Typical Natural Gas in Europe and their impact on the gas flow performance in a pipeline network equipped with compressors. The second part of the paper is dedicated to pipe segments. And in the third part, compressor stations are introduced between each pipe segment. At each step, an analysis of a mixed gas from one hundred per cent pure natural gas to one hundred per cent pure hydrogen is done. The paper provides some results for 10 %, 40 %, and 100 % of hydrogen blending in an international pipeline. The study shows that the energy quantity transported at the same pressure ratio is reduced respectively by 4 %, 14 %, and 15 to 20 %, and energy requirement for compression increases respectively by 7 %, 30 %, and 210 % (i.e. it more than triples). To transport the same quantity of energy in a network, assuming the resizing to the same level of optimizations, the energy requirement increases by 11 %, 52 %, and 280 %. In other words, it takes 4 times the energy to transport a given amount of energy if the gas is pure hydrogen than it takes if the gas is pure natural gas. The paper does not address the issue of equipment or material, it only compares the influence of hydrogen gas on the network capacity and the transport efficiency. This paper doesn’t take into account the limits of the equipment. All equipment is considered as compatible with any load of hydrogen blending.


Author(s):  
Volodymyr Moseichuk ◽  
Vladyslav Moseichuk ◽  
Vasyl Makolinets

Molecular hydrogen is one of the effective antioxidants, which not only does not disrupt normal metabolism in the body, but also activates its antioxidant systems. Hydrogen-saturated water has  antioxidant, anti-inflammatory, anti-allergic, anti-apoptotic properties, stimulates energy metabolism and contributes to the systemic recovery of the body. It is used as a therapeutic factor for the treatment of patients with various pathologies: arterial hypertension, coronary heart disease, diabetes, obesity, metabolic disorders, disorders of the musculoskeletal system. The article discusses the various methods of obtaining molecular hydrogen and hydrogen water (direct and indirect saturation). Technical characteristics are described and features of the hydrogen generator GVCh Life (manufacturer LTD «Chemtest Ukraine+», Kharkiv, Ukraine), which produces molecular hydrogen (purity of which is 99.99 %, productivity — 100 ml/min) and saturates water with it (https://chemtest.com.ua/generator_vodorodnoy_vodi_i_dihanie_gvch_life). In contrast to the problems of most known generators in the device GVChLife is completely no contact of the electrodes with water, so it is not subject to electrolysis and is not saturated with metal ions. Water saturated in this way has the following characteristics: redox potential 560 mV, hydrogen concentration 1.0–1.15 ppm(water volume 1 l, saturation duration 10 min). The generator can be used for both hydrogen saturation and hydrogen inhalation. In the case of therapeutic use of hydrogen water to obtain it, you can use any drinking water (spring, prepared or non-carbonated bottled), hydrogen inhalation using nasal cannulas. Inhalation of pure hydrogen gas (99.99 %) for 30 minutes is equal to the use of 15 liters of hydrogen water (concentration 1.1–1.2 ppm). Conclusions. The developed MoHC Life molecular hydrogen generator is safe to use, without special requirements during operation. It can be successfully used in the complex therapy of patients with various diseases, including musculoskeletal system.


RSC Advances ◽  
2014 ◽  
Vol 4 (36) ◽  
pp. 18512 ◽  
Author(s):  
Pratanu Nag ◽  
Sanhita Majumdar ◽  
Ali Bumajdad ◽  
Parukuttyamma Sujatha Devi

