Water contents of felsic melts: application to the rheological properties of granitic magmas

1996 ◽  
Vol 87 (1-2) ◽  
pp. 57-64 ◽  
Author(s):  
F. Holtz ◽  
B. Scaillet ◽  
H. Behrens ◽  
F. Schulze ◽  
M. Pichavant
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Water Solubility ◽  
Constant Pressure ◽  
Crustal Material ◽  
Crystal Fraction ◽  
Melt Water ◽  
Water Contents ◽  
Magma Viscosity

ABSTRACT:New experimental determinations of water solubility in haplogranitic melts (anhydrous compositions in the system Qz-Ab-Or and binary joins) and of the viscosity of hydrous Qz28Ab38Or34 melts (normative proportions) and natural peraluminous leucogranitic melt (Gangotri, High Himalaya) are used to constrain the evolution of viscosity of ascending magmas, depending on their P-T paths.At constant pressure, in the case of fluid-absent melting conditions, with water as the main volatile dissolved in the melts, the viscosity of melts generated from quartzo-feldspathic protoliths is lower at low temperature than at, high temperature (difference of 1-2 log units between 700 and 900°C). This is due to the higher water contents of the melts at low temperature than at high temperature and to the fact that decreasing temperature does not counterbalance the effect of increasing melt water content. In ascending magmas generated from crustal material the magma viscosity does not change significantly whatever the P-T path followed (i.e. path with cooling and crystallisation; adiabatic path with decompression melting) as long as the crystal fraction is low enough to assume a Newtonian behaviour (30-50% crystals, depending on size and shape). Comparison of the properties of natural and synthetic systems suggests that both water solubility and the viscosity of multicomponent natural felsic melts (with less than 30-35% normative Qz) can be extrapolated from those of the equivalent synthetic feldspar melts.

scholarly journals Evaluation of Micro-Mechanism and High- and Low-Temperature Rheological Properties of Disintegrated High Volume Crumb Rubber Asphalt (DHVRA)

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1145
Author(s):  
Wei Li ◽  
Sen Han ◽  
Xiaokang Fu ◽  
Ke Huang
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Particle Diameter ◽  
Gel Permeation Chromatography ◽  
High Volume ◽  
Crumb Rubber ◽  
Test Method ◽  
Polar Component ◽  
Temperature Performance

The aims of this paper are to prepare disintegrated high volume crumb rubber asphalt (DHVRA) with low viscosity, good workability and low-temperature performance by adding disintegrating agent (DA) in the preparation process, and to further analyze the disintegrating mechanism and evaluated high-temperature and low-temperature rheological properties. To obtain DHVRA with excellent comprehensive performance, the optimum DA dosage was determined. Based on long-term disintegrating tests and the Fluorescence Microscopy (FM) method, the correlations between key indexes and crumb rubber (CR) particle diameter was analyzed, and the evaluation indicator and disintegrating stage division standard were put forward. Furthermore, Fourier transform infrared spectroscopy (FT-IR) and Gel Permeation Chromatography (GPC) was used to reveal the reaction mechanism, and the contact angle test method was adopted to evaluate the surface free energy (SFE). In addition, the high-temperature and low-temperature rheological properties were measured, and the optimum CR content was proposed. Results indicated that the optimum DA dosage was 7.5‰, and the addition of DA promoted the melt decomposition of CR, reduced the viscosity and improved the storage stability. The 135 °C rotational viscosity (RV) of DHVRA from mixing for 3 h could be reduced to 1.475 Pa·s, and the softening point difference was even less than 2 °C. The linear correlation between 135 °C RV and the diameter of CR particle in rubber asphalt system was as high as 0.968, and the viscosity decay rate (VDR) was used as the standard to divide the disintegrating process into a fast disintegrating stage, stable disintegrating stage and slight disintegrating stage. Compared to common rubber asphalt (CRA), DHVRA has an absorption peak at 960 cm−1 caused by trans olefin = C-H, and higher molecular weight and polar component of surface energy. Compared with CRA, although the high-temperature performance of DHVRA decreases slightly, the low-temperature relaxation ability can be greatly improved.

Nanoemulsion with Controlled Rheology under Different Temperature for Effective Removal of Oil-based Drilling Fluid in Offshore Drilling

2021 ◽  
Author(s):  
Renzhou Meng ◽  
Chengwen Wang ◽  
Xiliang Dong ◽  
Chao Xiong
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Drilling Fluid ◽  
Offshore Drilling ◽  
Emulsion Droplets ◽  
Effective Removal ◽  
Engineering Requirement ◽  
Important Means ◽  
The Stability

Abstract Oil-based drilling fluid (OBDF) is an important means for offshore drilling, but it would affect the cementing quality. Nanoemulsions shows potential for OBDF removal, but how to prepare nanoemulsion meeting the engineering requirement is lack of good understanding. Moreover, nanoemulsions usually behave badly under low/high temperature, which would restrict the application. Revealing removal mechanisms of nanoemulsion and improving nanoemulsion stability at different temperature are of great significance. The nanoemulsion could rapidly spread on the wellbore surfaces, cause the adhering OBDF to curl into little droplets, and solubilize the removed OBDF. The removal efficiency can reach more than 98%. Low temperature and higher concentration of dispersed phase both increased the viscosity of nanoemulsions stabilized by surfactants. PEGs can induce the bridging of emulsion droplets at low temperature, leading to significant increase of nanoemulsions viscoelasticity at low temperature (around 5°C). To control the rheological properties of nanoemulsions, a hydrophobic association polymer, HAAP, was proposed. Nanoemulsions containing HAAP does not gel at low temperature (< 15°C). And the viscoelasticity of nanoemulsions increased slightly when the temperature is higher than 70°C because of the thermoassociating behavior of polymer, which can ensure the stability of the nanoemulsions at high temperature. This paper is helpful to establish a generic route for preparing nanoemulsions with controlled rheological properties under different temperature, which is benefit for their applications in offshore.

Impact of Rheological Properties of Fiber Asphalt Mortar on Mixture Road Performance

2013 ◽  
Vol 734-737 ◽  
pp. 2287-2291 ◽  
Author(s):  
De Dong Guo
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Asphalt Mixture ◽  
Temperature Stability ◽  
Fiber Content ◽  
High Temperature Stability ◽  
Temperature Performance ◽  
Low Temperature Performance ◽  
Asphalt Mortar

Fiber asphalt concrete has been more and more widely used in highway construction. For analyzing high and low temperature performance of fiber asphalt mixture, rheological properties of fiber asphalt mortar were studied through indoor test. Impact of Rheological properties of the fiber asphalt mortar on high temperature and low temperature properties of asphalt mixture was analyzed. Results showed that the larger fiber content was, the better performance of asphalt mixture's high temperature stability, fiber asphalt mortar rut factor and rutting tests results of asphalt mixture were linear correlation, reflecting the high temperature performance of asphalt mixture; With the increase of fiber content, variation of stiffness modulus, creep rate indicators and mixture low temperature performance was consistent, and rheological properties of fiber asphalt mortar could characterize low temperature performance of asphalt mixture.

scholarly journals Effect of Recycled Shell Waste as a Modifier on the High- and Low-Temperature Rheological Properties of Asphalt

2021 ◽  
Vol 13 (18) ◽  
pp. 10271
Author(s):  
Yuchen Guo ◽  
Xuancang Wang ◽  
Guanyu Ji ◽  
Yi Zhang ◽  
Hao Su ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Low Temperatures ◽  
High Speed ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Temperature Performance