From the fact that no carbonic acid gas is given out by venous blood when that fluid is subjected to the action of the air-pump, former experimentalists had inferred that this blood contains no carbonic acid. The author of the present paper contends that this is an erroneous inference; first, by showing that serum, which had been made to absorb a considerable quantity of this gas, does not yield it upon the removal of the atmospheric pressure; and next, by adducing several experiments in proof of the strong attraction exerted on carbonic acid both by hydrogen and by oxygen gases, which were found to absorb it readily through the medium of moistened membrane. By means of a peculiar apparatus, consisting of a double-necked bottle, to which a set of bent tubes were adapted, he ascertained that venous blood, agitated with pure hydrogen gas, and allowed to remain for an hour in contact with it, imparts to that gas a considerable quantity of carbonic acid. The same result had, indeed, been obtained, in a former experiment, by the simple application of heat to venous blood confined under hydrogen gas; but on account of the possible chemical agency of heat, the inference drawn from that experiment is less conclusive than from experiments in which the air-pump alone is employed. The author found that, in like manner, atmospheric air, by remaining, for a sufficient time, in contact with venous blood, on the application of the air-pump, acquires carbonic acid. The hypothesis that the carbon of the blood attracts the oxygen of the air into the fluid, and there combines with it, and that the carbonic acid thus formed is afterwards exhaled, appears to be inconsistent with the fact that all acids, and carbonic acid more especially, impart to the blood a black colour; whereas the immediate effect of exposing venous blood to atmospheric air, or to oxygen gas, is a change of colour from a dark to a bright scarlet, implying its conversion from the venous to the arterial character: hence the author infers that the acid is not formed during the experiment in question, but already exists in the venous blood, and is extracted from it by the atmospheric air. Similar experiments made with oxygen gas, in place of atmospheric air, were attended with the like results, but in a more striking degree and tend therefore to corroborate the views entertained by the author of the theory of respiration. According to these views, it is neither in the lungs, nor generally in the course of the circulation, but only during its passage through the capillary system of vessels, that the blood undergoes the change from arterial to venous; a change consisting in the formation of carbonic acid, by the addition of particles of carbon derived from the solid textures of the body, and which had combined with the oxygen supplied by the arterial blood: and it is by this combination that heat is evolved, as well as a dark colour imparted to the blood. The author ascribes, however, the bright red colour of arterial blood, not to the action of oxygen, which is of itself completely inert as a colouring agent, but to that of the saline ingredients naturally contained in healthy blood. On arriving at the lungs, the first change induced on the blood is effected by the oxygen of the atmospheric air, and consists in the removal of the carbonic acid, which had been the source of the dark colour of the venous blood; and the second consists in the attraction by the blood of a portion of oxygen, which it absorbs from the air, and which takes the place of the carbonic acid. The peculiar texture of the lungs, and the elevation of temperature in warm-blooded animals, concur in promoting the rapid production of these changes.


Atoms ◽  
2019 ◽  
Vol 7 (3) ◽  
pp. 63 ◽  
Author(s):  
Christian G. Parigger ◽  
Christopher M. Helstern ◽  
Ghaneshwar Gautam

This work discusses laboratory measurements of atomic and diatomic molecular species in laser-plasma generated in gases. Noticeable self-absorption of the Balmer series hydrogen alpha line occurs for electron densities of the order of one tenth of standard ambient temperature and pressure density. Emission spectra of selected diatomic molecules in air or specific gaseous mixtures at or near atmospheric pressure reveal minimal plasma re-absorption. Abel inversion of the plasma in selected gases and gas mixtures confirm expansion dynamics that unravel regions of atomic and molecular species of different electron temperature and density. Time resolved spectroscopy diagnoses self-absorption of hydrogen alpha and hydrogen beta lines in ultra-high pure hydrogen gas. Radiation from a Nd:YAG laser device induces micro-plasma for pulse widths in the range of 6–14 ns, energies in the range of 100–800 mJ, and peak irradiances of the order 1–10 TW/cm 2 . Atomic line profiles yield electron density and temperature from fitting of line profiles to wavelength and sensitivity corrected spectral radiance data. Analysis of measured diatomic emission data yields excitation temperature of primarily molecular recombination spectra. Applications of the laboratory experiments extend to investigations of stellar astrophysics white dwarf spectra.


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