The deteriorating ecological environment and the concept of sustainable development have highlighted the importance of waste reuse. This article investigates the performance changes resulting from the incorporation of shellac into asphalt binders. Seashell powder-modified asphalt was prepared with 5%, 10%, and 15% admixture using the high-speed shear method. The microstructure of the seashell powder was observed by scanning electron microscope test (SEM); the physical-phase analysis of the seashell powder was carried out using an X-ray diffraction (XRD) test; the surface characteristics and pore structure of shellac were analyzed by the specific surface area Brunauer-Emmett-Teller (BET) test; and Fourier infrared spectroscopy (FTIR) qualitatively analyzed the composition and changes of functional groups of seashell powder-modified asphalt. The conventional performance index of seashell powder asphalt was analyzed by penetration, softening point, and ductility (5 °C) tests; the effect of seashell powder on asphalt binder was studied using a dynamic shear rheometer (DSR) and bending beam rheometer (BBR) at high and low temperatures, respectively. The results indicate the following: seashell powder is a coarse, porous, and angular CaCO3 bio-material; seashell powder and the asphalt binder represent a stable physical mixture of modified properties; seashell powder improves the consistency, hardness, and high-temperature performance of the asphalt binder but weakens the low-temperature performance of it; seashell powder enhances the elasticity, recovery performance, and permanent deformation resistance of asphalt binders and improves high-temperature rheological properties; finally, seashell powder has a minimal effect on the crack resistance of asphalt binders at very low temperatures. In summary, the use of waste seashells for recycling as bio-modifiers for asphalt binders is a practical approach.

Effect of Ageing on Rheological Properties of Asphalt

2021 ◽  
Vol 891 ◽  
pp. 185-189
Author(s):  
Li Xing Ma
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Complex Modulus ◽  
Dynamic Shear ◽  
Dynamic Shear Rheometer ◽  
Field Behavior ◽  
Aged Asphalt ◽  
Actual Field

This paper is to study the mechanism of aging on the rheological properties of the asphalt and make correlations with the actual field behavior of the binder. The effects of ageing on rheological properties of asphalt has been studied by Dynamic Shear Rheometer(DSR). Significant differences of rheological properties and composition were observed between fresh and aged asphalt. The results show that aging at low temperature increases the complex modulus of asphalt, but has little effect at high temperature.

scholarly journals Research on Rheological Properties of High-Percentage Artificial RAP Binder with WMA Additives

2020 ◽  
Vol 2020 ◽  
pp. 1-24
Author(s):  
Weiying Wang ◽  
Songchang Huang ◽  
Yongchun Qin ◽  
Yiren Sun ◽  
Rui Dong ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Asphalt Binder ◽  
Creep Recovery ◽  
Recycled Asphalt ◽  
Reclaimed Asphalt ◽  
Temperature Performance ◽  
Huge Impact ◽  
Polyethylene Wax

With the development of pavement recycling technology, the requirement of reclaimed asphalt pavement (RAP) is substantially increasing. Warm-mix recycled asphalt (WMRA) technology has made great progress, which can effectively decrease the working temperature and improve the RAP content. In this study, the rheological properties of recycled binders with incorporation of high-percentage artificial RAP binder (30–70%) were evaluated using two types of warm-mix asphalt (WMA) additives, i.e., polyethylene wax R and surfactant M. The dynamic shear rheometer (DSR) and beam bending rheometer (BBR) tests were conducted on the recycled binders. The results showed that the temperature and frequency played an important role in determining the complex shear modulus of the high-percentage WMRA binders. The dependency of phase angle on frequency increased after the long-term aging. The WMA additive R had a relatively huge impact on the rheological properties of asphalt, which mainly occurred before the PAV aging of recycled asphalt binder; the WMA additive M had no significant impact on the rheological properties of recycled asphalt binder. The WMA additive R enhanced the low-temperature rheology of recycled asphalt binder, while the WMA additive M enhanced the high-temperature rheology of recycled asphalt binder. Both of these types of WMA additives improved the antifatigue performance of recycled asphalt binder. The increased content of RAP binder improved the high-temperature performance and reduced the low-temperature performance of the recycled asphalt binder. However, it had no obvious impact on the fatigue performance. In addition, there was a good linear relation between the RAP binder content and the two indexes of the multiple stress creep recovery (MSCR) test.

scholarly journals Properties and Components of Recycled Engine Oil Bottom Rejuvenated Asphalt and Its Grey Relationship Analysis

2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
Jin Li ◽  
Miaozhang Yu ◽  
Xinzhuang Cui ◽  
Wentong Wang
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Engine Oil ◽  
Relationship Analysis ◽  
Temperature Performance ◽  
Asphaltene Content ◽  
Aged Asphalt ◽  
Optimum Type ◽  
Low Temperature Flexibility

Numerous environmental pollution and resource waste problems are associated with recycled engine oil bottom (REOB), which cannot be effectively recycled. Based on the similarity compatibility theory and component adjustment theory, comparing the physical and rheological properties of laboratory-aged asphalt under three types of REOB (defined as REOB-1, REOB-2, and REOB-3) with different dosages, the optimum type and dosage of REOB as asphalt regenerant were explored. The rejuvenation mechanism of REOB on aged asphalt was revealed by combined performance, four-component, and infrared spectroscopy analyses. The relationship between the four components and physical rheological indexes in the process of asphalt rejuvenated by REOB was quantitatively obtained by the grey relationship analysis. The results show that only REOB-3 with a dosage of 7% on the aged asphalt has the best comprehensive rejuvenation effect. Also, the high-temperature rutting resistance of rejuvenated asphalt with 7% REOB-3 is better than that of the original asphalt, but the low-temperature flexibility and the crack resistance performance have yet to be improved. The mechanism through which REOB rejuvenates aged asphalt is an incomplete component adjustment; some of the components undergo physical or chemical reactions and transformations. Accordingly, the asphaltene content and the intensity of sulfoxide functional groups in aged asphalt decrease, thereby achieving rejuvenation gradually with the addition of REOB. A grey relationship analysis demonstrates that asphaltenes have the greatest influence on high-temperature performance and that low-temperature performance requires a reasonable combination of four components. Moreover, a comprehensive advantage analysis reveals that REOB is the most sensitive to the softening point and that the asphaltene content has the greatest influence on the physical and rheological properties of REOB-rejuvenated asphalt. Therefore, the asphaltene content should be strictly controlled during the addition of REOB to rejuvenate aged asphalt.

scholarly journals Rheological Properties of SBS/CRP Composite Modified Asphalt under Different Aging Treatments

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4921
Author(s):  
Shuhua Wu ◽  
Rui He ◽  
Huaxin Chen ◽  
Wenke Li ◽  
Guanghui Li
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Deformation Resistance ◽  
High Temperature Deformation ◽  
Temperature Deformation ◽  
Cold Regions ◽  
Modified Asphalt ◽  
Frequency Sensitivity ◽  
Aging Conditions

The objective of this study is to evaluate the rheological properties of SBS/CRP composite modified asphalt under different aging conditions in alpine cold regions. In this study, the styrene-butadiene-styrene (SBS) block copolymer, crumb rubber powder (CRP), softeners and various additives were used to prepare the SBS/CRP composite modified asphalt. The 4.5% SBS modified asphalt and SK90 virgin asphalt were also selected for comparing. The thin film oven test (TFOT) and pressure aging vessel (PAV) aging test were conducted to simulate the different aging conditions. The frequency sensitivity, high-temperature deformation resistance and low-temperature crack resistance of SBS/CRP composite modified asphalt under different aging conditions were studied by the dynamic shear rheometer (DSR) and bending beam rheometer (BBR) test. The results show that the frequency sensitivity of SBS/CRP composite modified asphalt is the lowest. At low and medium temperatures, it has relatively low strength and good flexibility. The master curve of composite modulus for the unaged and aged SBS/CRP composite modified asphalt is in a cluster state. It has strong anti-aging capability, which is less affected by aging conditions. It also has a strong low-temperature relaxation ability, which can meet the requirements of performance at −24 °C in PG classification. The high-temperature deformation resistance of SBS/CRP composite modified asphalt is not much different from SBS modified asphalt’s. Therefore, it can provide the basic support for the application in alpine cold regions under the conditions of low temperature, strong radiation and heavy load.

Comparative analysis on rheological characteristics of different modified asphalt based on DSR and BBR evaluation

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Guangyuan Wu ◽  
Haitao Zhang ◽  
Junfeng Sun ◽  
Tengjiang Yu
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Model Parameters ◽  
Content Type ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Low Temperature Performance ◽  
Sbs Modified Asphalt ◽  
Main Curve

Purpose In order to evaluate the rheological properties of asphalt more comprehensively and effectively, and to explore and discuss the practicability of relevant models in the evaluation of the rheological properties of asphalt. Design/methodology/approach Based on the rheological and viscoelastic theories, temperature scanning, frequency scanning and multiple stress creep recovery (MSCR) tests of different modified asphalt were carried out by dynamic shear rheometer (DSR) to obtain relevant viscoelastic parameters and evaluate the high temperature properties of different modified asphalt. Based on the time-temperature equivalence principle, the main curve was constructed to study the viscoelastic properties of asphalt in a wider frequency domain. The main curve was fitted with the CAM model, and the rheological properties of different modified asphalt were evaluated through the analysis of model parameters. The creep stiffness and creep velocity of different modified asphalt were obtained through the rheological test of bending beam (BBR), and the low-temperature performance of different modified asphalt was analyzed by using Burgers model to fit the creep compliance. Findings The results show that the high temperature rheological properties of several modified asphalt studied in the test are ranked from best to worst as follows: PE modified asphalt > SBS modified asphalt > SBR modified asphalt. Short-term aging can improve the high temperature performance of asphalt, and different types of modifiers can promote or inhibit this improvement effect. Based on BBR test and Burgers model fitting analysis, SBR modified asphalt has the best low temperature performance, followed by SBS modified asphalt, while PE modified asphalt has poor low temperature performance, so it is not suitable to be used as road material in low temperature area. Originality/value Combined with effective evaluation methods, the rheological properties of asphalt at different temperatures and angles were systematically evaluated, and the evolution of rheological properties of asphalt characterized by model parameters was further analyzed by advanced model simulation.

scholarly journals Effect of Biowaste on the High- and Low-Temperature Rheological Properties of Asphalt Binders

2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Xuancang Wang ◽  
Yuchen Guo ◽  
Guanyu Ji ◽  
Yi Zhang ◽  
Jing Zhao ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Asphalt Binder ◽  
Oyster Shell ◽  
Asphalt Binders ◽  
Creep Recovery ◽  
Oyster Shell Powder ◽  
Shell Powder ◽  
Rheological Performance

The growth of aquaculture has increased the production of oysters. However, the increased oyster shell volume has created serious environmental and recycling problems for the society. In order to study the sustainable utilization of waste oyster shells, asphalt binder of waste oyster shell powder was prepared by using modified asphalt material with waste oyster shells. The microstructure of oyster shell powder was analyzed by scanning electron microscopy experiments. The chemical composition of the asphalt binder was observed by Fourier transform infrared spectroscopy tests. The physical properties of the asphalt binder, including softness, high-temperature performance, and plastic deformation capacity, were initially evaluated through three indicators’ tests on asphalt. A preliminary performance evaluation of the asphalt binder was performed. The high-temperature stability of asphalt binders was evaluated using dynamic shear rheometry. The rutting resistance of the material was evaluated by temperature sweep tests, and the shear deformation resistance of the material was evaluated by frequency sweep tests. Multiple stress creep recovery tests determine the material’s ability to resist permanent deformation. The low-temperature rheological properties were evaluated by bending beam rheology tests. The study found that the waste oyster shell powder is a biomass with a porous irregular petal shape. No new characteristic absorption peaks are formed by mixing with asphalt. And, it can improve the viscosity, thermal stability, and temperature-sensitive properties of the material. It significantly improved the high-temperature rheological performance, rutting coefficient, and recovery elasticity of the material. However, it has little effect on low-temperature rheological performance. This study provides a solid foundation for the effective use of biowaste in engineering materials.

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